Ln13Br18B3 (Ln = Gd, Tb) - A compound containing a combination of discrete and condensed clusters

Angewandte Chemie - International Edition

Volumn 41, Issue 22, 2002, Pages 4257-4259

  Oeckler, Oliver ^a   Kienle, Lorenz ^a   Mattausch, Hansjürgen ^a   Simon, Arndt ^a  

^a MAX PLANCK INSTITUT FÜR FESTKÖRPERFORSCHUNG   (Germany)

Author keywords

Boron; Cluster compounds; Electron microscopy; Lanthanides; Solid state structures

Indexed keywords

CONDENSATION; ELECTRON MICROSCOPY; X RAY SCATTERING;

CONDENSED CLUSTERS;

TERBIUM COMPOUNDS;

BORON DERIVATIVE; BROMINE DERIVATIVE; GADOLINIUM; LANTHANIDE; TERBIUM;

ARTICLE; CHEMICAL ANALYSIS; ELECTRON MICROSCOPY; MATERIALS; MATERIALS TESTING; RADIATION SCATTERING;

EID: 0037112586     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3773(20021115)41:22<4257::AID-ANIE4257>3.0.CO;2-M     Document Type: Article

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15. 3 (750 mg)], Tb (433 mg) [Gd (323 mg)] and B (14.4 [10.7] mg; 5N, Aldrich) and sealed under Ar by arc-melting. These were heated for 30 days at 950°C [6 days at 1000°C]. Further details are analogous to the procedures described in reference [3g]. The compounds can be obtained as almost single-phase products according to X-ray powder diagrams. They are sensitive to moisture and need to be handled in a dry inert gas atmosphere.
16. 3). A detailed description of the structural analysis as well as an analysis of symmetry relationships and additional real structure phenomena will be published elsewhere (O, Oeckler, L. Kienle, H. Mattausch, O. Jarchow, A. Simon, Z. Kristallogr., submitted).
17. 3). A detailed description of the structural analysis as well as an analysis of symmetry relationships and additional real structure phenomena will be published elsewhere (O, Oeckler, L. Kienle, H. Mattausch, O. Jarchow, A. Simon, Z. Kristallogr., submitted).
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