Effective charge saturation in colloidal suspensions

Journal of Chemical Physics

Volumn 117, Issue 17, 2002, Pages 8138-8152

  Bocquet, Lydéric ^a   Trizac, Emmanuel ^b   Aubouy, Miguel ^c  

^a Laboratoire de Physique UMR CNRS ENSL   (France)

^b UNIVERSITÉ PARIS SUD   (France)

^c CEA GRENOBLE   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTROSTATICS; POLYELECTROLYTES; SALTS; SUSPENSIONS (FLUIDS); THERMAL EFFECTS;

NONLINEAR SCREENING EFFECTS;

COLLOIDS;

EID: 0036848897     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.1511507     Document Type: Article

References (71)

1. E.J.W. Verwey and J.T.G. Overbeek, Theory of the Stability of Lyophobic Colloids (Elsevier, Amsterdam, 1948).
2. R. Kjellander and D.J. Mitchell, Chem. Phys. Lett. 200, 76 (1992).
3. J. Ulander, H. Greberg, and R. Kjellander, J. Chem. Phys. 115, 7144 (2001), and references therein.
4. L. Belloni, Colloids Surf., A 140, 227 (1998).
5. S. Alexander, P.M. Chaikin, P. Grant, G.J. Morales, and P. Pincus, J. Chem. Phys. 80, 5776 (1984).
6. R.J. Hunter, Foundations of Colloid Science (Clarendon, Oxford, 1995).
7. J.-P. Hansen and H. Löwen, Annu. Rev. Phys. Chem. 51, 209 (2000).
8. This terminology should be used remembering that except in cylindrical geometry, there is no physical condensation (defined as the existence of a nonvanishing quantity of micro-ions in a layer of vanishing thickness around the polyion, see Refs. 9-11).
9. J.-L. Barrat and J.-F. Joanny, Adv. Chem. Phys. 94, 1 (1996).
10. R.M. Fuoss, A. Katchalsky, and S. Lifson, Proc. Natl. Acad. Sci. U.S.A. 37, 579 (1951); T. Alfrey, P. Berg, and H.J. Morawetz, J. Polym. Sci. 7, 543 (1951).
11. R.M. Fuoss, A. Katchalsky, and S. Lifson, Proc. Natl. Acad. Sci. U.S.A. 37, 579 (1951); T. Alfrey, P. Berg, and H.J. Morawetz, J. Polym. Sci. 7, 543 (1951).
12. G.V. Ramanathan, J. Chem. Phys. 78, 3223 (1983).
13. P. Attard, Adv. Chem. Phys. 92, 1 (1996).
14. C.N. Likos, Phys. Rep. 348, 267 (2001).
15. Y. Monovoukas and A.P. Gast, J. Colloid Interface Sci. 128, 533 (1989).
16. M.J. Stevens, M.L. Falk, and M.O. Robbins, J. Chem. Phys. 104, 5209 (1996).
17. B, see the discussion in Sec. III.
18. A. Diehl, M.C. Barbosa, and Y. Levin, Europhys. Lett. 53, 86 (2001)
19. P.S. Kuhn, Y. Levin, and M.C. Barbosa, Macromolecules 31, 8347 (1998).
20. M. Deserno, C. Holm, and S. May, Macromolecules 33, 199 (2000).
21. L. Belloni, J. Phys.: Condens. Matter 12, R549 (2000).
22. E. Trizac, L. Bocquet, and M. Aubouy, cond-mat/0201510.
23. E. Trizac, Phys. Rev. E 62, R1465 (2000).
24. I.A. Shkel, O.V. Tsodirov, and M.T. Record, J. Phys. Chem. B 104, 5161 (2000).
25. P. Wette, H.J. Shöpe, and T. Palberg, J. Chem. Phys. 116, 10981 (2002).
26. J.C. Crocker and D.G. Grier, Phys. Rev. Lett. 77, 1897 (1996).
27. S.H. Behrens and D.G. Grier, J. Chem. Phys. 115, 6716 (2001).
28. H. Oshima, T. Healy, and L.R. White, J. Colloid Interface Sci. 90, 17 (1982).
29. G.V. Ramanathan, J. Chem. Phys. 88, 3887 (1988).
30. T.M. Squires and M.P. Brenner, Phys. Rev. Lett. 85, 4976 (2000).
31. A.M. Larsen and D.G. Grier, Nature (London) 385, 230 (1997).
32. C.A. Tracy and H. Widom, Physica A 244, 402 (1997).
33. M. Fixman, J. Chem. Phys. 70, 4995 (1979).
34. R.A. Marcus, J. Chem. Phys. 23, 1057 (1955).
35. E. Trizac and J.-P. Hansen, J. Phys.: Condens. Matter 8, 9191 (1996).
36. M. Deserno and C. Holm, in Proceedings of the NATO Advanced Study Institute on Electrostatic Effects in Soft Matter and Biophysics, edited by C. Holm et al. (Kluwer, Dordrecht, 2001).
37. M. Deserno and H.H. von Grünberg, Phys. Rev. E 66, 011401 (2002).
38. W. Härtl and H. Versmold, J. Chem. Phys. 88, 7157 (1988).
39. H. Löwen, J. Chem. Phys. 100, 6738 (1994).
40. V. Lobaskin and P. Linse, J. Chem. Phys. 111, 4300 (1999).
41. E. Allahyarov and H. Löwen, J. Phys.: Condens. Matter 13, L277 (2001).
42. A.G. Moreira and R.R. Netz, Phys. Rev. Lett. 87, 078301 (2001); R.R. Netz, Eur. Phys. J. E 5, 557 (2001).
43. A.G. Moreira and R.R. Netz, Phys. Rev. Lett. 87, 078301 (2001); R.R. Netz, Eur. Phys. J. E 5, 557 (2001).
44. M. Dubois, T. Zemb, L. Belloni, A. Delville, P. Levitz, and R. Setton, J. Chem. Phys. 75, 944 (1992).
45. J.P. Hansen and E. Trizac, Physica A 235, 257 (1997).
46. M.O. Robbins, K. Kremer, and G.S. Grest, J. Chem. Phys. 88, 3286 (1988).
47. E.J. Meijer and D. Frenkel, J. Chem. Phys. 94, 2269 (1991).
48. F. Bitzer, T. Palberg, H. Löwen, R. Simon, and P. Leiderer, Phys. Rev. E 50, 2821 (1994).
49. E. Trizac and J.-P. Hansen, Phys. Rev. E 56, 3137 (1997).
50. P.L. Hansen, R. Podgornik, and V.A. Parsegian, Phys. Rev. E 64, 021907 (2001).
51. V. Reus, L. Belloni, T. Zemb, N. Lutterbach, and H. Versmold, J. Phys. II 7, 603 (1997).
52. H.E. Auer and Z. Alexandrowicz, Biopolymers 8, 1 (1969).
53. E. Raspaud, L. da Conceicao, and F. Livolant, Phys. Rev. Lett. 84, 2533 (2000).
54. M. Deserno, C. Holm, J. Blaul, M. Ballauff, and M. Rehahn, Eur. Phys. J. E 5, 97 (2001).
55. R.D. Groot, J. Chem. Phys. 95, 9191 (1991).
56. In neglects the discrete nature of the solvent, but takes into account the micro-ions explicitly as hard bodies.
57. B/a remains finite.
58. M. Deserno and C. Holm, cond-mat/0203599.
59. F. Cornu and B. Jancovici, J. Chem. Phys. 90, 2444 (1989).
60. B. Hribar, V. Vlachy V., L.B. Bhuiyan, and C.W. Outhwaite, J. Phys. Chem. B 104, 11533 (2000).
61. A. Evilevitch, V. Lobaskin, U. Olsson, P. Linse, and P. Schurtenberger, Langmuir 17, 1043 (2001).
62. T. Palberg, W. Mönch, F. Bitzer, R. Piazza, and T. Bellini, Phys. Rev. Lett. 74, 4555 (1995).
63. J.C. Crocker and D.G. Grier, Phys. Rev. Lett. 73, 352 (1994).
64. E. Allahyarov, I. d'Amico, and H. Löwen, Phys. Rev. Lett. 81, 1334 (1998).
65. P. Linse and V. Lobaskin, Phys. Rev. Lett. 83, 4208 (1999).
66. R. Messina, C. Holm, and K. Kremer, Phys. Rev. Lett. 85, 872 (2000).
67. L.B. Bhuiyan, V. Vlachy, and C.W. Outhwaite, Int. Rev. Phys. Chem. 21, 1 (2002).
68. H.H. von Grünberg, R. van Roij, and G. Klein, Europhys. Lett. 55, 580 (2001).
69. See, e.g., D. Andelman, in Membranes, their Structure and Conformation, edited by R. Lipowsky and E. Sackmann (Elsevier, Amsterdam, 1996).
70. B. Beresford-Smith, D.Y.C. Chan, and D.J. Mitchell, J. Colloid Interface Sci. 216, 9691 (1985).
71. L.F. Rojas, C. Urban, P. Schurtenberger, T. Gisler, and H.H. von Grünberg, Europhys. Lett. (submitted).