New heteronuclear Mo/Fe/S clusters. The syntheses and structures of (Cl4-cat)Mo (PEt3)Fe3S4(SPEt3)2Cl and (Cl4-cat) 2MoFe2S2 (PEt3)2(CO)4 clusters

Polyhedron

Volumn 21, Issue 24, 2002, Pages 2523-2530

  Han, Jaehong ^a   Huang, Mingsheng ^a,b   Coucouvanis, Dimitri ^a  

^a UNIVERSITY OF MICHIGAN   (United States)

^b Bldg 142   (United States)

Author keywords

CO; Mo Fe S cluster; S=PEt3 ligand; Structures; Synthesis

Indexed keywords

CHELATION; CHLORINE COMPOUNDS; CRYSTALLINE MATERIALS; IRON; IRON COMPOUNDS; LEAD COMPOUNDS; LIQUID CHROMATOGRAPHY;

CHROMATOGRAPHIC SEPARATIONS; CO; ELECTRON RESERVOIR; FE ATOMS; FE/S CLUSTERS; HETERONUCLEAR; MO/FE/S CLUSTER; NEUTRAL CLUSTERS; S=PET3 LIGAND; SYNTHETIC PATHWAYS;

LIGANDS;

ACETONITRILE; CARBON MONOXIDE; IRON DERIVATIVE; LIGAND; MOLYBDENUM; SULFUR DERIVATIVE;

ARTICLE; CHEMICAL REACTION; CHROMATOGRAPHY; CRYSTAL STRUCTURE; ELECTRON; MOLECULAR INTERACTION; MOSSBAUER SPECTROSCOPY; SYNTHESIS;

EID: 0037111356     PISSN: 02775387     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0277-5387(02)01208-1     Document Type: Article

References (42)

1. (a) J.B. Howard, D.C, Rees, Chem. Rev. 96 (1996) 2965 (and references therein);
2. (b) J.W. Peters, M.H.B. Stowell, S.M. Soltis, M.G. Finnegan, M.K. Johnson, D.C. Rees, Biochemistry 36 (1997) 1181;
3. (c) S.M. Mayer, D.M. Lawson, C.A. Gormal, S.M. Roe, B.E.J. Smith, Mol. Biol. 292 (1999) 871.
4. K.D. Demadis, C.F. Campana, D. Coucouvanis, J. Am. Chem. Soc. 117 (1995) 7832.
5. J. Han, M. Koutmos, S. Al-Ahmad, D. Coucouvanis, Inorg. Chem. 40 (2001) 5985.
6. (a) J. Han, K. Beck, N. Ockwig, D. Coucouvanis, J. Am. Chem. Soc. 121 (1999) 10448;
7. (b) M.A. Tyson, D. Coucouvanis, Inorg. Chem. 36 (1997) 3808.
8. D. Coucouvanis, J. Han, N. Moon, Inorg. Chem. 124 (2001) 216.
9. J. Han, D. Coucouvanis, J. Am. Chem. Soc. 123 (2001) 11304.
10. R.E. Palermo, R. Singh, J.K. Bashkin, R.H. Holm, J. Am. Chem. Soc. 106 (1984) 2600.
11. P.R. Challen, Ph.D. thesis, University of Michigan, 1990.
12. G. Booth, J. Chatt, J. Chem. Soc. (1962) 2099.
13. K.D. Demadis, C.F. Campana, D. Coucouvanis, J. Am. Chem. Soc. 117 (1995) 7832.
14. J.R. Moss, B.L. Shaw, J. Chem. Soc. A (1970) 595.
15. (a) P.K. Baker, A.I. Clark, M.G.B. Drew, M.C. Durrant, R.L. Richards, J. Organomet. Chem. 549 (1997) 193;
16. (b) B.J. Brisdon, A.G.W. Hodson, M.F. Mahon, K.C. Molloy, J. Chem. Soc., Dalton Trans. 245 (1993) 193;
17. (c) D.C. Brower, P.B. Winston, T.L. Tonker, J.L. Templeton, Inorg. Chem. 25 (1986) 2883.
18. C.G. Pierpont, R.M. Buchanan, Coord. Chem. Rev. 38 (1981) 45.
19. dmpe = 1,2-bis(dimethylphosphino)ethane;
20. (b) Y.-P. Zhang, J.K. Bashkin, R.H. Holm, Inorg. Chem. 26 (1987) 694.
21. 3] cluster are shown at 2.742(6), 2.729(11), 2.735(9), 2.775(9), and 2.749(10) Å, respectively.
22. F. Osterloh, B.M. Segal, C. Achim, R.H. Holm, Inorg. Chem. 39 (2000) 980.
23. 3] cluster are shown at 2.716(7), 2.722(10), 2.724(14), 2.728(3), and 2.707(19) Å, respectively.
24. For the experimental conditions, N. Moon, C.T. Coffin, D.C. Steinke, R.H. Sands, W.R. Dunham, Nucl. Inst. Meth. Phys. Res. B. 119 (1996) 555.
25. G. Christou, P.K. Mascharak, W.H. Armstrong, G.C. Papaefthymiou, R.B. Frankel, R.H. Holm, J. Am. Chem. Soc. 104 (1982) 2820.
26. -1, respectively. M.J. Carney, J.A. Kovacs, Y.-P. Zhang, G.C. Papaefthymiou, K. Spartalian, R.B. Frankel, R.H. Holm, Inorg. Chem. 26 (1987) 719.
27. -1, respectively.
28. (a) P. Mathur, I.J. Mavunkal, V. Rugmini, J. Organomet. Chem. 367 (1989) 243;
29. (b) M. Cowie, R.L. DeKock, T.R. Wagenmaker, D. Seyferth, R.S. Henderson, M.K. Gallagher, Organometallics 8 (1989) 119;
30. (c) Y. Wakatsuki, H. Yamazaki, G. Cheng, J. Organomet. Chem. 347 (1988) 151;
31. (d) D. Seyferth, R.S. Henderson, L.-C. Song, Organometallics 1 (1982) 125;
32. (e) D.A. Lesch, T.B. Rauchfuss, J. Organomet. Chem. 199 (1980) C6;
33. (f) D. Seyferth, R.S. Henderson, M.K. Gallagher, J. Organomet. Chem. 193 (1980) C75.
34. (a) B. Zhuang, P. Chen, L. Huang, J. Lu, Polyhedron 11 (1992) 127;
35. (b) P.T. Bishop, J.R. Dilworth, S. Morton, J.A. Zubieta, J. Organomet. Chem. 341 (1988) 373;
36. (c) J.R. Dilworth, S. Morton, J. Organomet. Chem. 314 (1986) C25.
37. K.S. Bose, S.A. Chmielewski, P.A. Eldredge, E. Sinn, B.A. Averill, J. Am. Chem. Soc. 111 (1989) 8953.
38. D.E. Barber, R.F. Bryan, M. Sabat, K.S. Bose, B.A. Averill, Inorg. Chem. 35 (1996) 4635.
39. K.S. Bose, P.E. Lamberty, J.E. Kovacs, E. Sinn, B.A. Averill, Polyhedron 5 (1986) 393.
40. P.A. Eldredge, R.F. Bryan, E. Sinn, B.A. Averill, J. Am. Chem. Soc. 110 (1988) 5573.
41. 4] cuboidal core has been reported by us in reference [5].
42. 1 = 0.0577 (for 1 > 2σ(1)).