A mechanistic study of the samarium(II)-mediated reduction of aryl nitro compounds to the corresponding arylamines. The crystal structures of {Sm[N(SiMe3)2]2(thf)}2 (μ2-O) and [(Me3Si)2N]2Sm(thf)}(μ-PhNNPh)Sm [N(SiMe3)2]2

Journal of the American Chemical Society

Volumn 124, Issue 24, 2002, Pages 7007-7015

  Brady, Erik D ^a   Clark, David L ^a   Keogh, D Webster ^a   Scott, Brian L ^a   Watkin, John G ^a  

^a LOS ALAMOS NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

INTERMEDIATE SPECIES;

CRYSTAL STRUCTURE; NUCLEAR MAGNETIC RESONANCE; X RAY CRYSTALLOGRAPHY;

SAMARIUM COMPOUNDS;

AROMATIC AMINE; AROMATIC NITRO COMPOUND; HYDRAZINE DERIVATIVE; NITRO DERIVATIVE; SAMARIUM;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; REDUCTION; STRUCTURE ANALYSIS; X RAY CRYSTALLOGRAPHY;

EID: 0037134817     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0168918     Document Type: Article

References (56)