Energy, enthalpy, and volume change of hydrogen-bond formation in large, charged, water vapor clusters, H+(H2O)c, determined from mass spectral distributions

Journal of Physical Chemistry A

Volumn 106, Issue 6, 2002, Pages 933-937

  Walrafen, G E ^a   Chu, Y C ^b   Carlon, H R ^c  

^a UNIVERSITY OF KANSAS   (United States)

^b HOWARD UNIVERSITY   (United States)

^c 1904 Norwood Court ^*  (United States)

Author keywords

[No Author keywords available]

Indexed keywords

MASS SPECTRAL DISTRIBUTIONS;

CONDENSATION; ENTHALPY; INFRARED SPECTROSCOPY; PARTIAL PRESSURE; RAMAN SPECTROSCOPY; STEAM; VISCOSITY;

HYDROGEN BONDS;

EID: 0037075378     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp013612u     Document Type: Article

References (12)

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7. Walrafen, G.E.; Yang, W.-H. Unpublished work.
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9. Ĉ is the most probable, or peak value, of the Y = CS versus X distribution, and as such seems most consistent with thermodynamics. For example, the thermodynamic energy, E, corresponds to the most probable value of the E distribution, because the E-distribution peak corresponds to the maximum entropy. The average value of the E distribution only equals the most probable value when the distribution is symmetric, i.e., when third and higher moments are zero.
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