An unexpected deboronation of [tBuB(3-tBuC3H2N2) 3]- in a reaction with iron(II) chloride, and the X-ray crystal structure of trans-FeCl2(tBuC3H3N 2)4

Inorganica Chimica Acta

Volumn 341, Issue , 2002, Pages 127-131

  Graziani, Olivier ^a   Toupet, Loïc ^b   Hamon, Jean René ^a   Tilset, Mats ^c  

^a CNRS   (France)

^b UNIVERSITÉ DE RENNES 1   (France)

^c UNIVERSITY OF OSLO   (Norway)

Author keywords

Crystal structures; Deboronation reaction; Iron complexes; Pyrazole complexes; Tris(pyrazolyl)borate

Indexed keywords

CHLORINE COMPOUNDS; CRYSTAL STRUCTURE;

DEBORONATION; HIGH SPINS; IRON CHLORIDES; IRON COMPLEX; PYRAZOLES; TRISPYRAZOLYLBORATE; X RAY CRYSTAL STRUCTURES;

IRON COMPOUNDS;

BORIC ACID; BORON DERIVATIVE; FERROUS CHLORIDE; IRON COMPLEX; THALLIUM;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL BOND; CHEMICAL REACTION; CRYSTAL STRUCTURE; DEBORONATION; GEOMETRY; STEREOSPECIFICITY; X RAY CRYSTALLOGRAPHY;

EID: 0037058843     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0020-1693(02)01178-7     Document Type: Article

References (35)

1. Hajela S.P., Johnson A.R., Xu J., Sunderland C.J., Cohen S.M., Caulder D.L., Raymond K.N. Inorg. Chem. 40:2001;3208.
2. Cohen S.M., Meyer M., Raymond K.N. J. Am. Chem. Soc. 120:1997;6277.
3. Karpishin T.B., Stack T.D.B., Raymond K.N. J. Am. Chem. Soc. 115:1993;6115.
4. Rodgers S.J., Lee C.W., Ng C.Y., Raymond K.N. Inorg. Chem. 26:1987;1622.
5. Trofimenko S. J. Am. Chem. Soc. 88:1966;1842.
6. Trofimenko S. Scorpionates: The Coordination Chemistry of Polypyrazolylborate Ligands. 1999;Imperial College Press, London.
7. Alobaidi N., Jones C.J., McCleverty J.A. Polyhedron. 8:1989;1033.
8. Paulo A., Reddy K.R., Domingos A., Santos I. Inorg. Chem. 37:1998;6807.
9. Cano M., Heras J.V., Santamaria E., Pinilla E., Monge M., Gutierrez E., Jones C.J., McCleverty J.A. Polyhedron. 12:1993;1711.
10. Trofimenko S., Rheingold A.L., Liable Sands L.M. Inorg. Chem. 41:2002;1889.
11. (a) Adams H., Bailey N.A., Drane A.S., McCleverty J.A. Polyhedron. 2:1983;465.
12. (b) Hinton H.A., Chen H.L., Hamor T.A., Mcquillan F.S., Jones C.J. Inorg. Chim. Acta. 285:1999;55.
13. (c) Taqui Khan M.M., Roy P.S., Venkatasubramanian V., Khan N.H. Inorg. Chim. Acta. 176:1990;49.
14. (d) C.J. Jones, J.A. McCleverty, A.S. Rothin, J. Chem. Soc., Dalton Trans. (1986) 109.
15. (e) King R.B., Bond A. J. Am. Chem. Soc. 96:1974;1343.
16. (f) Guo S., Peters F., Fabrizi de Biani F., Bats J.W., Herdtweck E., Zanello P., Wagner M. Inorg. Chem. 40:2001;4928.
17. 3- according to the nomenclature for poly(pyrazolyl)borate ligands and their complexes proposed by S. Trofimenko in ref. [2b].
18. tBuB).
19. Trofimenko S., Calabrese J.C., Thompson J.S. Inorg. Chem. 26:1987;1507.
20. Srebnik M., Cole T.E., Ramachandran V., Brown H.C. J. Org. Chem. 54:1989;6085.
21. 0/+.
22. O. Graziani, Ph.D. Thesis, Université de Rennes 1, Rennes, 2001.
23. Gorrell I.B., Parkin G. Inorg. Chem. 29:1990;2452.
24. Ito M., Ainagai H., Fukui H., Kitajima N., Moro-oka Y. Bull. Chem. Soc. Jpn. 69:1996;1937.
25. D.F. Evans, J. Chem. Soc. (1959) 2003.
26. Schubert E.M. J. Chem. Educ. 69:1992;62.
27. -3.
28. Sheldrick G.M. SHELX 97. Program for the Refinement of Crystal Structures. 1997;University of Göttingen, Götingen, Germany.
29. A.J.C. Wilson (Ed.), International Tables for X-ray Crystallography, vol. C, Kluwer Academic Publishers, Dordrecht, 1992.
30. 2; (d) S.C. Davies, D.L. Hughes, G.J. Leigh, J.R. Sanders, J.S. Desouza, J. Chem. Soc., Dalton Trans. (1997) 1981.
31. 2; (d) S.C. Davies, D.L. Hughes, G.J. Leigh, J.R. Sanders, J.S. Desouza, J. Chem. Soc., Dalton Trans. (1997) 1981.
32. 2; (d) S.C. Davies, D.L. Hughes, G.J. Leigh, J.R. Sanders, J.S. Desouza, J. Chem. Soc., Dalton Trans. (1997) 1981.
33. 2; (d) S.C. Davies, D.L. Hughes, G.J. Leigh, J.R. Sanders, J.S. Desouza, J. Chem. Soc., Dalton Trans. (1997) 1981.
34. Simaan J., Poussereau S., Blondin G., Girerd J.J., Defaye D., Philouze C., Guilhem J., Tchertanov L. Inorg. Chim. Acta. 299:2000;221.
35. Christie S., Subramanian S., Wang L., Zaworotko M.J. Inorg. Chem. 32:1993;5415.