Raman spectra of carbonaceous material in metasediments: A new geothermometer

Journal of Metamorphic Geology

Volumn 20, Issue 9, 2002, Pages 859-871

  Beyssac, O ^a   Goffe B ^a   Chopin, C ^a   Rouzaud, J N ^b  

^a ECOLE NORMALE SUPÉRIEURE   (France)

^b UNIVERSITÉ D'ORLÉANS   (France)

Author keywords

Carbonaceous material; Geothermometer; Graphitization; Irreversible transformation; Raman microspectroscopy; Regional metamorphism

Indexed keywords

CARBON; GEOTHERMOMETRY; GRAPHITIZATION; METASEDIMENT; P-T CONDITIONS; PETROLOGY; RAMAN SPECTROSCOPY; REGIONAL METAMORPHISM;

EID: 0036911771     PISSN: 02634929     EISSN: None     Source Type: Journal    
DOI: 10.1046/j.1525-1314.2002.00408.x     Document Type: Article

References (58)

1. Agard, P., Jolivet, L., & Goffé, B., 2001a. Tectonometamorphic evolution of the Schistes lustrés complex: implications for the exhumation of HP and UHP rocks in the western Alps. Bulletin de la Société Géologique de France, 172, 617-636.
2. Agard, P., Vidal, O. & Goffé, B., 2001b. Interlayer and Si content of phengite in HP-LT carpholite-bearing metapelites. Journal of Metamorphic Geology, 19, 479-496.
3. Azanon, J. M., 1994. Metamorfismo de alta presion/baja temperatura, baja presion/alta temperature y tectonica del complejo Alpujarride (Cordilleras Betico-Rifenas). PhD Thesis, University of Granada, Granada.
4. Banno, S., Sakai, C. & Higashino, T., 1986. Pressure-temperature trajectory of the Sanbagawa metamorphism deduced from garnet zoning. Lithos, 19, 51-63.
5. Bény-Bassez, C. & Rouzaud, J. N., 1985. Characterization of carbonaceous materials by correlated electron and optical microscopy and Raman microspectroscopy. In: Scanning Electron Microscopy, p. 119-132, SEM Inc, Chicago.
6. Beyssac, O., Rouzaud, J. N., Brunet, F., Petitet, J. P. & Goffé, B., 2000. Pressure effects on graphitization: experimental constraints. Journal of Conference Abstracts, 5, 13.
7. Beyssac, O., Rouzaud, J. N., Goffé, B., Brunet, F. & Chopin, C., 2002. Characterization of high-pressure, low-temperature graphitization: a Raman microspectroscopy and HRTEM study. Contributions to Mineralogy and Petrology, 143, 19-31.
8. Bonijoly, M., Oberlin, M., & Oberlin, A., 1982. A possible mechanism for natural graphite formation. International Journal of Coal Geology, 1, 283-312.
9. Borghi, A., Cadoppi, P., Porro, A, & Sacchi, R., 1985. Metamorphism in the northern part of the Dora Maira massif (Cottian Alps). Bollettino Del Museo Regionale Di Scienze Naturali, Torino, 3, 369-380.
10. Borghi, A., Compagnoni, R. & Sandrone, R., 1986. Composite P-T paths in the Internal Penninic Massifs of the Western Alps: Petrological constraints to their thermo-mechanical evolution. Eclogae Geologicae Helvetiae, 89, 345-367.
11. Bouybaouene, M., Michard, A. & Goffé, B., 1998. High-Pressure granulites on top of the Beni Bousera peridotites, Morocco: a record of an ancient thickened crust in the Alboran domain. Bulletin de la Société Geologique de France, 169, 153-162.
12. Buseck, P. R. & Huang, B.-J., 1985. Conversion of carbonaceous material to graphite during metamorphism. Geochimica et Cosmochimica Acta, 49, 2003-2016.
13. Cesare, B. & Maineri, C., 1999. Fluid-present anatexis of metapelites at El Joyazo (SE Spain): constraints from Raman spectroscopy of graphite. Contributions to Mineralogy and Petrology, 135, 41-52.
14. Chopin, C., Henry, C. & Michard, A., 1991. Geology and petrology of the coesite-bearing terrain. Dora-Maira massif, Western Alps. European Journal of Mineralogy, 3, 263-291.
15. Compagnini, G., Puglisi, O. & Foti, G., 1997. Raman spectra of virgin and damaged edge planes. Carbon, 35, 1793-1797.
16. Compagnoni, R., Hirajima, T. & Chopin, C., 1995. Ultrahigh-pressure metamorphism in the western Alps. In; Ultra-High- Pressure Metamorphism (eds R. G. Coleman & X. Wang), pp. 206-243. Cambridge University Press, Cambridge.
17. Deurbergue, A., Oberlin, A., Oh, J. H. & Rouzaud, J. N., 1987. Graphitization of Korean Anthracites as studied by Transmission Electron Microscopy and X-Ray Diffraction. International Journal of Coal Geology, 8, 375-393.
18. Diessel, C. F. K., Brothers, N. R. & Black, P. M., 1978. Coalification and Graphitization in high-pressure schists in New Caledonia. Contributions to Mineralogy and Petrology, 68, 63-78.
19. Duber, S., Pusz, S., Kwiecinska, B. K. & Rouzaud, J. N., 2000. On the optical biaxial character and heterogeneity of anthracites. International Journal of Coal Geology, 44, 227-250.
20. Dunn, S. R. & Valley, J. W., 1992. Calcite-graphite isotope thermometry: a test for polymetamorphism in marble. Tudor gabbro aureole, Ontario, Canada. Journal of Metamorphic Geology, 10, 487-501.
21. Enami, M., 1983. Petrology of pelitic schists in the oligoclase- biotite zone of the Sanbagawa metamorphic terrain, Japan: phase equilibria in the highest grade zone of a high-pressure intermediate type of metamorphic belt. Journal of Metamorphic Geology, 1, 141-161.
22. Enami, M., Wallis, S.R. & Banno, Y., 1994. Paragenesis of sodic pyroxene-bearing quartz schists: implications for the P-T history of the Sanbagawa belt. Contributions to Mineralogy and Petrology, 116, 182-198.
23. Everall, N.J., Lumsdon, J. & Christopher, D.J., 1991. The effect of laser-induced heating upon the vibrational Raman spectra of graphites and carbon fibres. Carbon, 29, 133-137.
24. Faure, M., 1985. Microtectonic evidence for eastward ductile shear in the Jurassic orogen of SW Japan. Journal of Metamorphic Geology, 7, 175-186.
25. Frey, M., Bucher, K., Frank, E. & Mullis, J., 1980. Alpine metamorphism along the GeoTraverse Basel-Chiasso-a review. Eclogae Geologicae Helvetiae, 73, 527-546.
26. Grew, E. S., 1974. Carbonaceous material in some metamorphic rocks of New England and other areas. Journal of Geology. 82, 50-73.
27. Itaya, T., 1981. Carbonaceous material in pelitic schists of the Sanbagawa metamorphic belt in central Shikoku, Japan. Lithos, 14, 215-224.
28. Jehlicka, J. & Bény, C., 1992. Application of Raman microspectrometry in the study of structural changes in Precambrian kerogens during regional metamorphism. Organic Geochemistry, 2, 211-213.
29. Jehlicka, J. & Rouzaud, J. N., 1989. Organic geochemistry of precambrian shales and schists (Bohemian massif. Central Europe). Advances in Organic Geochemistry, 16, 865-872.
30. Jolivet, L., Beyssac, O., Goffe, B., Avigad, D., Lepvrier, C., Maluski, H. & Thang, T. T., 2001. Oligo-Miocene midcrustal subhorizontal shear zone in Indochina. Tectonics, 20, 46-57.
31. Kagi, H., Tsuchida, I., Wakatsuki, M., Takahashi, K., Kamimura, N., Iuchi, K. & Wada, H., 1994. Proper understanding of down-shifted Raman spectra of natural graphite: Direct estimation of laser-induced rise in sample temperature. Geochimica et Cosmochimica Acta, 58, 3527-3530.
32. Kovalevski, V. V., Buseck, P. R. & Cowley, J. M., 2001: Comparison of carbon in shungite rocks to other natural carbons: An X-ray and TEM study. Carbon, 39, 243-256.
33. Kribek, B., Hrabal, J., Landais, P. & Hladikova, J., 1994. The association of poorly ordered graphite, coke and bitumens in greenschist facies rocks of the Ponickla Group, Lugicum, Czech Republic: the results of graphitization of various types of carbonaceous matter. Journal of Metamorphic Geology, 12, 493-503.
34. Landis, C. A., 1971. Graphitization of dispersed carbonaceous materials in metamorphic rocks. Contributions to Mineralogy and Petrology, 30, 34-45.
35. Large, D. J., Christy, A. G. & Fallick, A. E., 1994. Poorly crystalline carbonaceous matter in high grade metasediments: implications of graphitization and metamorphic fluids compositions. Contributions to Mineralogy and Petrology, 116, 108-116.
36. Lespade, P., Marchand, A., Couzi, M. & Cruege, F., 1984. Caractérisation de matériaux carbonés par microspectroscopie Raman. Carbon, 22, 375-385.
37. Lugue, F. J., Pasteris, J. D., Wopenka, B., Rodas, M. & Barrenechea, J. F., 1998. Natural fluid deposited graphite: mineralogical characteristics and mechanisms of formation. American Journal of Science, 298, 471-498.
38. Mostefaoui, S., Perron, C., Zinner, E. & Sagon, G., 2000. Metal-associated carbon in primitive chondrites: Structure, isotopic composition and origin. Geochimica et Cosmochimica Acta, 64, 1945-1964.
39. Nemanich, R. J. & Solin, S. A., 1979. First- and second-order Raman scattering from finite-size crystals of graphite. Physical Review B, 20, 392-401.
40. Nishimura, Y., Coombs, D. S., Landis, C. A. & Itaya, T., 2000. Continuous metamorphic gradient documented by graphitization and K-Ar age, southeast Otago, New Zealand. American Mineralogist, 84, 1625-1636.
41. Okuyama-Kusunose, Y., & Itaya, T., 1987. Metamorphism of carbonaceous material in the Tono contact aureole, Kitakami Mountains, Japan. Journal of Metamorphic Geology, 5, 121-139.
42. Parra, T., Vidal, O. & Jolivet, L., 2002. P-T path of high-pressure, low-temperature schists on Tinos Island (Cyclades Archipelago, Greece) using chlorite-potassic white mica pairs. Lithos, 63, 41-66.
43. Pasteris, J. D., 1989. In situ analysis in geological thin-sections by Laser Raman micropobe microspectroscopy: a cautionary note. Applied Spectroscopy, 43, 567-570.
44. Pasteris, J. D. & Wopenka, B., 1991. Raman spectra of graphite as indicators of degree of metamorphism. Canadian Mineralogist, 29, 1-9.
45. Patriat, M. & Jolivet, L., 1998. Post-orogenic extension and shallow-dipping shear zones, study of a brecciated decollement horizon in Tinos (Cyclades, Greece). Comptes Rendus de l'Académie Des Sciences. Paris, 326, 355-362.
46. Pearson, D. G., Boyd, F. R., Haggerty, S. E., Pasteris, J. D., Field, S. W., Nixon, P. H. & Pokhilenko, N. P., 1994. The characterisation and origin of graphite in cratonic lithospheric mantle: a petrological carbon isotope and Raman spectroscopy study. Contributions to Mineralogy and Petrology, 115, 449-466.
47. Rietmeijer, F. J. M. & Mackinnon, I. D. R., 1985. Poorly graphitized carbon as a new cosmothermometer for primitive extraterrestrial materials. Nature, 316, 733-736.
48. Saliot, P., 1973. Les principales zones de métamorphisme dans les Alpes françaises. répartition et signification. Comptes rendus de l'Académié des Sciences. Paris, 276, 3081-3084.
49. Todd, C.S. & Engi, M., 1997. Metamorphic field gradients in the Central Alps. Journal of Metamorphic Geology, 15, 513-530.
50. Trotet, F., 2000. Exhumation des roches de Haute Pression - Basse Temperature le long d'un transect des Cyclades au Péloponnèse (Grèce): implications géodynamiques. PhD Thesis, Université Paris 11. Paris.
51. Tsu, R., Gonzales, H. & Hernandez, I., 1978. Observation of splitting of the E2g mode and two-phonon spectrum in graphites. Solid State Communications, 27, 507-510.
52. Tuinstra, F. & Koenig, J. L., 1970. Raman spectrum of graphite. Journal of Chemical Physics, 53, 1126-1130.
53. Vidal, O., Parra, T. & Trotet, F., 2001. A thermodynamic model for Fc-Mg aluminous chlorite using data from phase equilibrium experiments and natural pelitic assemblages in the 100-600 °C, 1-25 kbar P-T range. American Journal of Science, 301, 557-592.
54. Wada, H., Tomita, T., Matsuura, K., Iuchi, K., Ito, M. & Morikiyo, T., 1994. Graphitization of carbonaceous matter during metamorphism with references to carbonate and pelitic rocks of contact and regional metamorphisms. Japan. Contributions to Mineralogy and Petrology, 118, 217-228.
55. Wang. A., Dhamelincourt, P., Dubessy, J., Guerard, D., Landais, P. & Lelaurain, M., 1989. Characterization of graphite alteration in an uranium deposit by micro-Raman spectroscopy, X-RAY diffraction. Transmission Electron Microscopy and Scanning Electron Microscopy. Carbon. 27, 209-218.
56. Wopenka, B. & Pasteris, J. D., 1993. Structural characterization of kerogens to granulite-facies graphite: Applicability of Raman microprobe spectroscopy. American Mineralogist, 78, 533-557.
57. Yiu, T.-F., Huang, E. & Xu, J., 1996. Raman spectrum of carbonaceous material: a possible metamorphic grade indicator for low-grade metamorphic rocks. Journal of Metamorphic Geology, 14, 115-124.
58. Zinner, E., Amari, S., Wopenka, B. & Lewis, R. S., 1995. Interstellar graphite in meteorites: Isotopic compositions and structural properties of single graphite grains from Murchison. Meteoritics, 30, 209-226.