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Volumn 9, Issue 5, 2002, Pages 405-412

The polymer mat: Arrested rebound of a compressed polymer layer

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EID: 0036954887     PISSN: 12928941     EISSN: None     Source Type: Journal    
DOI: 10.1140/epje/i2002-10053-9     Document Type: Article
Times cited : (21)

References (42)
  • 19
    • 0003472957 scopus 로고
    • Plenum Press, New York
    • + and PEO chains may form (see F.E. Bailey jr., J.V. Koleske, Poly (ethylene glycol) (Academic Press, New York, 1976)) and change the conformation of the chains. Hydrogen bonds may form between the oxygen atoms of the PEO and the hydrogen atoms of the water molecules (M. Ide, D. Yoshikawa, Y. Maeda, H. Kitano, Langmuir 15, 926 (1999); S.R. Sheth, D. Leckband, Proc. Natl. Acad. Sci. USA 94, 8399 (1997)).
    • (1992) Poly (Ethylene Glycol) Chemistry: Biotechnical and Biomedical Application
    • Harris, J.M.1
  • 20
    • 0003518670 scopus 로고
    • Academic Press, New York
    • + and PEO chains may form (see F.E. Bailey jr., J.V. Koleske, Poly (ethylene glycol) (Academic Press, New York, 1976)) and change the conformation of the chains. Hydrogen bonds may form between the oxygen atoms of the PEO and the hydrogen atoms of the water molecules (M. Ide, D. Yoshikawa, Y. Maeda, H. Kitano, Langmuir 15, 926 (1999); S.R. Sheth, D. Leckband, Proc. Natl. Acad. Sci. USA 94, 8399 (1997)).
    • (1976) Poly (Ethylene Glycol)
    • Bailey F.E., Jr.1    Koleske, J.V.2
  • 21
    • 0033075858 scopus 로고    scopus 로고
    • + and PEO chains may form (see F.E. Bailey jr., J.V. Koleske, Poly (ethylene glycol) (Academic Press, New York, 1976)) and change the conformation of the chains. Hydrogen bonds may form between the oxygen atoms of the PEO and the hydrogen atoms of the water molecules (M. Ide, D. Yoshikawa, Y. Maeda, H. Kitano, Langmuir 15, 926 (1999); S.R. Sheth, D. Leckband, Proc. Natl. Acad. Sci. USA 94, 8399 (1997)).
    • (1999) Langmuir , vol.15 , pp. 926
    • Ide, M.1    Yoshikawa, D.2    Maeda, Y.3    Kitano, H.4
  • 22
    • 0030831255 scopus 로고    scopus 로고
    • + and PEO chains may form (see F.E. Bailey jr., J.V. Koleske, Poly (ethylene glycol) (Academic Press, New York, 1976)) and change the conformation of the chains. Hydrogen bonds may form between the oxygen atoms of the PEO and the hydrogen atoms of the water molecules (M. Ide, D. Yoshikawa, Y. Maeda, H. Kitano, Langmuir 15, 926 (1999); S.R. Sheth, D. Leckband, Proc. Natl. Acad. Sci. USA 94, 8399 (1997)).
    • (1997) Proc. Natl. Acad. Sci. USA , vol.94 , pp. 8399
    • Sheth, S.R.1    Leckband, D.2
  • 29
    • 0003544037 scopus 로고
    • Cornell University Press, Ithaca, N.Y.
    • 0 = 2.6 ± 0.6 nm would correspond to volume fraction of roughly 0.6. Similar if slightly lower values (0.5 ± 0.1) apply for the other samples, see Table 1. At these concentrations excluded-volume effects are negligible (P.G. de Gennes, Scaling Concepts in Polymer Physics, Cornell University Press, Ithaca, N.Y., 1979) and a Gaussian random walk is a good approximation.
    • (1979) Scaling Concepts in Polymer Physics
    • De Gennes, P.G.1
  • 32
    • 0012482506 scopus 로고    scopus 로고
    • note
    • 2 < 2h we get α = 0.86 ± 0.14 nm.
  • 33
    • 0012543356 scopus 로고    scopus 로고
    • note
    • Note that we use scaling exponents, though at the highest concentration of the strong compressed layers mean-field exponents, might better apply. This is not expected to change our results qualitatively.
  • 34
    • 0012590106 scopus 로고    scopus 로고
    • private communication
    • Toluene behaves as a good solvent under our experimental conditions [15,16], though differing solvation properties have been reported under other conditions (N.P. Balsara, private communication).
    • Balsara, N.P.1


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