Synthesis of α-acyl-functionalized azacycles by Pd-catalyzed cross-coupling reactions of α-alkoxyboronates with lactam-derived vinyl triflates

Journal of Organic Chemistry

Volumn 67, Issue 20, 2002, Pages 7144-7146

  Occhiato, Ernesto G ^a   Prandi, Cristina ^b   Ferrali, Alessandro ^a   Guarna, Antonio ^a   Deagostino, Annamaria ^c   Venturello, Paolo ^c  

^a UNIVERSITY OF FLORENCE   (Italy)

^b UNIVERSITY OF EASTERN PIEDMONT   (Italy)

^c UNIVERSITY OF TURIN   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

CROSS-COUPLING REACTIONS;

CATALYSTS; HYDROLYSIS; PALLADIUM; SYNTHESIS (CHEMICAL);

AROMATIC COMPOUNDS;

2,3,4,5 TETRAHYDROAZEPINE DERIVATIVE; 3,4 DIHYDRO (2H) PYRIDINE DERIVATIVE; 3,4,5,6,7,8 HEXAHYDRO (2H) CYCLOPENTA[B]AZEPIN 8 ONE; ALPHA ALKOXYBORONATE; BORONIC ACID DERIVATIVE; HETEROCYCLIC COMPOUND; HEXAHYDRO[1]PYRINDIN 7 ONE; LACTAM DERIVATIVE; LEAD; PYRIDINE DERIVATIVE; UNCLASSIFIED DRUG; VINYL DERIVATIVE; VINYL TRIFLATE DERIVATIVE;

ARTICLE; CATALYSIS; CHEMICAL MODIFICATION; CHEMICAL REACTION; CYCLIZATION; HYDROLYSIS; METHODOLOGY; REACTION ANALYSIS; SYNTHESIS;

EID: 0037019958     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo025930a     Document Type: Article

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33. 1H NMR analysis) was attributable to the corresponding cyclic carbamate, but this was not isolated.
34. -1.
35. 3N to the eluant.
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