Characterization of commercial iron chelates and their behavior in an alkaline and calcareous soil

Journal of Agricultural and Food Chemistry

Volumn 50, Issue 26, 2002, Pages 7609-7615

  Cantera, Rodrigo G ^a   Zamarreño, Angel M ^a   García Mina, José M ^a,b  

^a Department of Research   (Spain)

^b UNIVERSITY OF NAVARRA   (Spain)

Author keywords

Alkaline and calcareous soils; Chelate stability; Iron chelates; Iron chlorosis; Soil incubation

Indexed keywords

AGRICULTURAL CHEMICAL; CALCIUM; IRON; IRON CHELATE; IRON CHELATING AGENT;

AGRICULTURE; ALKALINITY; ARTICLE; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; IRON DEFICIENCY; MASS SPECTROMETRY; MODEL; NONHUMAN; PH; PLANT GROWTH; SOIL; SOLUBILITY; SOLUTION AND SOLUBILITY; SPAIN; THIN LAYER CHROMATOGRAPHY;

AGRICULTURE; AGROCHEMICALS; CALCIUM; CHROMATOGRAPHY, HIGH PRESSURE LIQUID; HYDROGEN-ION CONCENTRATION; IRON; IRON CHELATING AGENTS; SOIL; SOLUBILITY; SOLUTIONS; SPAIN;

EID: 0037132521     PISSN: 00218561     EISSN: None     Source Type: Journal    
DOI: 10.1021/jf025745y     Document Type: Article

References (15)

1. Martens, D. C.; Westermann, D. T. Fertilizer applications for correcting micronutrient deficiencies. In Micronutrients in Agriculture, 2nd Ed.; Mortvedt, J. J., Cox, F. R., Shuman, L. M., Welch, R. M., Eds.; SSSA books series no 4; Soil Science Society of America: Madison, WI, 1991; pp 549-592.
2. Hernández-Apaolaza, L.; Barak, P.; Lucena, J. Chromatographic determination of commercial Fe(III) chelates of ethylenediaminetetraacetic acid, ethylenediamine(o-hydroxyphenylacetic) acid and ethylenediaminedi(o-hydroxy-p-methilphenylacetic) acid. J. Chromatogr. A 1997, 789, 453-460.
3. Cremonini, M.; Álvarez-Fernández, A.; Lucena, J.; Rombolà, A.; Marangoni, B.; Placucci, G. NMR analysis of the iron ligand ethylenediaminedi (o-hydroxyphenyl)acetic acid (EDDHA) employed in fertilizers. J. Agric. Food Chem. 2001, 49, 3527- 3532.
4. Lucena, J. J.; Barak, P.; Hernández-Apaolaza, L.; Isocratic ionpair high-performance liquid chromatographic method for the determination of various iron (III) chelates. J. Chromatogr. A 1996, 727, 253-264.
5. Norvell, W.; Lindsay, W. Reaction of DTPA chelates of iron, zinc, copper and manganese with soils. Soil Sci. Soc. Am. Proc. 1972, 36, 778-783.
6. Goos, R.; Germain, S. Solubility of twelve iron fertilizer products in alkaline soils. Commun. Soil. Sci. Plant Anal. 2001, 32, 2317-2323.
7. Hellín, E.; Ureña, R.; Sevilla, F.; Alcaraz, C. F. Comparative study of the efectiveness of several iron compounds in the iron chlorosis correction in citrus plants. J. Plant Nutr. 1987, 10, 411-421.
8. Sánchez-Andreu, J.; Jordá, J.; Juárez, M. Reactions of FeEDTA and FeEDDHA applied to alkaline and calcareous soils. In Iron Nutrition and Interactions in Plants; Hen, Y., Hadar, Y., Eds.; Kluwer Academic Publishers: Dordrecht, Netherlands, 1991; pp 57-62.
9. Hill-Cottingham, D.; Lloyd-Jones, C. Behaviour of iron chelates in alkaline and calcareous soils, II. Plant Soil 1958, IX (3), 189-201.
10. Alvarez-Fernández, A.; Gárate, A.; Lucena, J. J. Interaction of iron chelates with several soil materials and with a soil standard. J. Plant Nutr. 1997, 20, 559-572.
11. Bannochie, J.; Martell, A. Affinities of Racemic and Meso Forms of N,N′-Ethylenebis[2-(o-hydroxyphenyl)glycine] for Divalent and Trivalent Metal Ions. J. Am. Chem. Soc. 1989, 111, 4735-4742.
12. Bailey, N. A.; Cummins, D.; McKenzie, E. D.; Worthington, J. M. Iron (III) compounds of phenolic ligands. The crystal and molecular structure of iron (III) compounds of the sexadentate ligand N,N′-ethylene-bis-(o-hydroxyphenlyglycine). Inorg. Chim. Acta 1981, 50, 111-120.
13. Patch, M. G.; Simolo, K. P.; Carrano, C. J. Evaluation of iron (III) N,N′-ethylenebis((o-hydroxyphenyl) glycinate) as a model for the iron binding site in the transferrins. Inorg. Chem. 1983, 22, 2630-2634.
14. Ahrland, S.; Dahlgren, A.; Persson, I. Stabilities and hydrolysis of some iron (III) and manganese (III) complexes with chelating ligands. Acta Agric. Scand. 1990, 40, 101-111.
15. Barak P.; Chen, Y. Determination of FeEDDHA in Soils and Fertilizers by Anion Exchange Chromatography. Soil Sci. Soc. Am. J. 1987, 51, 893-896.