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Volumn 106, Issue 39, 2002, Pages 10074-10081

Time-resolved EPR study on reorganization energies for charge recombination processes in nanometer-separated radical ion pairs

Author keywords

[No Author keywords available]

Indexed keywords

AROMATIC COMPOUNDS; ELECTRONS; IONS; MOLECULES; PARAMAGNETIC RESONANCE; SOLVENTS;

EID: 0037015766     PISSN: 10895647     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp021119s     Document Type: Article
Times cited : (23)

References (68)
  • 35
    • 33947485310 scopus 로고
    • The electrochemical oxidations of the methoxybenzenes have been known to cause dimerization reactions in methanolic potassium hydroxide solution. Bellean, B.; Weinberg, N.L. J. Am. Chem. Soc. 1963, 85, 2525.
    • (1963) J. Am. Chem. Soc. , vol.85 , pp. 2525
    • Bellean, B.1    Weinberg, N.L.2
  • 47
    • 0011779762 scopus 로고    scopus 로고
    • note
    • s values is ∼0.01 eV in BuN and ∼0.02 eV in DMF under the temperature regions in this study.
  • 52
    • 0011772357 scopus 로고    scopus 로고
    • note
    • CT > 0 did not vary with temperature.
  • 55
    • 0011757112 scopus 로고    scopus 로고
    • note
    • s value is adequately small (<0.05 eV) between r = 1.2 and 1.3 nm in eq 3.
  • 56
    • 0011772609 scopus 로고    scopus 로고
    • note
    • D value was confirmed by a comparison with intramolecular reorganization energy for ionization of 1,4-diaza[2.2.2]bicyclooctane (DABCO) obtained with the difference between the vertical and adiabatic ionization potentials (see ref 32c).
  • 57
    • 0011714397 scopus 로고    scopus 로고
    • note
    • D values in the methoxynaplenes.
  • 63
    • 0011747506 scopus 로고    scopus 로고
    • note
    • .-. However, these quinone anion radicals do not show significant localization effects on the reorganization energies.
  • 65
    • 0011716066 scopus 로고    scopus 로고
    • note
    • 0 mixing is effectively created where the magnitude of the 2J is comparable to the hyperfine interaction.
  • 67
    • 0000684896 scopus 로고
    • Radical diffusion rates have been found to agree well with the Stokes-Einstein equation
    • Radical diffusion rates have been found to agree well with the Stokes-Einstein equation; see Terazima, M.; Okamoto, K.; Hirota, N. J. Chem. Phys. 1995, 102, 2506.
    • (1995) J. Chem. Phys. , vol.102 , pp. 2506
    • Terazima, M.1    Okamoto, K.2    Hirota, N.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.