Highly varying photophysical properties of thiocarbonyls: Validation of fundamental theoretical concepts of electronic radiationless transitions

Journal of Physical Chemistry A

Volumn 106, Issue 13, 2002, Pages 3072-3076

  Moule, David C ^a   Lim, Edward C ^b  

^a BROCK UNIVERSITY   (Canada)

^b UNIVERSITY OF AKRON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRONIC RADIATIONLESS TRANSITIONS;

ELECTRON ENERGY LEVELS; ELECTRON TRANSITIONS; FLUORESCENCE; PHOSPHORESCENCE;

ORGANIC COMPOUNDS;

EID: 0037018550     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp013929u     Document Type: Article

References (29)

1. Robinson, G.W. In Excited States; Lim, E.C., Ed.; Academic Press: New York, 1974; Vol. 1 and references therein.
2. See, for reviews: (a) Henry, B.R.; Siebrand, W. In Organic Molecular Photophysics; Birks, J.B., Ed.; Wiley-Interscience: London, 1973; Vol. 1, p 153.
3. (b) Freed, K.F. In Topics in Applied Physics; Fong, F.K., Ed.; Springer-Verlag: Berlin, 1976; Vol. 15, p 23.
4. Avouris, P.; Gelbart, W.M.; El-Sayed, M.A. Chem. Rev. 1977, 77, 793.
5. Bixon, M.; Jortner, J. J. Chem. Phys. 1968, 48, 715.
6. Lin, S.H.; Bersohn, R. J. Chem. Phys. 1968, 48, 2732.
7. Lin, S.H. J. Chem. Phys. 1966, 44, 3759.
8. Gardner, P.J.; Kasha, M. J. Chem. Phys. 1969, 50, 1543.
9. Clouthier, D.J.; Moule, D.C. Top. Curr. Chem. 1989, 150, 167.
10. El-Sayed, M.A. J. Chem. Phys. 1963, 38, 2834.
11. Moule, D.C.; Lim, E.C. J. Chem. Phys. 1999, 110, 9341.
12. Kim, T.-S.; Choi, Y.S. Bull. Korean Chem. Soc. 1996, 17, 745.
13. Moule, D.C.; Burling, I.R.; Liu, H.; Lim, E.C. J. Chem. Phys. 1999, 111, 5027.
14. Dunlop, J.R.; Karolczak, J.; Clouthier, D.J.; Ross, S.C. J. Phys. Chem. 1991, 95, 3045.
15. Dunlop, J.R.; Karolczak, J.; Clouthier, D.J.; Ross, S.C. J. Phys. Chem. 1991, 95, 3063.
16. Hackey, M.R.J.; Grein, F. J. Mol. Spectrosc. 1995, 172, 384.
17. Hackey, M.R.J.; Grein, F. J. Mol. Spectrosc. 1995, 197, 61.
18. Brand, J.C.D.; Callomon, J.H.; Moule, D.C.; Tyrell, J.; Goodwin, T. Trans. Faraday Soc. 1965, 61, 2365.
19. Moule, D.C.; Subramanian J. Mol. Spectrosc. 1973, 48, 336.
20. Judge, R.H.; Moule, D.C. J. Mol. Spectrosc. 1987, 122, 371.
21. Laane, J. J. Phys. Chem. A 2000, 104, 771.
22. Clouthier, D.J.; Kerr, C.M.L.; Ramsay, D.A. Chem. Phys. 1981, 56, 73.
23. Clouthier, D.J.; Kerr, C.M.L. Chem. Phys. 1982, 70, 55.
24. (a) Steer, R.P. Rev. Chem. Intermed. 1981, 4, 1.
25. (b) Maciejewski, A.; Steer, R.P. Chem. Rev. 1993, 93, 67 and references therein.
26. McDonald, J.R.; Brus, L.E. Chem. Phys. Lett. 1972, 16, 587.
27. Clouthier, D.J.; Moule, D.C. J. Mol. Spectrosc. 1981, 87, 471.
28. Clouthier, D.J. Private communication, 2001.
29. 2-CO displays a weak phosphorescence with quantum yield of ∼0.01 under the same experimental conditions. See: Lutz, A.C.; Maxon, V.T. Chem. Phys. Lett. 1974, 26, 553.