Structures and transport properties of new molecular conductors based on TMEO-ST-TTP

Journal of Solid State Chemistry

Volumn 168, Issue 2, 2002, Pages 608-615

  Misaki, Yohji ^a   Taniguchi, Masateru ^a   Tanaka, Kazuyoshi ^a   Takimiya, Kazuo ^b   Morikami, Atsushi ^b   Otsubo, Tetsuo ^b   Mori, Takehiko ^c  

^a KYOTO UNIVERSITY   (Japan)

^b HIROSHIMA UNIVERSITY   (Japan)

^c TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

Band calculation; Electrical conductivity; Organic metal; Radical cation salts; Tetrathiapentalene; Thermoelectric power; X ray structure analysis; electron donor

Indexed keywords

2 [4,5 BIS(METHYLTHIO) 1,3 DISELENOL 2 YLIDENE] 5 (4,5 ETHYLENEDIOXY 1,3 DITHIOL 2 YLIDENE) 1,3,4,6 TETRATHIAPENTALENE; GOLD; METAL; RHENIUM; THIOL DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CONDUCTANCE; STRUCTURE ANALYSIS; TEMPERATURE DEPENDENCE; X RAY ANALYSIS;

EID: 0036869891     PISSN: 00224596     EISSN: None     Source Type: Journal    
DOI: 10.1006/jssc.2002.9758     Document Type: Article

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34. The transfer integral (t) is defined by the following equation, t = 10S.
35. The difference between first and second redox potentials obtained from cyclic voltammetry in solution (0.23 V for TMEO-ST-TTP and 0.31 V for BEDT-TTF) occasionally suggests that on-site Coulomb energy of TMEO-ST-TTP is about two-thirds as large as that of BEDT-TTF.