Conversion of a Re(IV) tetrahedral cluster to.a Re(III) octahedral cluster: Synthesis of [(CH3)C(NH2)2]4 [Re6Se8(CN)6] by a solvothermal route

Inorganic Chemistry

Volumn 41, Issue 24, 2002, Pages 6170-6171

  Emirdag Eanes, Mehtap ^a   Ibers, James A ^a  

^a NORTHWESTERN UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACETONITRILE; AMMONIUM CHLORIDE; CARBON; NITROGEN; POTASSIUM DERIVATIVE; RHENIUM; SELENIUM DERIVATIVE; SOLVENT;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; HYDROGEN BOND; REACTION ANALYSIS; SOLVATION; SYNTHESIS; THERMAL ANALYSIS;

EID: 0037010954     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic020433y     Document Type: Article

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3. - for half occupancy of this third cation and thus with the charge of 4-on the anion.
4. 6] were recovered by suction filtration and washed with acetone. Yield of crystals was 0.007 g (50% based on Re). A second preparation afforded a yield of 40% based on Re. Examination of these crystals with an EDX-equipped Hitachi S-3500 SEM gave Re/Se = 3:4. The compound is stable in air.
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