Glucosamine-based phosphines. Efficient ligands in the Suzuki cross-coupling reaction in water

Tetrahedron Letters

Volumn 43, Issue 41, 2002, Pages 7397-7400

  Parisot, Sophie ^a   Kolodziuk, Robert ^a   Goux Henry, Catherine ^a   Iourtchenko, Alexander ^a,b   Sinou, Denis ^a  

^a UNIVERSITÉ LYON 1   (France)

^b INSTITUTE OF ORGANIC CHEMISTRY   (Ukraine)

Author keywords

Carbohydrate; Recycling; Suzuki coupling; Water soluble

Indexed keywords

2 (DIPHENYLPHOSPHINO)BENZOIC ACID; 4 (DIPHENYLPHOSPHINO)BENZOIC ACID; BENZOIC ACID DERIVATIVE; GLUCOSAMINE DERIVATIVE; PHOSPHINE DERIVATIVE; UNCLASSIFIED DRUG; WATER;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION; COMPARATIVE STUDY; ELECTRON; RECYCLING; STRUCTURE ACTIVITY RELATION; SUZUKI REACTION;

LATEOLABRAX JAPONICUS;

EID: 0037037888     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(02)01749-5     Document Type: Article

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15. 4 and concentrated in vacuo. Purification of the crude product by flash-chromatography on silica gel gave the coupling product. In the case of the recycling experiments, the water/ethanol layer was transferred under argon into a second flask containing the aryl halide, the boronic acid and the base, in a mixture water/toluene.