Pulse radiolysis study of absorption spectra of Ag0 and Ag2+ in water from room temperature up to 380 °C

Journal of Physical Chemistry A

Volumn 106, Issue 13, 2002, Pages 3123-3127

  Mostafavi, Mehran ^a   Lin, Mingzhang ^b   Wu, Guozhong ^b   Katsumura, Yosuke ^b   Muroya, Yusa ^b  

^a UNIVERSITÉ PARIS SUD   (France)

^b UNIVERSITY OF TOKYO   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

PULSE RADIOLYSIS;

ABSORPTION SPECTROSCOPY; ACTIVATION ENERGY; DIMERS; ELECTRONS; HYDRATION; POSITIVE IONS; PRESSURE EFFECTS; RADIOLYSIS; RATE CONSTANTS; REDUCTION; THERMAL EFFECTS;

SILVER;

EID: 0037018521     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp012853z     Document Type: Article

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31. According to a personal communication made by our colleague Dr. P. Archirel, the recent SCF calculations shows that the solvation of the external electron of silver atom is very improbable then the silver atom spectra in water does not present a real CTTS character. That could explain why we find that the shift of the absorption spectra versus temperature is not very important.