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Volumn , Issue 11, 2002, Pages 2850-2856

Novel complexes trans(Cl)-[Os(bpy)(CO)-(CH3CN)Cl2]n (n = 0, +1; bpy = 2,2′-bipyridine): Photo- and electrochemical syntheses and comparative study of their bonding and redox properties

Author keywords

Charge transfer photochemistry; Decarbonylation; Electrochemical oxidation; N ligands; Osmium

Indexed keywords

ACETONITRILE; BINARY ALLOYS; CYCLIC VOLTAMMETRY; DICHLOROMETHANE; ELECTROCHEMICAL OXIDATION; LIGANDS; REDOX REACTIONS; RUTHENIUM COMPOUNDS; SPECTROELECTROCHEMISTRY; SYNTHESIS (CHEMICAL);

EID: 0036844614     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/1099-0682(200211)2002:11<2850::AID-EJIC2850>3.0.CO;2-4     Document Type: Article
Times cited : (15)

References (42)
  • 23
    • 85153233353 scopus 로고    scopus 로고
    • note
    • 2], the 6-H and 6-H′ signals are well separated by 0.7-0.9 ppm if one of the Cl ligands occupies an equatorial position, the signal of 6-H at the pyridine ring trans to the Cl ligand being shifted to values at δ > 9.6 ppm.[9]
  • 25
    • 85153238486 scopus 로고    scopus 로고
    • note
    • -1 (n = -2; DBCat/DBCat).[28]
  • 28
    • 85153230096 scopus 로고    scopus 로고
    • unpublished results
    • F. Hartl, unpublished results.
    • Hartl, F.1
  • 34
    • 85153220275 scopus 로고    scopus 로고
    • note
    • 2{C(O)OiPr}Cl] is photostable in acetonitrile at ambient temperature and CO substitution does not occur.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.