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+ and PEO chains may form (see F.E. Bailey jr., J.V. Koleske, Poly (ethylene glycol) (Academic Press, New York, 1976)) and change the conformation of the chains. Hydrogen bonds may form between the oxygen atoms of the PEO and the hydrogen atoms of the water molecules (M. Ide, D. Yoshikawa, Y. Maeda, H. Kitano, Langmuir 15, 926 (1999); S.R. Sheth, D. Leckband, Proc. Natl. Acad. Sci. USA 94, 8399 (1997)).
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+ and PEO chains may form (see F.E. Bailey jr., J.V. Koleske, Poly (ethylene glycol) (Academic Press, New York, 1976)) and change the conformation of the chains. Hydrogen bonds may form between the oxygen atoms of the PEO and the hydrogen atoms of the water molecules (M. Ide, D. Yoshikawa, Y. Maeda, H. Kitano, Langmuir 15, 926 (1999); S.R. Sheth, D. Leckband, Proc. Natl. Acad. Sci. USA 94, 8399 (1997)).
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+ and PEO chains may form (see F.E. Bailey jr., J.V. Koleske, Poly (ethylene glycol) (Academic Press, New York, 1976)) and change the conformation of the chains. Hydrogen bonds may form between the oxygen atoms of the PEO and the hydrogen atoms of the water molecules (M. Ide, D. Yoshikawa, Y. Maeda, H. Kitano, Langmuir 15, 926 (1999); S.R. Sheth, D. Leckband, Proc. Natl. Acad. Sci. USA 94, 8399 (1997)).
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0030831255
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+ and PEO chains may form (see F.E. Bailey jr., J.V. Koleske, Poly (ethylene glycol) (Academic Press, New York, 1976)) and change the conformation of the chains. Hydrogen bonds may form between the oxygen atoms of the PEO and the hydrogen atoms of the water molecules (M. Ide, D. Yoshikawa, Y. Maeda, H. Kitano, Langmuir 15, 926 (1999); S.R. Sheth, D. Leckband, Proc. Natl. Acad. Sci. USA 94, 8399 (1997)).
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0 = 2.6 ± 0.6 nm would correspond to volume fraction of roughly 0.6. Similar if slightly lower values (0.5 ± 0.1) apply for the other samples, see Table 1. At these concentrations excluded-volume effects are negligible (P.G. de Gennes, Scaling Concepts in Polymer Physics, Cornell University Press, Ithaca, N.Y., 1979) and a Gaussian random walk is a good approximation.
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32
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0012482506
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note
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2 < 2h we get α = 0.86 ± 0.14 nm.
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33
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0012543356
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note
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Note that we use scaling exponents, though at the highest concentration of the strong compressed layers mean-field exponents, might better apply. This is not expected to change our results qualitatively.
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34
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0012590106
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private communication
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Toluene behaves as a good solvent under our experimental conditions [15,16], though differing solvation properties have been reported under other conditions (N.P. Balsara, private communication).
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Balsara, N.P.1
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