-
1
-
-
0003579939
-
-
(Eds.: L. Paquette), Wiley, New York
-
See for example: [1a] A. Garcia Martínez, L. R. Subramanian, M. Hanack, in Encyclopedia of Reagents for Organic Synthesis. Vol. 7. (Eds.: L. Paquette), Wiley, New York, 1995.
-
(1995)
Encyclopedia of Reagents for Organic Synthesis
, vol.7
-
-
Garcia Martínez, A.1
Subramanian, L.R.2
Hanack, M.3
-
2
-
-
0032580338
-
-
[1b] A. Garcia Martínez, E. Teso Vilar, A. García Fraile, A. Herrera Fernàndez, S. de la Moya Cerero, F. Moreno Jimenez, Tetrahedron 1998, 54, 4607-4614.
-
(1998)
Tetrahedron
, vol.54
, pp. 4607-4614
-
-
Garcia Martínez, A.1
Teso Vilar, E.2
García Fraile, A.3
Herrera Fernàndez, A.4
De la Moya Cerero, S.5
Moreno Jimenez, F.6
-
3
-
-
0035840366
-
-
and references cited therein
-
[1c] A. Garcia Martinez, E. Teso Vilar, A. García Fraile, S. de la Moya Cerero, B. Lora Maroto, Tetrahedron Lett. 2001, 42, 6539-6541, and references cited therein.
-
(2001)
Tetrahedron Lett.
, vol.42
, pp. 6539-6541
-
-
Garcia Martinez, A.1
Teso Vilar, E.2
García Fraile, A.3
De la Moya Cerero, S.4
Lora Maroto, B.5
-
4
-
-
0011850967
-
-
[2a] A. García Martínez, E. Teso Vilar, A. García Fraile, J. Osío Barcina, M. Hanack, L. R. Subramanian, Tetrahedron Lett. 1989, 30, 1503-1506.
-
(1989)
Tetrahedron Lett.
, vol.30
, pp. 1503-1506
-
-
García Martínez, A.1
Teso Vilar, E.2
García Fraile, A.3
Osío Barcina, J.4
Hanack, M.5
Subramanian, L.R.6
-
5
-
-
0027377002
-
-
[2b] A. García Martínez, E. Teso Vilar, J. Osio Barcina, M. E. Rodriguez Herrero, S. de la Moya Cerero, M. Hanack, L. R. Subramanian, Tetrahedron: Asymmetry 1993, 4, 2333-2334.
-
(1993)
Tetrahedron: Asymmetry
, vol.4
, pp. 2333-2334
-
-
García Martínez, A.1
Teso Vilar, E.2
Osio Barcina, J.3
Rodriguez Herrero, M.E.4
De la Moya Cerero, S.5
Hanack, M.6
Subramanian, L.R.7
-
6
-
-
0028100613
-
-
[2c] A. García Martínez, J, Osío Barcina, M. E. Rodríguez Herrero, M, Iglesias de Dios, E, Teso Vilar, L. R. Subramanian, Tetrahedron Lett. 1994, 35, 7285-7288.
-
(1994)
Tetrahedron Lett.
, vol.35
, pp. 7285-7288
-
-
García Martínez, A.1
Osío Barcina, J.2
Rodríguez Herrero, M.E.3
Iglesias de Dios, M.4
Teso Vilar, E.5
Subramanian, L.R.6
-
7
-
-
0030605045
-
-
[2d] A. García Martínez, J. Osío Barcina, E. Teso Vilar, Tetrahedron 1996, 52, 14041-14048.
-
(1996)
Tetrahedron
, vol.52
, pp. 14041-14048
-
-
García Martínez, A.1
Osío Barcina, J.2
Teso Vilar, E.3
-
8
-
-
0000496864
-
-
[2e] A. García Martínez, E. Teso Vilar, S. de la Moya Cerero, J. Osío Barcina, P. C. Gómez, J. Org. Chem. 1999, 64, 5611-5619.
-
(1999)
J. Org. Chem.
, vol.64
, pp. 5611-5619
-
-
García Martínez, A.1
Teso Vilar, E.2
De la Moya Cerero, S.3
Osío Barcina, J.4
Gómez, P.C.5
-
9
-
-
0035914520
-
-
[2f] García Martínez, E. Teso Vilar, A. García Fraile, S. de la Moya Cerero, B. Lora Maroto, C. Díaz Morillo, Tetrahedron Lett. 2001, 42, 8293-8296.
-
(2001)
Tetrahedron Lett.
, vol.42
, pp. 8293-8296
-
-
García Martínez, A.1
Teso Vilar, E.2
García Fraile, A.3
De la Moya Cerero, S.4
Lora Maroto, B.5
Díaz Morillo, C.6
-
10
-
-
0037067016
-
-
[2g] A. García Martínez, E. Teso Vilar, J. Osío Barcina, S. de la Moya Cerero, J. Am. Chem. Soc. 2002, 124, 6676-6685.
-
(2002)
J. Am. Chem. Soc.
, vol.124
, pp. 6676-6685
-
-
García Martínez, A.1
Teso Vilar, E.2
Osío Barcina, J.3
De la Moya Cerero, S.4
-
11
-
-
0001442801
-
-
and references cited therein
-
Bridgehead-subsituted norbornanes: [3a] A. García Martínez, E. Teso Vilar, A. García Fraile, S. de la Moya Cerero, P. Martínez Ruiz, Tetrahedron: Asymmetry 1998, 9, 1737-1745 and references cited therein. Norbornane-derived chiral catalysts: [3b] A. García Martínez, E. Teso Vilar, A. García Fraile, S. de la Moya Cerero, P. Martínez Ruiz, P. Chicharro Villas, Tetrahedron: Asymmetry 2002, 13, 1-4 and references cited therein. C(10)-substituted camphors and fenchones: [3c] A. García Martínez, E. Teso Vilar, A. Garcia Fraile, S. de la Moya Cerero, B. Lora Maroto, Tetrahedron: Asymmetry 2002, 13, 17-19 and references cited therein. Cyclopentanoids from 1-norbornyl triflates: [3d] A. García Martínez, E. Teso Vilar, A. García Fraile, S. de la Moya Cerero, S. de Oro Osuna, B. Lora Maroto, Tetrahedron Lett. 2001, 42, 7795-7799 and references cited therein. Bicyclo[2.1.1]hexanes from 1-norbornyl triflates: [3e] Garcia Martinez, E. Teso Vilar, A. García Fraile, S. de la Moya Cerero, L. R. Subramanian, Synlett 1994, 563-464 and ref.[2b]
-
(1998)
Tetrahedron: Asymmetry
, vol.9
, pp. 1737-1745
-
-
García Martínez, A.1
Teso Vilar, E.2
García Fraile, A.3
De la Moya Cerero, S.4
Martínez Ruiz, P.5
-
12
-
-
0037070071
-
-
and references cited therein
-
Bridgehead-subsituted norbornanes: [3a] A. García Martínez, E. Teso Vilar, A. García Fraile, S. de la Moya Cerero, P. Martinez Ruiz, Tetrahedron: Asymmetry 1998, 9, 1737-1745 and references cited therein. Norbornane-derived chiral catalysts: [3b] A. García Martínez, E. Teso Vilar, A. García Fraile, S. de la Moya Cerero, P. Martínez Ruiz, P. Chicharro Villas, Tetrahedron: Asymmetry 2002, 13, 1-4 and references cited therein. C(10)-substituted camphors and fenchones: [3c] A. García Martínez, E. Teso Vilar, A. Garcia Fraile, S. de la Moya Cerero, B. Lora Maroto, Tetrahedron: Asymmetry 2002, 13, 17-19 and references cited therein. Cyclopentanoids from 1-norbornyl triflates: [3d] A. García Martínez, E. Teso Vilar, A. García Fraile, S. de la Moya Cerero, S. de Oro Osuna, B. Lora Maroto, Tetrahedron Lett. 2001, 42, 7795-7799 and references cited therein. Bicyclo[2.1.1]hexanes from 1-norbornyl triflates: [3e] Garcia Martinez, E. Teso Vilar, A. García Fraile, S. de la Moya Cerero, L. R. Subramanian, Synlett 1994, 563-464 and ref.[2b]
-
(2002)
Tetrahedron: Asymmetry
, vol.13
, pp. 1-4
-
-
García Martínez, A.1
Teso Vilar, E.2
García Fraile, A.3
De la Moya Cerero, S.4
Martínez Ruiz, P.5
Chicharro Villas, P.6
-
13
-
-
0037070077
-
-
and references cited therein
-
Bridgehead-subsituted norbornanes: [3a] A. García Martínez, E. Teso Vilar, A. García Fraile, S. de la Moya Cerero, P. Martinez Ruiz, Tetrahedron: Asymmetry 1998, 9, 1737-1745 and references cited therein. Norbornane-derived chiral catalysts: [3b] A. García Martínez, E. Teso Vilar, A. García Fraile, S. de la Moya Cerero, P. Martínez Ruiz, P. Chicharro Villas, Tetrahedron: Asymmetry 2002, 13, 1-4 and references cited therein. C(10)-substituted camphors and fenchones: [3c] A. García Martínez, E. Teso Vilar, A. García Fraile, S. de la Moya Cerero, B. Lora Maroto, Tetrahedron: Asymmetry 2002, 13, 17-19 and references cited therein. Cyclopentanoids from 1-norbornyl triflates: [3d] A. García Martínez, E. Teso Vilar, A. García Fraile, S. de la Moya Cerero, S. de Oro Osuna, B. Lora Maroto, Tetrahedron Lett. 2001, 42, 7795-7799 and references cited therein. Bicyclo[2.1.1]hexanes from 1-norbornyl triflates: [3e] Garcia Martinez, E. Teso Vilar, A. García Fraile, S. de la Moya Cerero, L. R. Subramanian, Synlett 1994, 563-464 and ref.[2b]
-
(2002)
Tetrahedron: Asymmetry
, vol.13
, pp. 17-19
-
-
García Martínez, A.1
Teso Vilar, E.2
García Fraile, A.3
De la Moya Cerero, S.4
Lora Maroto, B.5
-
14
-
-
0011892689
-
-
and references cited therein
-
Bridgehead-subsituted norbornanes: [3a] A. García Martínez, E. Teso Vilar, A. García Fraile, S. de la Moya Cerero, P. Martinez Ruiz, Tetrahedron: Asymmetry 1998, 9, 1737-1745 and references cited therein. Norbornane-derived chiral catalysts: [3b] A. García Martínez, E. Teso Vilar, A. García Fraile, S. de la Moya Cerero, P. Martínez Ruiz, P. Chicharro Villas, Tetrahedron: Asymmetry 2002, 13, 1-4 and references cited therein. C(10)-substituted camphors and fenchones: [3c] A. García Martínez, E. Teso Vilar, A. Garcia Fraile, S. de la Moya Cerero, B. Lora Maroto, Tetrahedron: Asymmetry 2002, 13, 17-19 and references cited therein. Cyclopentanoids from 1-norbornyl triflates: [3d] A. García Martínez, E. Teso Vilar, A. García Fraile, S. de la Moya Cerero, S. de Oro Osuna, B. Lora Maroto, Tetrahedron Lett. 2001, 42, 7795-7799 and references cited therein. Bicyclo[2.1.1]hexanes from 1-norbornyl triflates: [3e] Garcia Martinez, E. Teso Vilar, A. García Fraile, S. de la Moya Cerero, L. R. Subramanian, Synlett 1994, 563-464 and ref.[2b]
-
(2001)
Tetrahedron Lett.
, vol.42
, pp. 795-7799
-
-
García Martínez, A.1
Teso Vilar, E.2
García Fraile, A.3
De la Moya Cerero, S.4
De Oro Osuna, S.5
Lora Maroto, B.6
-
15
-
-
0001695817
-
-
and ref.[2b]
-
Bridgehead-subsituted norbornanes: [3a] A. García Martínez, E. Teso Vilar, A. García Fraile, S. de la Moya Cerero, P. Martinez Ruiz, Tetrahedron: Asymmetry 1998, 9, 1737-1745 and references cited therein. Norbornane-derived chiral catalysts: [3b] A. García Martínez, E. Teso Vilar, A. García Fraile, S. de la Moya Cerero, P. Martínez Ruiz, P. Chicharro Villas, Tetrahedron: Asymmetry 2002, 13, 1-4 and references cited therein. C(10)-substituted camphors and fenchones: [3c] A. García Martínez, E. Teso Vilar, A. Garcia Fraile, S. de la Moya Cerero, B. Lora Maroto, Tetrahedron: Asymmetry 2002, 13, 17-19 and references cited therein. Cyclopentanoids from 1-norbornyl triflates: [3d] A. García Martínez, E. Teso Vilar, A. García Fraile, S. de la Moya Cerero, S. de Oro Osuna, B. Lora Maroto, Tetrahedron Lett. 2001, 42, 7795-7799 and references cited therein. Bicyclo[2.1.1]hexanes from 1-norbornyl triflates: [3e] Garcia Martinez, E. Teso Vilar, A. García Fraile, S. de la Moya Cerero, L. R. Subramanian, Synlett 1994, 563-464 and ref.[2b]
-
(1994)
Synlett
, pp. 563-464
-
-
García Martínez, A.1
Teso Vilar, E.2
García Fraile, A.3
De la Moya Cerero, S.4
Subramanian, L.R.5
-
16
-
-
0027990553
-
-
For the preparation of chiral ligands (diols and amino alcohols) from 1-norbornyl triflates see for example: [4a] A. García Martínez, E. Teso Vilar, A. García Fraile, S. de la Moya Cerero, L. R. Subramanian, Tetrahedron: Asymmetry 1994, 5, 1373-1376. [4b] A. García Martínez, E. Teso Vilar, A. García Fraile, S. de la Moya Cerero, P. Martínez Ruiz, L. R. Subramanian, Tetrahedron: Asymmetry 1996, 7, 1257-1260 and ref.[3b] For the importance of tridentate norbornane-based ligands as chiral catalysts, see for example: [4c] I. Philipova, V. Dimitrov, S. Simova, Tetrahedron: Asymmetry 1999, 10, 913-921 and 1381-1391. Restricted norbornane-based triols can be interesting intermediates for the synthesis of artificial lyposomes (see for example: [4d] A. D. Miller, Angew. Chem. Int. Ed. 1998, 37, 1768-1785), whereas restricted aminodiols can be used in the synthesis of artificial sphingosines (see for example: [4e] N. Khiar, K. Singh, M. Garcia, M. Martín-Lomas, Tetrahedron Lett. 1999, 40, 5779-5782). On the other hand, chiral tridentate triols are interesting ligands for the preparation of transition-metal complex chiral catalysts (see for example: [4f] H. Lütjens, G. Wahl, F. Möller, P. Knöchel, J. Sundermeyer, Organometallics 1997, 16, 5869-5878).
-
(1994)
Tetrahedron: Asymmetry
, vol.5
, pp. 1373-1376
-
-
García Martínez, A.1
Teso Vilar, E.2
García Fraile, A.3
De la Moya Cerero, S.4
Subramanian, L.R.5
-
17
-
-
0000170238
-
-
and ref.[3b]
-
For the preparation of chiral ligands (diols and amino alcohols) from 1-norbornyl triflates see for example: [4a] A. García Martínez, E. Teso Vilar, A. Garcia Fraile, S. de la Moya Cerero, L. R. Subramanian, Tetrahedron: Asymmetry 1994, 5, 1373-1376. [4b] A. García Martínez, E. Teso Vilar, A. García Fraile, S. de la Moya Cerero, P. Martínez Ruiz, L. R. Subramanian, Tetrahedron: Asymmetry 1996, 7, 1257-1260 and ref.[3b] For the importance of tridentate norbornane-based ligands as chiral catalysts, see for example: [4c] I. Philipova, V. Dimitrov, S. Simova, Tetrahedron: Asymmetry 1999, 10, 913-921 and 1381-1391. Restricted norbornane-based triols can be interesting intermediates for the synthesis of artificial lyposomes (see for example: [4d] A. D. Miller, Angew. Chem. Int. Ed. 1998, 37, 1768-1785), whereas restricted aminodiols can be used in the synthesis of artificial sphingosines (see for example: [4e] N. Khiar, K. Singh, M. Garcia, M. Martín-Lomas, Tetrahedron Lett. 1999, 40, 5779-5782). On the other hand, chiral tridentate triols are interesting ligands for the preparation of transition-metal complex chiral catalysts (see for example: [4f] H. Lütjens, G. Wahl, F. Möller, P. Knöchel, J. Sundermeyer, Organometallics 1997, 16, 5869-5878).
-
(1996)
Tetrahedron: Asymmetry
, vol.7
, pp. 1257-1260
-
-
García Martínez, A.1
Teso Vilar, E.2
García Fraile, A.3
De la Moya Cerero, S.4
Martínez Ruiz, P.5
Subramanian, L.R.6
-
18
-
-
0033548383
-
-
For the preparation of chiral ligands (diols and amino alcohols) from 1-norbornyl triflates see for example: [4a] A. García Martínez, E. Teso Vilar, A. Garcia Fraile, S. de la Moya Cerero, L. R. Subramanian, Tetrahedron: Asymmetry 1994, 5, 1373-1376. [4b] A. García Martínez, E. Teso Vilar, A. García Fraile, S. de la Moya Cerero, P. Martínez Ruiz, L. R. Subramanian, Tetrahedron: Asymmetry 1996, 7, 1257-1260 and ref.[3b] For the importance of tridentate norbornane-based ligands as chiral catalysts, see for example: [4c] I. Philipova, V. Dimitrov, S. Simova, Tetrahedron: Asymmetry 1999, 10, 913-921 and 1381-1391. Restricted norbornane-based triols can be interesting intermediates for the synthesis of artificial lyposomes (see for example: [4d] A. D. Miller, Angew. Chem. Int. Ed. 1998, 37, 1768-1785), whereas restricted aminodiols can be used in the synthesis of artificial sphingosines (see for example: [4e] N. Khiar, K. Singh, M. Garcia, M. Martín-Lomas, Tetrahedron Lett. 1999, 40, 5779-5782). On the other hand, chiral tridentate triols are interesting ligands for the preparation of transition-metal complex chiral catalysts (see for example: [4f] H. Lütjens, G. Wahl, F. Möller, P. Knöchel, J. Sundermeyer, Organometallics 1997, 16, 5869-5878).
-
(1999)
Tetrahedron: Asymmetry
, vol.10
, pp. 913-921
-
-
Philipova, I.1
Dimitrov, V.2
Simova, S.3
-
19
-
-
0032479769
-
-
For the preparation of chiral ligands (diols and amino alcohols) from 1-norbornyl triflates see for example: [4a] A. García Martínez, E. Teso Vilar, A. Garcia Fraile, S. de la Moya Cerero, L. R. Subramanian, Tetrahedron: Asymmetry 1994, 5, 1373-1376. [4b] A. García Martínez, E. Teso Vilar, A. García Fraile, S. de la Moya Cerero, P. Martínez Ruiz, L. R. Subramanian, Tetrahedron: Asymmetry 1996, 7, 1257-1260 and ref.[3b] For the importance of tridentate norbornane-based ligands as chiral catalysts, see for example: [4c] I. Philipova, V. Dimitrov, S. Simova, Tetrahedron: Asymmetry 1999, 10, 913-921 and 1381-1391. Restricted norbornane-based triols can be interesting intermediates for the synthesis of artificial lyposomes (see for example: [4d] A. D. Miller, Angew. Chem. Int. Ed. 1998, 37, 1768-1785), whereas restricted aminodiols can be used in the synthesis of artificial sphingosines (see for example: [4e] N. Khiar, K. Singh, M. Garcia, M. Martín-Lomas, Tetrahedron Lett. 1999, 40, 5779-5782). On the other hand, chiral tridentate triols are interesting ligands for the preparation of transition-metal complex chiral catalysts (see for example: [4f] H. Lütjens, G. Wahl, F. Möller, P. Knöchel, J. Sundermeyer, Organometallics 1997, 16, 5869-5878).
-
(1998)
Angew. Chem. Int. Ed.
, vol.37
, pp. 1768-1785
-
-
Miller, A.D.1
-
20
-
-
0033618299
-
-
For the preparation of chiral ligands (diols and amino alcohols) from 1-norbornyl triflates see for example: [4a] A. García Martínez, E. Teso Vilar, A. Garcia Fraile, S. de la Moya Cerero, L. R. Subramanian, Tetrahedron: Asymmetry 1994, 5, 1373-1376. [4b] A. García Martínez, E. Teso Vilar, A. García Fraile, S. de la Moya Cerero, P. Martínez Ruiz, L. R. Subramanian, Tetrahedron: Asymmetry 1996, 7, 1257-1260 and ref.[3b] For the importance of tridentate norbornane-based ligands as chiral catalysts, see for example: [4c] I. Philipova, V. Dimitrov, S. Simova, Tetrahedron: Asymmetry 1999, 10, 913-921 and 1381-1391. Restricted norbornane-based triols can be interesting intermediates for the synthesis of artificial lyposomes (see for example: [4d] A. D. Miller, Angew. Chem. Int. Ed. 1998, 37, 1768-1785), whereas restricted aminodiols can be used in the synthesis of artificial sphingosines (see for example: [4e] N. Khiar, K. Singh, M. García, M. Martín-Lomas, Tetrahedron Lett. 1999, 40, 5779-5782). On the other hand, chiral tridentate triols are interesting ligands for the preparation of transition-metal complex chiral catalysts (see for example: [4f] H. Lütjens, G. Wahl, F. Möller, P. Knöchel, J. Sundermeyer, Organometallics 1997, 16, 5869-5878).
-
(1999)
Tetrahedron Lett.
, vol.40
, pp. 5779-5782
-
-
Khiar, N.1
Singh, K.2
García, M.3
Martín-Lomas, M.4
-
21
-
-
0041687313
-
-
For the preparation of chiral ligands (diols and amino alcohols) from 1-norbornyl triflates see for example: [4a] A. García Martínez, E. Teso Vilar, A. Garcia Fraile, S. de la Moya Cerero, L. R. Subramanian, Tetrahedron: Asymmetry 1994, 5, 1373-1376. [4b] A. García Martínez, E. Teso Vilar, A. García Fraile, S. de la Moya Cerero, P. Martínez Ruiz, L. R. Subramanian, Tetrahedron: Asymmetry 1996, 7, 1257-1260 and ref.[3b] For the importance of tridentate norbornane-based ligands as chiral catalysts, see for example: [4c] I. Philipova, V. Dimitrov, S. Simova, Tetrahedron: Asymmetry 1999, 10, 913-921 and 1381-1391. Restricted norbornane-based triols can be interesting intermediates for the synthesis of artificial lyposomes (see for example: [4d] A. D. Miller, Angew. Chem. Int. Ed. 1998, 37, 1768-1785), whereas restricted aminodiols can be used in the synthesis of artificial sphingosines (see for example: [4e] N. Khiar, K. Singh, M. Garcia, M. Martín-Lomas, Tetrahedron Lett. 1999, 40, 5779-5782). On the other hand, chiral tridentate triols are interesting ligands for the preparation of transition-metal complex chiral catalysts (see for example: [4f] H. Lütjens, G. Wahl, F. Möller, P. Knöchel, J. Sundermeyer, Organometallics 1997, 16, 5869-5878).
-
(1997)
Organometallics
, vol.16
, pp. 5869-5878
-
-
Lütjens, H.1
Wahl, G.2
Möller, F.3
Knöchel, P.4
Sundermeyer, J.5
-
22
-
-
0029821881
-
-
and references cited therein
-
For the preparation of 4 from camphor, see: M. Gianini, A. von Zelewsky, Synthesis 1996, 702-706, and references cited therein.
-
(1996)
Synthesis
, pp. 702-706
-
-
Gianini, M.1
Von Zelewsky, A.2
-
23
-
-
0011879834
-
-
note
-
13C NMR spectra agree with the proposed structure.
-
-
-
-
24
-
-
0011798966
-
-
note
-
13C NMR spectra agree with the structure).
-
-
-
-
25
-
-
0011800271
-
-
note
-
2 1:4). After chromatography, pure 7 was obtained (0.13 g, 97% yield from 6) (for characterization data see ref.[7]).
-
-
-
-
26
-
-
1542587019
-
-
Solvent addition to the carbonyl group before the trifiate-group cleavage has been previously proposed, although to the best of our knowledge not totally demonstrated, for the solvolysis of some 2-oxo- and 2-thioxo-substituted bridgehead triflates. See for example: [9a] X. Creary, Chem. Rev. 1991, 91, 1625-1677. [9b] K. Takunaga, T. Ohtsu, Y. Ohga, K. Takeuchi, J. Org. Chem. 1998, 63, 2209-2217. See also ref.[2d] and the references cited therein.
-
(1991)
Chem. Rev.
, vol.91
, pp. 1625-1677
-
-
Creary, X.1
-
27
-
-
0011836726
-
-
See also ref.[2d] and the references cited therein
-
Solvent addition to the carbonyl group before the trifiate-group cleavage has been previously proposed, although to the best of our knowledge not totally demonstrated, for the solvolysis of some 2-oxo- and 2-thioxo-substituted bridgehead triflates. See for example: [9a] X. Creary, Chem. Rev. 1991, 91, 1625-1677. [9b] K. Takunaga, T. Ohtsu, Y. Ohga, K. Takeuchi, J. Org. Chem. 1998, 63, 2209-2217. See also ref.[2d] and the references cited therein.
-
(1998)
J. Org. Chem.
, vol.63
, pp. 2209-2217
-
-
Takunaga, K.1
Ohtsu, T.2
Ohga, Y.3
Takeuchi, K.4
|