Phase-transfer catalysis: A new rigorous mechanistic model for liquid-liquid systems

Chemical Engineering Science

Volumn 57, Issue 8, 2002, Pages 1355-1377

  Satrio, Justinus A B ^a   Doraiswamy, L K ^a  

^a IOWA STATE UNIVERSITY   (United States)

Author keywords

Benzaldehyde synthesis; Homogeneous PT catalyst; Kinetics; Mathematical modeling; Multiphase reactions; Phase transfer catalysis

Indexed keywords

CATALYSTS; COMPOSITION; ELECTROLYTES; ESTERIFICATION; HYDROLYSIS; OXIDATION; PHASE TRANSITIONS;

PHASE-TRANSFER CATALYSIS (PTC);

CATALYSIS;

BENZYL DERIVATIVE; CATALYSIS; CHEMICAL REACTION; KINETICS; LIQUID; MATHEMATICAL MODELING; MODEL TEST; PHASE CHANGE; SYNTHESIS;

EID: 0037129066     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0009-2509(02)00061-1     Document Type: Article

References (28)

1. Sodium hypochlorite as oxidant in phase transfer catalytic systems. Part I. Oxidation of aromatic aldehydes
2. The distribution and dissolution equilibria of phase transfer catalyst tricapryl-methilammonium chloride and its aqueous phase mass transfer
3. Oxidation of benzyl alcohol using hypochlorite ion via phase-transfer catalysis
4. Distribution and dissociation equilibria of phase transfer catalysts, tetrabutyl ammonium salts
5. Chromate ion as a synthetically useful nucleophile: A novel synthesis of aldehydes from alkyl halides
6. The design of gas absorbers: I. Methods for predicting rates of absorption with chemical reaction in packed columns and tests with 1 1/2 raschig rings
7. Kinetics of the oxidation of benzyl alcohol by hypochlorite ion in the presence of phase-transfer catalyst
8. Process for aqueous chromate ion oxidation of allylic halides and halomethylated aromatics to allylic and aromatic aldehydes
9. Kinetics and mechanism of oxidation of benzyl chloride by chromic acid
10. On the mechanism of phase transfer catalysis
11. Effect of potassium dichromate on aralkyl and alkyl halide in the presence of quaternary ammonium salts
12. Bis-tetrabutylammonium dichromate as an oxidizing nucleophile: Synthesis of aldehydes and ketones from alkyl halides
13. Phase transfer catalyzed oxidations of alcohols and amines by aqueous hypochlorite
14. An effective tri-phasic catalytic systems for oxidation of benzyl alcohol under phase transfer conditions
15. A procedure for the oxidation of alcohols to aldehydes based on phase transfer catalysis
16. Determination of quaternary ammonium salts by ion-pair extraction-titrations with tetrabromo-phthalein ethyl ester indicator
17. Production of benzaldehyde: A case study in a possible industrial application of phase-transfer catalysis
18. Triphase catalysis: A rigorous mechanistic model for nucleophilic substitution reactions based on a modified Langmuir-Hinshelwood/Eley-Rideal approach
19. B. Sur la solubilite des gaz danz les solutions aqueuses
20. Benzyl ether from phase transfer catalyzed acetate displacement of benzyl chloride
21. Benzyl alcohol from phase transfer catalyzed weakly alkaline hydrolysis of benzyl chloride
22. Mechanistic and kinetic investigation of liquid-liquid phase transfer catalyzed oxidation of benzyl chloride to benzaldehyde
23. Theoretical and experimental analysis of capsule membrane phase transfer catalysis: Selective alkaline hydrolysis of benzyl chloride to benzyl alcohol
24. A new model of capsule membrane phase transfer catalysis for oxidation of benzyl chloride to benzaldehyde with hydrogen peroxide