Electron-withdrawing substituents decrease the electrophilicity of the carbonyl carbon. An investigation with the aid of 13C NMR chemical shifts, v(C=O) frequency values, charge densities, and isodesmic reactions to interprete substituent effects on reactivity

Journal of Organic Chemistry

Volumn 67, Issue 20, 2002, Pages 6995-7003

  Neuvonen, Helmi ^a   Neuvonen, Kari ^a   Koch, Andreas ^b   Kleinpeter, Erich ^b   Pasanen, Paavo ^a  

^a UNIVERSITY OF TURKU   (Finland)

^b UNIVERSITY OF POTSDAM   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTROPHILICITY;

CARBON; CARBOXYLIC ACIDS; ELECTRONS; ESTERS; NUCLEAR MAGNETIC RESONANCE; RESONANCE;

CHEMICAL REACTIONS;

CARBON; CARBONYL DERIVATIVE; ORGANIC COMPOUND; PHENYLACETIC ACID DERIVATIVE;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL REACTION; CHEMICAL STRUCTURE; ELECTRON; ENERGY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLARIZATION;

EID: 0037019992     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo020121c     Document Type: Article

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