Unusual properties of the first copper complex containing a π(η2)-coordinated phosphorus-carbon double bond moiety

Chemical Communications

Volumn , Issue 17, 2002, Pages 1820-1821

  Gudat, Dietrich ^a   Nieger, Martin ^a   Schmitz, Katja ^a   Szarvas, Laslo ^a  

^a UNIVERSITY OF BONN   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON; COPPER COMPLEX; PHOSPHORUS;

ANALYTIC METHOD; ARTICLE; CALCULATION; CHEMICAL BOND; CHEMICAL INTERACTION; CRYSTAL STRUCTURE; GEOMETRY; PROTON NUCLEAR MAGNETIC RESONANCE; TEMPERATURE DEPENDENCE; X RAY DIFFRACTION;

EID: 0036970662     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/b204144h     Document Type: Article

References (27)

1. (a) Modern Organocopper Chemistry, ed. N. Krause, Wiley-VCH, Weinheim, 2002;
2. (b) G. van Koten, S. L. James and J. T. B. H. Jastrzebski, inComprehensive Organometallic Chemistry II, ed. E. W. Abel, F. G. A. Stone and G. Wilkinson, Pergamon, New York, 1995, vol 3, p. 57ff;
3. (c) M. P. Doyle, in ref. 1 (b), vol 12, p. 387ff.
4. (a) R. W. Turner and E. L. Amma, J. Am. Cem. Soc., 1966, 88, 1877;
5. (b) M. B. Dines and P. H. Bird, Chem. Commun., 1973, 12;
6. (c) H. Schmidbaur, W. Bublak, B. Huber, G. Reber and G. Müller, Angew. Chem., Int. Ed. Engl., 1986, 25, 1089;
7. (d) R. R. Conry and W. S. Striejewske, Chem. Commun., 1998, 555;
8. (e) Y. Shimazaki, H. Yokoyama and O. Yamauchi, Angew. Chem., Int. Ed., 1999, 38, 2401.
9. K. B. Dillon, F. Mathey and J. F. Nixon, Phosphorus: The Carbon Copy, Wiley & Sons, Chichester, 1998, pp. 88-127, 258-358 and references therein.
10. (a) S. Ito and M. Yoshifuji, Chem. Lett., 2000, 1390;
11. (b) S. Ito, K. Toyota and M. Yoshifuji, J. Organomet. Chem., 1998, 553, 135.
12. D. Gudat, S. Häp, L. Szarvas and M. Nieger, Chem. Commun., 2000, 1637.
13. (a) D. Gudat, M. Schrott and M. Nieger, J. Chem. Soc., Chem. Commun., 1995, 1541;
14. (b) D. Gudat, A. W. Holderberg, N. Korber, M. Nieger and M. Schrott, Z. Naturforsch., Teil B, 1999, 54, 1244.
15. Result of a quest in the CCSD database.
16. S. Häp, L. Szarvas, M. Nieger and D. Gudat, Eur. J. Inorg. Chem., 2001, 2763.
17. (a) D. Gudat, S. Häp and M. Nieger, Z. Anorg. Allg. Chem., 2001, 627, 2269;
18. (b) D. Gudat, S. Häp and M. Nieger, J. Organomet. Chem., 2002, 643, 181.
19. E. M. Menger and W. S. Veeman, J. Magn. Reson., 1982, 46, 257.
20. (a) S. Kroeker, J. V. Hanna, R. E. Wasylishen, E. W. Ainscough and A. M. Brodie, J. Magn. Res., 1998, 135, 208;
21. (b) J. H. Nelson, Conc. Magn. Reson., 2002, 14, 19.
22. Program WSolids1, K. Eichele and R. E. Wasylishen, Dalhousie Univ., Halifax, Canada; further details are given as ESI†.
23. A. H. Cowley, in, Phosphorus-31 NMR Spectroscopy in Stereochemical Analysis, ed. J. G. Verkade and L. D. Quin, VCH Publishers, Deerfield Beach, Fl, 1987, p. 621 and references therein.
24. All calculations were performed with Gaussian 98 (Rev. A.7), M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, M. A. Robb, J. R. Cheeseman, V. G. Zakrzewski, J. A. Montgomery, R. E. Stratmann, J. C. Burant, S. Dapprich, J. M. Millam, A. D. Daniels, K. N. Kudin, M. C. Strain, O. Farkas, J. Tomasi, V. Barone, M. Cossi, R. Cammi, B. Mennucci, C. Pomelli, C. Adamo, S. Clifford, J. Ochterski, G. A. Petersson, P. Y. Ayala, Q. Cui, K. Morokuma, D. K. Malick, A. D. Rabuck, K. Raghavachari, J. B. Foresman, J. Cioslowski, J. V. Ortiz, B. B. Stefanov, G. Liu, A. Liashenko, P. Piskorz, I. Komaromi, R. Gomperts, R. L. Martin, D. J. Fox, T. Keith, M. A. Al-Laham, C. Y. Peng, A. Nanayakkara, C. Gonzalez, M. Challacombe, P. M. W. Gill, B. G. Johnson, W. Chen, M. W. Wong, J. L. Andres, M. Head-Gordon, E. S. Replogle and J. A. Pople, Gaussian, Inc., Pittsburgh PA, 1998. Details on methods and basis sets are given as ESI†.
25. S. Dapprich and G. Frenking, J. Phys. Chem., 1995, 99, 9352.
26. (a) D. Gudat, W. Hoffbauer, E. Niecke, W. W. Schoeller, U. Fleischer and W. Kutzelnigg, Am. Chem. Soc., 1994, 116, 7325;
27. (b) N. Burford, T. S. Cameron, J. A. C. Clyburne, K. Eichele, K. N. Robertson, S. Sereda, R. E. Wasylishen and A. W. Whitla, Inorg. Chem., 1996, 35, 5460.