Rheodielectric behavior of entangled cis-polyisoprene under fast shear

Macromolecules

Volumn 35, Issue 23, 2002, Pages 8802-8818

  Watanabe, H ^a   Ishida, S ^a   Matsumiya, Y ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CONVECTIVE CONSTRAINT RELEASE; DYNAMIC TUBE DILATION; NONEQUILIBRIUM CHAIN DYNAMICS; RHEODIELECTRIC RELAXATION TIME; RHEODIELECTRIC TESTS;

DIELECTRIC RELAXATION; MATERIALS TESTING; MOLECULAR DYNAMICS; RHEOLOGY; VISCOSITY;

POLYISOPRENES;

EID: 0037027612     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma020562y     Document Type: Article

References (46)

1. Ferry, J. D. Viscoelastic Properties of Polymers, 3rd ed; Wiley: New York, 1980.
2. Graessley, W. W. Adv. Polym. Sci. 1974, 16, 1.
3. Watanabe, H. Prog. Polym. Sci. 1999, 24, 1253.
4. Doi, M.; Edwards, S. F. The Theory of Polymer Dynamics; Clarendon: Oxford, England 1986.
5. Pearson, D. S.; Kiss, A. D.; Fetters, L. J., Doi, M. J. Rheol. 1989, 33, 517.
6. Pearson, D. S.; Herbolzheimer, E.; Grizzuti, N.; Marrucci, G. J. Polym. Sci., Part B: Polym. Phys. 1991, 29, 1589.
7. Marrucci, G. J. Non-Newtonian Fluid Mech. 1996, 62, 279.
8. Ianniruberto, G.; Marrucci, G. J. Non-Newtonian Fluid Mech. 1996, 65, 241.
9. Mead, D. W.; Larson, R. G.; Doi, M. Macromolecules 1998, 31, 7895.
10. Milner, S. T.; McLeish, T. C. B.; Likhtman, A. E. J. Rheol. 2001, 45, 539.
11. Stockmayer, W. H. Pure Appl. Chem. 1967, 15, 539.
12. Watanabe, H.; Matsumiya, Y.; Osaki, K. J. Polym. Sci., B: Polym. Phys. 2000, 38, 1024.
13. Matsumiya, Y.; Watanabe, H.; Osaki, K. Macromolecules 2000, 33, 499.
14. Matsumiya, Y.; Watanabe, H. Macromolecules 2001, 34, 5702.
15. Watanabe, H. Macromol. Rapid Commun. 2001, 22, 127.
16. Watanabe, H. Korea-Aust. Rheol. J. 2001, 13, 205.
17. Watanabe, H.; Matsumiya, Y.; Inoue, T. Macromolecules 2002, 35, 2339.
18. Marrucci, G. J. Polym. Sci., Polym. Phys. Ed. 1985, 23, 159.
19. Ball, R. C.; McLeish, T. C. B. Macromolecules 1989, 22, 1911.
20. Milner, S. T.; McLeish, T. C. B. Macromolecules 1997, 30, 2159,
21. ibid. 1998, 31, 7479.
22. Cole, R. H. J. Chem. Phys. 1965, 42, 637.
23. Riande, E.; Saiz, E. Dipole Moments and Birefringence of Polymers; Prentice Hall: Englewood Cliffs, NJ, 1992.
24. r)>/3.
25. o> does not contribute to Δε and φ(t).
26. Watanabe, H.; Urakawa, O,; Kotaka, T. Macromolecules 1993, 26, 5073.
27. Watanabe, H.; Sato, T.; Osaki, K. Macromolecules 1996, 29, 104.
28. Hayakawa, R.; Kanda, H.; Sakamoto, M.; Wada, Y. Jpn. J. Appl. Phys. 1975, 14, 2039.
29. Adachi, K.; Hirano, H. Macromolecules 1998, 31, 3958.
30. Sato, T.; Watanabe, H.; Osaki, K. Macromolecules 1996, 29, 6231.
31. Matsumiya, Y.; Watanabe, H.; Inoue, T.; Osaki, K.; Yao, M. L. Macromolecules 1998, 31, 7973.
32. Milner, S. T.; McLeish, T. C. B. Phys. Rev. Lett. 1998, 81, 725.
33. Takahashi, M.; Masuda, T.; Bessho, N.; Osaki, K. J. Rheol. 1980, 24, 517.
34. Osaki, K.; Kimura, S.; Kurata, M. J. Polym. Sci., Polym. Phys. Ed. 1981, 19, 517.
35. Magda, J. J.; Lee, C. S.; Muller, S. J.; Larson, R. G. Macromolecules 1993, 26, 1696.
36. Brown, E. F.; Burghardt, W. R.; Kahvand, H.; Venerus, D. C. Rheol. Acta 1995, 34, 221.
37. r for th rheodielectric measurements, the local motion of monomeric segments of the PI chains was too fast to be detected in our experimental window shown in Figures 8-11.
38. Muller. R.; Pesce, J. J.; Picot, C. Macromolecules 1993, 26, 4356.
39. Nagai, K. J. Phys. Soc. Jpn. 1958, 13, 928.
40. Hsiung, C.; Hsiung, H.; Gordus, A. J. Chem. Phys. 1964, 34, 535.
41. Yamakawa, H. Modern Theories of Polymer Solutions; Harper & Row: New York, 1971.
42. eq = 0).
43. Watanabe, H.; Kotaka, T. Macromolecules 1984, 17, 2316.
44. Struglinski, M. J.; Graessley, W. W. Macromolecules 1985, 18, 2630.
45. Viovy, J. L.; Rubinstein, M.; Colby, R. H. Macromolecules 1991, 24, 3587.
46. For example, the simplest extension of the Milner-McLeish-Likhtman model can be made in the following way. In this model, the time evolution is formulated for the isochronal orientation function (with s and s′ being the contour variables corresponding to n and n′ utilized in this study). The cross-correlation function can be calculated from the same time evolution equation except that the operations with respect to s′, included in the original equation are quenched.