Electron structure of highly symmetrical f-element compounds. Part 33. First experimental derivation of crystal field parameters of a trigonal-bipyramidal coordinated lanthanide(III) system: Pr[N(SiMe3)2]3(CNR)2 (R = tBu, C6H11);Zur elektronenstruktur hochsymmetrischer verbindungen der f-elemente. Teil 33. Erstmalige experimentelle ableitung der kristallfeld-parameter eines trigonal-bipyramidal koordinierten lanthanid(III)-systems: Pr[N(SiMe3)2]3(CNR)2 (R = tBu, C6H11)

Spectrochimica Acta - Part A Molecular and Biomolecular Spectroscopy

Volumn 58, Issue 2, 2002, Pages 379-396

  Amberger, Hanns Dieter ^a   Jank, Stefan ^a   Reddmann, Hauke ^a   Edelstein, Norman M ^b  

^a UNIVERSITY OF HAMBURG   (Germany)

^b UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

Crystal field analysis; Optical and magnetic circular dichroism spectra; Paramagnetic susceptibility; Praseodymium(III); Trigonal bipyramidal coordination

Indexed keywords

ORGANOMETALLIC COMPOUND; PRASEODYMIUM;

ARTICLE; CHEMISTRY; CIRCULAR DICHROISM; CRYSTALLIZATION;

CIRCULAR DICHROISM; CRYSTALLIZATION; ORGANOMETALLIC COMPOUNDS; PRASEODYMIUM;

COMPLEXATION; COMPUTER SIMULATION; COORDINATION REACTIONS; ELECTRONIC STRUCTURE; HAMILTONIANS; LIGHT ABSORPTION; LUMINESCENCE; MAGNETIC SUSCEPTIBILITY; SINGLE CRYSTALS; THERMAL EFFECTS;

TRIGONAL BIPYRAMIDAL COORDINATION;

PRASEODYMIUM COMPOUNDS;

EID: 0037079567     PISSN: 13861425     EISSN: None     Source Type: Journal    
DOI: 10.1016/S1386-1425(01)00547-9     Document Type: Article

References (42)

1. Crystal fields in non-metallic (rare earth) compounds
2. Rationalization of crystal field parametrization
3. Lanthanide Amides
4. Routes to monomeric lanthanide alkoxides
5. Raman scattering by crystal-field excitations
6. Spectroscopic properties of the f-Elements in compounds and Solutions