Unusual sulfur chemistry in the thermal reaction of sultene and thiophene endoperoxide sulfur donors with cyclic alkynes: Reversible formation of a persistent thiirenium ion and trapping of a thiirene by [4 + 2] cycloaddition

Journal of the American Chemical Society

Volumn 124, Issue 28, 2002, Pages 8316-8320

  Adam, Waldemar ^a   Bosio, Sara G ^a   Fröhling, Bettina ^a   Leusser, Dirk ^a   Stalke, Dietmar ^a  

^a UNIVERSITY OF WÜRZBURG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

PEROXIDES;

CYCLOADDITION;

SULFUR;

ALKADIENE; ALKYNE; CARBENE; SULFENIC ACID DERIVATIVE; SULFUR; SULTENE; THIIRENE; THIIRENIUM; THIOPHENE DERIVATIVE; THIOPHENE ENDOPEROXIDE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CYCLOADDITION; REACTION ANALYSIS; STEREOCHEMISTRY;

EID: 0037125487     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja025934x     Document Type: Article

References (20)