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see footnote 25
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38
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0011721502
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Manuscript to be published
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Terfort, A. Manuscript to be published.
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Terfort, A.1
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39
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0011723694
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note
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The saturation concentration of MMTA in ethanol was estimated by first preparing a 0.1 mM solution and then diluting it until any turbidity disappeared. A ultrasonic bath was used to accelerate the solution process. The values determined this way amount to about 0.003 mM for ethanol and to about 0.05 mM for THF. Note that these values are significantly lower than those provided in earlier work (ref 34).
-
-
-
-
40
-
-
0011723695
-
-
note
-
An ultrahigh precision balance (Sartorius 2104) with a resolution of 1μg and a reproducibility of better than 5 μg was used.
-
-
-
-
41
-
-
0011775986
-
-
note
-
Absorbance units: 0 AU = 100% transmission, 1 AU = 10% transmission, 2 AU = 1% transmission (logarithm scale).
-
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42
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0011752603
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note
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2 asym. vibration.
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49
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0034660159
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51
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0011788605
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-
note
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NaOH is not soluble in pure ethanol, but ethanol regularly contains small amounts of water which are sufficient to solve small amounts of NaOH.
-
-
-
-
54
-
-
0011779052
-
-
note
-
The bands were fitted using a set of more than 30 Pearson-VII functions to take overlapping band intensities into account.
-
-
-
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56
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0003459529
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Chastain, J., Ed.; Perkin-Elmer Corp., Physical Electronics Division: Eden Prairie, MN
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Moulder, J.F.; Stickle, W.E.; Sobol, P.E.; Bomben, K.D. Handbook of X-ray Photoelectron Spectroscopy; Chastain, J., Ed.; Perkin-Elmer Corp., Physical Electronics Division: Eden Prairie, MN, 1992.
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58
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0011778664
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Manuscript to be published
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Wehner, B.1
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59
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0011753175
-
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note
-
For photoelectrons with a kinetic energy of 1202 eV (C 1s excited by Al Kα), a mean free path of 35 Å was used in the case of the aliphatic octadecanethiol whereas 0.78 × 35 Å was used in the case of the aromatic MMTA. This reduced mean free path reflects the somewhat higher electron absorption/scattering of the aromatic species. For 1400 eV electrons (Au 4f), a mean free path of 45 Å was used in all cases.
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61
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0030668848
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A possible change of the excitation probabilities, which may also be caused by the deshielding, will be neglected.
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67
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0011721145
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note
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-1 is related to an overlap of the band of the TFA cyclic dimer and the two bands of the TFA-MHDA cyclic dimer. These bands are not relevant for the present investigations.
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81
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0011787429
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note
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2 of the SAM surface. This amount is clearly below the maximum amount of metal ion content as provided by the supplier (typical value of 0.02 ppm per species of metal ions).
-
-
-
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83
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0011762446
-
-
note
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3 vibrations could be detected in the corresponding IR spectrum.
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84
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0000693071
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