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This has been subsequently referred to as the Zavitsas and Pinto postulate
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note
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The polar effect traces its origins to: Mayo, F. R.; Walling C. Chem. Rev. 1950, 46, 191. Shaik et al., in their ref 2, have a historical error: Walling's seminal book Free Radicals in Solution was published in 1957, not 1973.
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