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Volumn 124, Issue 41, 2002, Pages 12098-12099

Reversal of enantioselectivity in the asymmetric rhodium- versus iridium-catalyzed hydroboration of meso substrates

Author keywords

[No Author keywords available]

Indexed keywords

BORON DERIVATIVE; HYDRAZINE DERIVATIVE; IRIDIUM; RHODIUM;

EID: 0037120915     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja026714m     Document Type: Article
Times cited : (84)

References (24)
  • 2
    • 84985609802 scopus 로고
    • Männig, D.; Nöth, H. Angew. Chem., Int. Ed. Engl. 1985, 24, 878; Angew. Chem. 1985, 97, 854.
    • (1985) Angew. Chem. , vol.97 , pp. 854
  • 3
    • 0010883065 scopus 로고    scopus 로고
    • Jacobsen, E. N., Pfaltz, A., Yamamoto, H., Eds.; Springer-Verlag: Berlin, and references therein
    • Hayashi, T. In Comprehensive Asymmetric Catalysis; Jacobsen, E. N., Pfaltz, A., Yamamoto, H., Eds.; Springer-Verlag: Berlin, 1999; Vol. 1, pp 351-364 and references therein.
    • (1999) Comprehensive Asymmetric Catalysis , vol.1 , pp. 351-364
    • Hayashi, T.1
  • 9
    • 0031470418 scopus 로고    scopus 로고
    • (a) Wadepohl, H. Angew. Chem., Int. Ed. Engl. 1997, 36, 2441; Angew. Chem. 1997, 109, 2547.
    • (1997) Angew. Chem. , vol.109 , pp. 2547
  • 14
    • 0003400107 scopus 로고
    • Wiley-Interscience: New York
    • Reversal of enantioselectivity in the asymmetric hydrogenation using Rh-BINAP or Ru-BINAP systems is well documented, but the two catalytic cycles involve completely different reactive intermediates and kinetic profiles: Noyori, R. Asymmetric Catalysis in Organic Synthesis; Wiley-Interscience: New York, 1994.
    • (1994) Asymmetric Catalysis in Organic Synthesis
    • Noyori, R.1
  • 15
    • 0000526264 scopus 로고
    • Experimental studies: Evans, D. A.; Fu, G. C.; Anderson, B. A. J. Am. Chem. Soc. 1992, 114, 6679. Theoretical studies: Dorigo, A. E.; von Ragué Schleyer, P. Angew. Chem., Int. Ed. Engl. 1995, 34, 115; Angew. Chem. 1995, 107, 108.
    • (1992) J. Am. Chem. Soc. , vol.114 , pp. 6679
    • Evans, D.A.1    Fu, G.C.2    Anderson, B.A.3
  • 16
    • 33745121502 scopus 로고
    • Experimental studies: Evans, D. A.; Fu, G. C.; Anderson, B. A. J. Am. Chem. Soc. 1992, 114, 6679. Theoretical studies: Dorigo, A. E.; von Ragué Schleyer, P. Angew. Chem., Int. Ed. Engl. 1995, 34, 115; Angew. Chem. 1995, 107, 108.
    • (1995) Angew. Chem., Int. Ed. Engl. , vol.34 , pp. 115
    • Dorigo, A.E.1    Von Ragué Schleyer, P.2
  • 17
    • 0000526264 scopus 로고
    • Experimental studies: Evans, D. A.; Fu, G. C.; Anderson, B. A. J. Am. Chem. Soc. 1992, 114, 6679. Theoretical studies: Dorigo, A. E.; von Ragué Schleyer, P. Angew. Chem., Int. Ed. Engl. 1995, 34, 115; Angew. Chem. 1995, 107, 108.
    • (1995) Angew. Chem. , vol.107 , pp. 108


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