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84984135544
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During the course of the reaction sequence an additional stereogenic center is formed on the phosphorous atom which results in the formation of two diastereomers which are observed as two separate peaks in the sip NMR spectrum. See also: (a) Stegerhoek, L.J.; Verkade, P.E. Recl. Trav. Chim. Pays-Bas 1958, 77, 133. (b) Gielkens, J.W.; Hoefnagel, M.A.; Stegerhoek, L.J.; Verkade, P.E. Recl. Tray. Chim. Pays-Bas 1958, 77, 656.
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84982367445
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During the course of the reaction sequence an additional stereogenic center is formed on the phosphorous atom which results in the formation of two diastereomers which are observed as two separate peaks in the sip NMR spectrum. See also: (a) Stegerhoek, L.J.; Verkade, P.E. Recl. Trav. Chim. Pays-Bas 1958, 77, 133. (b) Gielkens, J.W.; Hoefnagel, M.A.; Stegerhoek, L.J.; Verkade, P.E. Recl. Tray. Chim. Pays-Bas 1958, 77, 656.
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0002088628
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s symmetry and is triangular in projection with only two of the four basal edges being expressed. Type II calcite can be formed through nucleation from different faces, that is, [00.1] (n-eicosyl sulphate) and [1-10] (stearic acid). The calcite formed in the present case is of type II and has nucleated from the (10.0) face. Type I calcite is thought to arise from a realignment and subsequent secondary growth of type II calcite at the monolayer surface.
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Mann, S.1
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0011289066
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note
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Under liquid expanded monolayers also a small amount of type I vaterite was formed (approximately 15% of the crystals). When the experiments were performed under compressed monolayers, this number was reduced to approximately 8%.
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note
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In addition, a significant amount of vaterite crystals was observed
-
In addition, a significant amount of vaterite crystals was observed.
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51
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0011326657
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note
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Surfactant 3 was insoluble in water, and no distinct aggregate morphology could therefore be detected by transmission electron microscopy.
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54
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0011344739
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note
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2 deduced from these models is in good agreement with the value obtained from the π-A isotherm.
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