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13 All buffers were 20 mM in each of MES, HEPES, and TAPS and contained 10-20 mM sodium acetate as additional supporting electrolyte.
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0010602919
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note
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Specifically, the midpoint potentials for the Fe(III/II), Mo(VI/V), and Mo-(V/IV) couples for the low pH Cl, inhibited form (and the high pH. uninhibited form) were reported as 90 mV (51 mV), 131 mV (-57 mV), and 86 mV (-233 mV), respectively, all versus the hydrogen electrode (ref 17)
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21
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0010534295
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note
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tot the calculated surface coverage, A is the area of the electrode surface, and n is the stoichiometric number of electrons passed.
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23
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0010604093
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note
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As found for the nonturnover experiments, the behavior is identical on both graphite and modified-gold surfaces, indicating that the electrochemistry is not influenced by surface effects.
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24
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0035892152
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