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Taking the Pd monolayer adsorbed on the oxygen termination as a reference, the adhesion energy calculated within FP-LAPW (FP-LMTO) approach increases by 0.4 (0.1), 1.1 (1.3), 2.1 (2.4), and 2.7 (3.0) eV along the series Cu, Ru, Mo, and Zr. FP-LMTO reproduces also correctly the fine features, as e.g. the inversed stability of oxygen and magnesium (111) terminations covered with Pd and Cu monolayers.
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