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Note
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3 (referenced to linear polystyrene standards) are similar to values reported using DMF. In cases where cyclic oligomer formation is substantial, the GPC-reported molecular weights and polydispersities are for the high polymer fraction. The outlying PDI value of entry 4 is likely due to the insolubility of poly(cycloctene) in DMF; thus, at low macromononomer incorporation, a collapsed conformation and artificially low PDI value of this polymer would not be surprising.
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Comparative studies show almost no formation of cyclic oligomers when cyclooctene is hompolymerized with I under identical conditions. Attempted homopolymerization of PEG-cyclooctene macromonomers 4 and 5 affords oligomers despite nearly complete macromonomer conversion. Future reports will detail these homopolymerization studies, including the more effective homopolymerization of 4 and 5 using II as the catalyst.
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