Activation of the tertiary carboxamide C-N bond in werner complexes: A classical structure-function relationship

Angewandte Chemie - International Edition

Volumn 41, Issue 18, 2002, Pages 3386-3388

  Niklas, Nicole ^a   Heinemann, Frank W ^a   Hampel, Frank ^a   Alsfasser, Ralf ^a  

^a UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

Author keywords

Amides; Cadmium; Cleavage reactions; Coordination chemistry; Copper; Isomerization

Indexed keywords

CHEMICAL BONDS; ISOMERIZATION;

COORDINATION COMPOUNDS;

ORGANIC COMPOUNDS;

AMIDE; CARBON; NITROGEN;

ARTICLE; CHEMICAL BOND; CHEMICAL STRUCTURE; COMPLEX FORMATION; ISOMERISM; PROTEIN FOLDING; STRUCTURE ANALYSIS;

EID: 0037119706     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3773(20020916)41:18<3386::AID-ANIE3386>3.0.CO;2-9     Document Type: Article

References (21)

1. The Amide Linkage: Selected Structural Aspects in Chemistry, Biochemistry, and Materials Science (Eds.:33 A. Greenberg, C.M. Breneman, J. F. Liebman), Wiley-VCH, Weinheim, 2000, p. 47.
2. C. Cox, T. Lectka, Acc. Chem. Res. 2000, 33, 849.
3. M. I. Page, Acc. Chem. Res. 1984, 17, 144;
4. b) E. C. Constable, Metals and Ligand Reactivity, VCH, Weinheim, 1996, p. 56.
5. C. Cox, D. Ferraris, N. N. Murthy, T. Lectka, J. Am. Chem. Soc. 1996, 118, 5332.
6. N. Niklas, F. Hampel, G. Liehr, A. Zahl, R. Alsfasser, Chem. Eur. J. 2001, 7, 5135.
7. a) J.-C. Wang, C.-H. Sun, T. J. Chow, L.-K. Liu, Acta Crystallogr. Sect. C 1991, 47 2459;
8. b) F. Muller, G. van Koten, K. Vrieze, B. Krijnan, C. H. Stam, J. Chem. Soc. Chem. Commun. 1986, 150;
9. c) F. Muller, G. van Kotem, M. J. A. Kraakman, K. Vrieze, D. Heijdenrijk, M. C. Zoutberg, Organometallics 1989, 8, 1331;
10. d) F. Muller, G. van Koten, K. Vrieze, D. Heijdenrijk, Organometallics 1989, 8, 33;
11. e) L. H. Polm, G. van Koten, K. Vrieze, C. H. Stam, W. C. J. van Tunen, J. Chem. Soc. Chem. Commun. 1983, 1177;
12. f) O. C. P. Beers, J. G. P. Delis, W. P. Mul, K. Vrieze, C. J. Elsevier, W. J. J. Smeets, A. L. Spek, Inorg. Chem. 1993, 32, 3640;
13. g) Z. Chen, L. Luo, S. P. Nolan, J. L. Petersen, M. L. Trudell, J. Organomet. Chem. 1997, 533, 25;
14. h) P. Maslak, J. J. Sczepanski, M. Parvez, J. Am. Chem. Soc. 1991, 113, 1062.
15. -3 3
16. F. K. Winkler, J. D. Dunitz, J. Mol. Biol. 1971, 59, 169.
17. a) E. Chelain, R. Goumont, L. Hamon, A. Parlier, M. Rudler, H. Rudler, J.-C. Daran, J. Vaissermann, J. Am. Chem. Soc. 1992, 114, 8088;
18. b) M. Rosoff, M. Rudler, J. Vaissermann, J. Am. Chem. Soc. 1992, 114, 8088;
19. c) J. A. King, Jr., G. L. Bryant, Jr., Acta Crystallogr. Sect. C 1991, 47, 2249.
20. 6]acetone. Details of the method are described in reference [5].
21. N. Niklas, F. W. Heinemann, unpublished results. Cleavage experiments were performed using solutions of the respective pure metal complex in methanol/dichloromethane (1:0, 4:1, 3:2, 1:1) mixtures assuring pseudo- first-order conditions.