Origin of the anodic overvoltage observed during fluorine evolution in KF-2HF

Journal of the Electrochemical Society

Volumn 149, Issue 12, 2002, Pages

  Groult, H ^a   Devilliers, D ^a   Lantelme, F ^a   Caire, J P ^b   Combel, M ^c   Nicolas, F ^c  

^a SORBONNE UNIVERSITÉ   (France)

^b Grenoble INP Phelma   (France)

^c Service RandD   (France)

Author keywords

[No Author keywords available]

Indexed keywords

CALCULATIONS; ELECTROCHEMICAL ELECTRODES; ELECTROLYSIS; FLUORINE; INTERFACES (MATERIALS); POTASSIUM COMPOUNDS; REACTION KINETICS; SOLID ELECTROLYTES; SURFACE PHENOMENA; THRESHOLD VOLTAGE;

ANODIC OVERVOLTAGE; ELECTRODE ELECTROLYTE INTERFACE; ELECTRODE GEOMETRY; FLUORINE EVOLUTION REACTION; SURFACE CARBON FLUORINE FILMS;

ANODES;

EID: 0036959222     PISSN: 00134651     EISSN: None     Source Type: Journal    
DOI: 10.1149/1.1516776     Document Type: Article

References (26)

1. H. Groult and F. Lantelme, J. Electrochem. Soc., 148, E13 (2001).
2. P. J. Sides, in Modern Aspects of Electrochemistry, Vol. 18, R. E. White, B. Conway, and J. O'M. Bockris, Editors. p. 303. Plenum Publishing Corp., New York (1986).
3. L. J. J. Janssen and J. G. Hoogland, Electrochim. Acta, 15, 1013 (1970).
4. A. T. Kuhn and M. Stevenson, Electrochim. Acta, 27, 329 (1982).
5. H. Roustan J.-P. Caire, F. Nicolas, and P. Pham, J. Appl. Electrochem., 28, 237 (1998).
6. J. Eigeldinger and H. Vogt, Electrochim. Acta, 45, 4449 (2000).
7. H. Vogt, in Comprehensive Treatise of Electrochemistry, Vol. 6, E. Yeager, J. O'M. Bockris, and B. E. Conway, Editors, p. 455, Plenum Publishing Corp., New York (1983).
8. J. Barber, S. Morin, and B. E. Conway. J. Electroanal. Chem., 446, 125 (1998).
9. F. Lantelme, H. Alexopoulos, and O. Haas, J. Appl. Electrochem., 23, 717 (1978).
10. O. R. Brown, B. M. Ikeda, and M. J. Wilmott, Electrochim. Acta, 32, 1163 (1987).
11. L. Bai and B. E. Conway, J. Appl. Electrochem., 20, 916 (1990).
12. P. T. Hough, in Electrochemistry in the Preparation of Fluorine and Its Compounds, W. V. Childs and T. Fuchigami, Editors, PV 97-15, p. 113, The Electro-chemical Society Proceedings Series, Pennington, NJ (1997).
13. W. V. Childs and G. L. Bauer, J. Electrochem. Soc., 142, 2286 (1995).
14. N. Watanabe, T. Nakajima, and H. Touhara, Graphite Fluorides, Vol. 8, Elsevier, Amsterdam (1988).
15. H. Groult, D. Devilliers, and M. Vogler, in Current Topics in Electrochemistry, Vol. 4, p. 23, Research trends, Poojupura, Trivandrum, India (1997).
16. H. Groult, D. Devilliers, M. Vogler, C. Hinnen, P. Marcus, and F. Nicolas, Electrochim. Acta, 38, 2413 (1993).
17. H. Groult, D. Devilliers, S. Durand-Vidal, F. Nicolas, and M. Combel, Electrochim. Acta, 44, 2793 (1999).
18. T. Nakajima, T. Ogawa, and N. Watanabe, J. Electrochem. Soc., 134, 8 (1987).
19. D. Devilliers, B. Teysseyre, and M. Chemla, Electrochim. Acta, 35, 153 (1990).
20. P. T. Hough and D. M. Novak-Antoniou, U.S. Pat. 4, 602, 985 (1986).
21. N. Watanabe, M. Inoue, and S. Yoshizawa, Denki Kagaku oyobi Kogyo Butsuri Kagaku, 31, 698 (1963).
22. T. Tojo, Y.-B. Chong, and N. Watanabe, in Proceedings 12th International Symposium on Fluorine Chemistry, Abstract no. 408, Santa Cruz, CA (1988).
23. T. Tojo, J. Hiraiwa, M. Dohi, Y.-B. Chong, and N. Watanabe, J. Fluorine Chem., 54, 136 (1991).
24. Asahi Glass Co., JP-Kokai Pat. 58 81 981 (1983).
25. O. R. Brown and M. J. Witmott, Eur. Pat. 255 225 (1988).
26. H. Roustan, Ph.D. Thesis, ENSEEG-INPG, Saint Martin d'Hères, Grenoble, France (1998).