Role of structure and pH in cyclization of allene oxide fatty acids: Implications for the reaction mechanism

Chemistry and Physics of Lipids

Volumn 120, Issue 1-2, 2002, Pages 87-99

  Grechkin, Alexander N ^a   Chechetkin, Ivan R ^a   Mukhtarova, Lucia S ^a   Hamberg, Mats ^b  

^a KAZAN INSTITUTE OF BIOCHEMISTRY AND BIOPHYSICS   (Russian Federation)

^b KAROLINSKA INSTITUTE   (Sweden)

Author keywords

Allene oxide synthase; Cyclization mechanism; Cyclopentenone formation; Fatty acid allene oxides; Oxylipins

Indexed keywords

ALLENE DERIVATIVE; CATION; CYCLOPENTANONE DERIVATIVE; FATTY ACID DERIVATIVE; HYDROPEROXIDE DERIVATIVE; LINOLEIC ACID; OXIDE; CYCLOPENTANE DERIVATIVE; CYCLOPENTENONE; FATTY ACID; HYDROPEROXIDE ISOMERASE; ISOMERASE; PEROXIDE;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION KINETICS; CYCLIZATION; FATTY ACID ANALYSIS; GEOMETRY; ISOMER; MAIZE; MOLECULAR DYNAMICS; PH; PRIORITY JOURNAL; STRUCTURE ANALYSIS; SUBSTITUTION REACTION; CHEMICAL STRUCTURE; CHEMISTRY; ENZYMOLOGY; FLAX; METABOLISM; STEREOISOMERISM;

LINUM USITATISSIMUM; ZEA MAYS;

CYCLIZATION; CYCLOPENTANES; FATTY ACIDS; FLAX; HYDROGEN-ION CONCENTRATION; INTRAMOLECULAR OXIDOREDUCTASES; LINOLEIC ACID; MOLECULAR STRUCTURE; PEROXIDES; STEREOISOMERISM; ZEA MAYS;

EID: 0036890380     PISSN: 00093084     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0009-3084(02)00107-X     Document Type: Article

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