Adsorption of sulfur dioxide from pseudo binary mixtures on hydrophobic zeolites: Modeling of the breakthrough curves

Adsorption

Volumn 8, Issue 4, 2002, Pages 279-289

  Mello, Marcus ^a   Eić, Mladen ^a  

^a UNIVERSITY OF NEW BRUNSWICK   (Canada)

Author keywords

Adsorption; Breakthrough curves; Modeling; Roll up effect; SO2

Indexed keywords

BINARY MIXTURES; FINITE ELEMENT METHOD; HYDROPHOBICITY; MASS TRANSFER; MATHEMATICAL MODELS; SULFUR DIOXIDE; VAPORS; ZEOLITES;

HYDROPHOBIC ZEOLITES; MORDENITE; MULTILAYER ADSORPTION; ROLL UP EFFECT; WATER CONCENTRATION LEVEL;

ADSORPTION;

EID: 0036962081     PISSN: 09295607     EISSN: None     Source Type: Journal    
DOI: 10.1023/A:1021581312948     Document Type: Article

References (25)

1. Arumugam, B.K., J.F. Banks, and P.C. Wankat, "Pressure Effects in Adsorption Systems," Adsorption, 5, 261-278 (1999).
2. Chen, N.Y., "Hydrophobic Properties of Zeolites," J. Phys. Chem., 80(1), 60-63 (1976).
3. Chriswell, C.D. and D.T. Gjerde, "Sampling of Stack Gas for Sulfur Dioxide with a Molecular Sieve Adsorbent," Anal. Chem., 54, 1911-1913 (1982).
4. Do, D.D., Adsorption Analysis: Equilibria and Kinetics, ch. 6, Imperial College Press, London, 1998.
5. Dunn, J.P., Y. Cai, S. Liebmann, H.G. Stenger, Jr., and D.R. Simpson, "A Test and Demonstration Unit for Concentrating Sulfur Dioxide from Flue Gas," Ind. Eng. Chem. Res., 35, 1409-1416 (1996).
6. Edwards, M.F. and J.F. Richardson, "Gas Dispersion in Packed Beds," Chem. Eng. Sci., 23, 109-123 (1968).
7. Glueckauf, E. and J.E. Coates, "Theory of Chromatography, Part IV. The Influence of Incomplete Equilibrium on the Front Boundary of Chromatograms and on the Effectiveness of Separation," J. Chem. Soc., 1315-1321 (1947).
8. Gollakota, S.V. and C.D. Chriswell, "Study of an Adsorption Process Using Silicalite for Sulfur Dioxide Removal from Combustion Gases," Ind. Eng. Chem. Res., 27(1), 139-143 (1988).
9. Gregg, S.J. and K.S.W. Sing, Adsorption, Surface Area and Porosity, ch. 3, Academic Press, London, 1967.
10. 2 on Molecular Sieves Zeolites by Gas Chromatography," AIChE J., 18(6), 1148-1153 (1972).
11. 2 in Sodium Mordenite," AIChE J., 19(5), 1055-1059 (1973).
12. Ma, Y.H., R.J. Byron, P. Feltri, and T.Y. Lee, "Effects of Presorbed Water Vapor upon the Sorption and Diffusion of Sulfur Dioxide in Natural Mordenites," AIChE Symp. Ser., 74(179), 48-52 (1978).
13. Mello, M., "Adsorption of Sulphur Dioxide from Multicomponent Mixtures on Hydrophobic Zeolites," Ph.D. Thesis, University of New Brunswick, Canada, 2000.
14. Mello, M., M. Eić, S. Hočevar, and U. Lavrenčič-Štangar, "Modeling of Sulfur Dioxide Breakthrough Curves from Ternary Wet Mixtures on MOR Type Zeolite," Stu. Surf. Sci. Cat. 135
15. Mello, M., M. Eić, S. Hočevar, and U. Lavrencǐič-Štangar, "Modeling of Sulfur Dioxide Breakthrough Curves from Ternary Wet Mixtures on MOR Type Zeolite," Zeolites and Mesoporous Materials at the Dawn of the 21st Century, A. Galarneau, F. DiRenzo, F. Fajula, and J. Vedrine (Eds.), CD-ROM, Elsevier, Amsterdam, 2001.
16. Nakamoto, H. and H. Takahashi, "Hydrophobic Natures of Zeolite ZSM-5," Zeolites, 2, 67-69 (1982).
17. 2 from Wet Mixtures on Hydrophobic Zeolites," Adsorption, 4, 25-33 (1998).
18. Roux, A., A.A. Huang, Y.H. Ma, and I. Zwiebel, "Sulfur Dioxide Adsorption on Mordenites," AIChE Symp. Ser., 69(134), 46-53 (1973).
19. Ruthven D.M., Principles of Adsorption and Adsorption Processes, ch. 8, John Wiley & Sons, New York, 1984.
20. Ruthven D.M., Microporous Materials, 22, 537-541 (1998).
21. Sing, K.S.W., "Analysis of Physisorption Isotherms," in Physical Adsorption: Experiment, Theory and Applications, J. Fraissard (Ed.), pp. 9-16, Kluwer Academic Publishers, Netherlands, 1997.
22. Sing, K.S.W., D.H. Everett, R.A.W. Haul, L. Moscou, R.A. Pierotti, J. Rouquerol, and T. Siemienewska, "Reporting Physisorption Data for Gas/Solid Systems-with Special Reference to the Determination of Surface Area and Porosity," Pure Appl. Chem., 57(4), 603-619 (1985).
23. 2O onto Mordenite Synthesized from Perlite," Gas Sep. and Purif., 7(1), 19-25 (1993a).
24. Stenger Jr., H.G., K. Hu, and D. Simpson, "Chromatographic Separation and Concentration of Sulfur Dioxide in Flue Gases," Ind. Eng. Chem. Res., 32(11), 2736-2739 (1993b).
25. Tantet, J., M. Eić, and R. Desai, "Breakthrough Study of the Adsorption and Separation of Sulfur Dioxide from Wet Gas Using Hydrophobic Zeolites," Gas Sep. and Purif., 9(3), 213-220 (1995).