Synthesis, characterization and X-ray structures of the new dinucleating ligand 2,8-dimethyl-1,4,5,6,7,10,11,12-octahydroimidazo[4,5-h] imidazo[4,5-c][1,6]diazecine-5,11-diethanoic acid and its Cu(II) complex; an alternating chain of Cu(II) ions, coupled both intramolecularly and intermolecularly

Inorganica Chimica Acta

Volumn 339, Issue , 2002, Pages 51-59

  Mendoza Díaz, Guillermo ^a   Driessen, Willem L ^b   Reedijk, Jan ^b   Gorter, Syb ^b   Gasque, Laura ^c   Thompson, Kimberly R ^a  

^a UNIVERSITY OF GUANAJUATO   (Mexico)

^b LEIDEN UNIVERSITY   (Netherlands)

^c UNIVERSIDAD NACIONAL AUTÓNOMA DE MÉXICO   (Mexico)

Author keywords

Copper(II) complex; Diazecine ring; Dinuclear complexes; Imidazole

Indexed keywords

AMINO ACIDS; CHELATION; CHROMIUM COMPOUNDS; COMPLEX NETWORKS; COMPLEXATION; CONFORMATIONS; CRYSTAL STRUCTURE; HYDROGEN BONDS; LIGANDS; MAGNETIC SUSCEPTIBILITY; MAGNETISM; METAL IONS; METALS; MOLECULES; TEMPERATURE;

COPPER COMPLEXES; DINUCLEAR COMPLEX; HYDROGEN BOND NETWORKS; IMIDAZOLE; METAL-METAL DISTANCES; ONE-DIMENSIONAL NETWORKS; PYRAMIDAL ENVIRONMENTS; TWO-DIMENSIONAL NETWORKS;

COPPER COMPOUNDS;

2,8 DIMETHYL 1,4,5,6,7,11,12 OCTAHYDROIMIDAZO[4,5 C][1,6]DIAZECINE 5,11 DIETHANOIC ACID; ACETIC ACID DERIVATIVE; COPPER COMPLEX; GLYCINE; HETEROCYCLIC COMPOUND; LIGAND; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL BOND; CONFORMATION; CRYSTAL STRUCTURE; HYDROGEN BOND; MAGNETISM; MOLECULAR INTERACTION; PROTEIN CONFORMATION; STRUCTURE ANALYSIS; SYNTHESIS; TEMPERATURE; X RAY ANALYSIS;

EID: 0037112114     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0020-1693(02)00916-7     Document Type: Article

References (21)

1. Richardson J.S., Thomas K.A., Rubin B.H., Richardson D.C. Proc. Natl. Acad. Sci. USA. 72:1975;1349.
2. Bouwman E., Driessen W.L., Reedijk J. J. Coord. Chem. Rev. 104:1990;143.
3. Hay P.J., Thibeault J.C., Hoffman R. J. Am. Chem. Soc. 97:1975;4884.
4. Solomon E.I., Penfield K.W., Wilcox D.E. Pure Appl. Chem. 55:1983;1069.
5. Karunakaran S., Kandaswamy M. J. Chem. Soc. Dalton Trans. 1994;1595.
6. Mendoza-Díaz G., Driessen W.L., Reedijk J. Acta Crystallogr., C. 52:1996;960.
7. Stocker F.B., Kurtz J.L., Byron L.G., Forsyth D.A. J. Org. Chem. 35:1970;883.
8. Teo S.-B., Ng C.-H., Tiekink E.R.T. J. Coord. Chem. 29:1993;57.
9. Berndt D.C. J. Org. Chem. 35:1970;1129.
10. Geue R.J., Höhn A., Ralph S.F., Sargeson A.M., Willis A.C. J. Chem. Soc. Chem. Commun. 1994;1513.
11. Baumann G.C., Summers M.F., Hutchinson J.P., Zubieta J., Marzilli L.G. Inorg. Chem. 23:1984;3104.
12. International Tables for X-Ray Crystallography. Kynoch Press, Birmingham, vol. 4 (1974).
13. S.R. Hall, H.D. Flack, J.M. Stewart, Xtal3.2 Program; University of Western Australia, Nedlands, WA, 1992.
14. A.L. Spek, PLUTON-92. Interactive Molecular Graphics Program, Utrecht University, Utrecht, The Netherlands, 1992.
15. Cremer D., Pople J.A. J. Am. Chem. Soc. 97:1975;1354.
16. V.A. Palyulin et al., J. Mol. Struct. 70 (1981) 65.
17. A.L. Spek, PLATON-93. Program for the automated analysis of molecular geometry, Utrecht University, Utrecht, The Netherlands, 1993.
18. Spek A.L. Acta Crystallogr., A. 46:1990;C34.
19. Musci G., Fraterrigo T.Z.L., Calabrese L., McMillin D.R. J. Biol. Inorg. Chem. 4:1999;441.
20. Hall J.W., Marsh W.E., Weller R.R., Hatfield W.E. Inorg. Chem. 20:1981;1033.
21. Coffman R.E., Buetlner G.R. J. Phys. Chem. 83:1979;2387.