Spectroscopic study of the coordination sphere of Gd(III) in Gd(III)-M(II) complexes with a compartmental ligand, where the local environment around Gd(III) is controlled by (M(II) M(II) = Ni(II), Zn(II) and a vacancy)

Polyhedron

Volumn 21, Issue 21, 2002, Pages 2127-2135

  Miyamoto, Ryo ^a   Sugai, Takayasu ^a   Sudoh, Susumu ^a  

^a HIROSAKI UNIVERSITY   (Japan)

Author keywords

4f Electron; Coordination structures; EPR spectroscopy; Rare earth complexes

Indexed keywords

ELECTRON SPIN RESONANCE SPECTROSCOPY; ELECTRONS; ETHYLENE; GADOLINIUM COMPOUNDS; LIGANDS; MOLECULAR ORBITALS; NICKEL COMPOUNDS; ORBITS; RARE EARTHS; SPECTROSCOPIC ANALYSIS; ZINC COMPOUNDS;

4F-ELECTRONS; COMPARTMENTAL LIGANDS; COORDINATION SPHERE; COORDINATION STRUCTURES; EPR SPECTROSCOPY; EPR SPECTRUM; LOCAL ENVIRONMENTS; RARE EARTH COMPLEX; SPECTROSCOPIC STUDIES; UV-VIS-IR SPECTRA;

IONS;

COORDINATION COMPOUND; GADOLINIUM; LANTHANIDE; LIGAND; MANGANESE; METAL COMPLEX; NICKEL COMPLEX; ZINC COMPLEX;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL REACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; CRYSTAL STRUCTURE; ELECTRON SPIN RESONANCE; PROTON NUCLEAR MAGNETIC RESONANCE; ULTRAVIOLET SPECTROPHOTOMETRY; X RAY ANALYSIS;

EID: 0037106195     PISSN: 02775387     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0277-5387(02)01160-9     Document Type: Article

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