Heterodinuclear Cu(II)-Zn(II) complexes: 19F NMR as a versatile tool to control the synthesis

Inorganica Chimica Acta

Volumn 333, Issue 1, 2002, Pages 144-147

  Torelli, Stéphane ^a   Belle, Catherine ^a   Gautier Luneau, Isabelle ^a   Hamman, Sylvain ^a   Pierre, Jean Louis ^a  

^a CNRS   (France)

Author keywords

Experimental method; Heterobimetallic Cu Zn complexes; Paramagnetic 19F NMR

Indexed keywords

CHELATION; COPPER ALLOYS; LIGANDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PARAMAGNETISM; SYNTHESIS (CHEMICAL); ZINC ALLOYS; ZINC COMPOUNDS;

19F NMR; DINUCLEATING LIGANDS; EXPERIMENTAL METHODS; EXPERIMENTAL PROCEDURE; FLUORINATED LIGANDS; PARAMAGNETIC COMPLEXES; STATISTICAL DISTRIBUTION; ZN COMPLEX;

COPPER COMPOUNDS;

2,6 BIS[[2 (2 PYRIDYLMETHYL)AMINO]METHYL] 4 FLUOROPHENOL; 2,6 BIS[[BIS(2 PYRIDYLMETHYL)AMINO]METHYL] 4 METHYLPHENOL; COPPER COMPLEX; CRESOL; LIGAND; PHENOL DERIVATIVE; UNCLASSIFIED DRUG; ZINC COMPLEX;

ARTICLE; FLUORINATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; STATISTICAL ANALYSIS; STRUCTURE ANALYSIS; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

EID: 0037094254     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0020-1693(02)00770-3     Document Type: Article

References (7)

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4. Torelli S., Belle C., Gautier-Luneau I., Pierre J.-L., Saint-Aman E., Latour J.M., Le Pape L., Luneau D. Inorg. Chem. 39:2000;3526.
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6. 3.
7. 1H NMR spectra of Cu-Zn complexes described herein show few and extremely broad signals. The homodinuclear Cu-Cu complexes present relatively well resolved isotropically shifted resonances and identified on a 200 ppm spectral window for the isolated compound but non-usable when different species are present in the medium.