Iron- and ruthenium-containing triple-decker complexes with a central pentaphospholyl ligand - X-ray structures of [(η-C5H5)Fe(μ-η: η-P5)Ru(η-C5Me5)]PF6 and [(η-C5Me5)Ru(μ-η: η-P5)Ru(η-C5Me5)]PF6

European Journal of Inorganic Chemistry

Volumn , Issue 11, 2002, Pages 3018-3027

  Kudinov, Alexander R ^a   Loginov, Dmitry A ^a   Starikova, Zoya A ^a   Petrovskii, Pavel V ^a   Corsini, Maddalena ^b   Zanello, Piero ^b  

^a A N NESMEYANOV INSTITUTE OF ORGANOELEMENT COMPOUNDS   (Russian Federation)

^b UNIVERSITY OF SIENA   (Italy)

Author keywords

Electrochemistry; Iron; Phosphorus; Ruthenium; Sandwich compounds; Triple decker complexes

Indexed keywords

COBALT COMPOUNDS; IRON COMPOUNDS; LIGANDS; PHOSPHORUS COMPOUNDS; RUTHENIUM COMPOUNDS; SYNTHESIS (CHEMICAL); X RAY DIFFRACTION;

ANALOGOUS COMPLEXES; CATIONIC COMPLEXES; DEGRADATION REACTION; HALF-SANDWICH; SANDWICH COMPOUND; STACKINGS; SYNTHESISED; TRIPLE-DECKER COMPLEX; X- RAY DIFFRACTIONS; X-RAY STRUCTURE;

ELECTROCHEMISTRY;

IRON COMPLEX; PHOSPHORUS DERIVATIVE; RUTHENIUM DERIVATIVE;

ARTICLE; CHEMICAL REACTION; COMPLEX FORMATION; ELECTROCHEMICAL ANALYSIS; OXIDATION REDUCTION REACTION; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; SYNTHESIS; X RAY ANALYSIS; X RAY DIFFRACTION;

EID: 0036843483     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/1099-0682(200211)2002:11<3018::AID-EJIC3018>3.0.CO;2-A     Document Type: Article

References (60)

1. [1a] O. J. Scherer, Angew. Chem. Int. Ed. Engl. 1990, 29, 1104.
2. [1b] M. Scheer, E. Herrmann, Z. Chem. 1990, 30, 41.
3. O. J. Scherer, J. Schwalb, G. Wolmershäiuser, W. Kaim, R. Gross, Angew. Chem. Int. Ed. Engl. 1986, 25, 363.
4. [3a] L. Y. Goh, R. C. S. Wong, C. K. Chu, T. W. Hambley, J Chem. Soc., Dalton Trans. 1990, 977.
5. [3b] A. K. Hughes, V. J. Murphy, D. O'Hare, J. Chem. Soc., Chem. Commun. 1994, 163.
6. M. Scheer, K. Schuster, A. Krug, H. Hartung, Chem. Ber./Recueil 1997, 130, 1299.
7. Our recent results on this topic are summarised in the review: A. R. Kudinov, M. I. Rybinskaya, Izv. Akad. Nauk, Ser. Khim. 1999, 1636 [Russ. Chem. Bull. 1999, 48, 1615 (Engl. Transl.)].
8. [6a] O. J. Scherer, T. Brück, G. Wolmershäuser, Chem. Ber. 1989, 122, 2049.
9. [6b] B. Rink, O. J. Scherer, G. Heckmann, G. Wolmershäuser, Chem, Ber. 1992, 125, 1011.
10. A. R. Kudinov, P. V. Petrovskii, M. I. Rybinskaya, Izv. Akad. Nauk, Ser Khim. 1999, 1374 [Russ. Chem. Bull. 1999, 48, 1362 (Engl. Transl.)].
11. Preliminary account of this work: A. R. Kudinov, D. A. Loginov, P. V. Petrovskii, M. I. Rybinskaya, Izv. Akad Nauk, Ser. Khim. 1998, 1625 [Russ. Chem. Bull. 1998, 47, 1583 (Engl. Transl.)].
12. A. R. Kudinov, M. I. Rybinskaya, Yu. T. Struchkov, A. I. Yanovskii, P. V. Petrovskii, J. Organomet. Chem. 1987, 336, 187.
13. - anions (the anions are omitted in the schemes).
14. [11a] D. Catheline, D. Astruc, Z Organomet. Chem. 1983, 248, C9.
15. [11b] D. Catheline, D. Astruc, Organometallics 1984, 3, 1094.
16. G. E. Herberich, U. Englert, B. Ganter, C. Lamertz, Organometallics 1996, 15, 5236.
17. n (n = 1-4).[6a]
18. + complexes: B. Chaudret, F. A. Jalon, J. Chem. Soc., Chem. Commun. 1988, 711.
19. [15a] B. Chaudret, X. He, Y. Huang, J. Chem. Soc., Chem. Commun. 1989, 1844.
20. [15b] X. D. He, B. Chaudret, E Dahan, Y.-S. Huang, Organometallics 1991, 10, 970.
21. [15c] U. Koelle, M. H. Wang, G. Raabe, Organometallics 1991, 10, 2573.
22. [15d] G. E. Herberich, U. Englert, F. Marken, P. Hofmann, Organometallics 1993, 12, 4039.
23. [16a] V. S. Kaganovich, A. R. Kudinov, M. I. Rybinskaya, Izv. Akad Nauk SSSR, Ser Khim. 1986, 492 [Bull. Acad. Sci. USSR, Div. Chem. Sci. 1986, 35, 456 (Engl. Transl.)].
24. [16b] V. S. Kaganovich, A. R. Kudinov, M. I. Rybinskaya, Metalloorg. Khim. 1990, 3, 70 [Organomet. Chem. USSR 1990, 3, 35 (Engl. Transl.)].
25. 5, Cp*(1), and Cp*(2) rings, respectively.
26. B. P. Biryukov, Yu. T. Struchkov, Usp. Khim 1970, 39, 1672. [Russ. Chem. Rev. 1970, 39, 789 (Engl. Transl.)].
27. O. J. Scherer, T Brück, G. Wolmershäuser, Chem. Ber. 1988, 121, 935.
28. J. W. Lauher, M. Elian, R. H. Summerville, R. Hoffmann, J. Am. Chem. Soc. 1976, 98, 3219.
29. [21a] A. Salzer, H. Werner, Synth. Inorg. Met.-Org. Chem. 1972, 2, 249.
30. [21b] A. R. Kudinov, A. A. Fil'chikov, P. V. Petrovskii, M. I. Rybinskaya, Izv. Akad. Nauk, Ser. Khim. 1999, 1364 [Russ. Chem. Bull. 1999, 48, 1352 (Engl. Transl.)].
31. [22a] G. E. Herberich, B. Hessner, R. Saive, J Organomet. Chem. 1987, 319, 9.
32. [22b] G. E. Herberich, B. J. Dunne, B. Hessner, Angew. Chem. Int. Ed. Engl. 1989, 28, 737.
33. [22c] G. E. Herberich, U. Büschges, B. J. Dunne, B. Hessner, N. Klaff, D. P. J. Köffer, K. M. Peters, J. Organomet. Chem. 1989, 372, 53.
34. W. Siebert, W. Rothermel, C. Böhle, C. Krüger, D. J. Brauer, Angew. Chem. Int. Ed. Engl. 1979, 18, 949.
35. [24a] G. E. Herberich, U. Englert, D. Pubanz, J Organomet. Chem. 1993, 459, 1.
36. [24b] A. R. Kudinov, D. A. Loginov, Z. A. Starikova, P V. Petrovskii, J Organomet. Chem. 2002, 649, 136.
37. [25a] G. E. Herberich, B. Ganter, Organometallics 1997, 16, 522.
38. [25b] A. R. Kudinov, D. A. Loginov, S. N. Ashikhmin, A. A. Fil'chikov, L. S. Shul'pina, P. V. Petrovskii, Izv. Akad. Nauk, Ser. Khim. 2000, 1647 [Russ. Chem. Bull. 2000, 49, 1637 (Engl. Transl.)].
39. [25c] G. E. Herberich, B. Ganter, Inorg. Chem. Commun. 2001, 4, 100.
40. R. F. Winter, W. E. Geiger, Organometallics 1999, 18, 1827.
41. M. Di Vaira, L. Sacconi, Angew. Chem. Int. Ed. Engl. 1982, 21, 330.
42. O. J. Scherer, J. Schwalb, H. Swarowsky, G. Wolmershäuser, W. Kaita Kaim, R. Gross, Chem. Ber. 1988, 121, 443.
43. O. Blacque, H. Brunner, M. M. Kubicki, F. Leis, D. Lucas, Y. Mugnier, B. Nuber, J. Wachter, Chem. Eur. J. 2001, 7, 1342.
44. C. Bianchini, F. Laschi, D. Masi, F. M. Ottaviani, A. Pastor, M. Peruzzini, P. Zanello, F. Zanobini, J. Am. Chem. Soc 1993, 115, 2723.
45. [31a] D. E. Richardson, H. Taube, Inorg. Chem. 1981, 20, 1278.
46. [31b] R. R. Gagné, C. L. Spiro, T J. Smith, C. A. Hamann, W. R. Thies, A. K. Shiemke, J. Am. Chem. Soc. 1981, 103, 4073.
47. [31c] D. Astruc, in Electron Transfer and Radical Processes in Transition-Metal Chemistry, Wiley-VCH, New York, 1995.
48. [31d] B. S. Brunschwig, N. Sutin, Coord. Chem. Rev. 1999, 187, 233.
49. A. R. Kudinov, D. A. Loginov, I. V. Pruss, Z. A. Starikova, P. V. Petrovskii, Eur. J. Inorg. Chem., in preparation
50. B. Rink, O. J. Scherer, G. Wolmershäuser, Chem. Ber. 1995, 128, 71.
51. A. N. Nesmeyanov, N. A. Vol'kenau, I. N. Bolesova, L. S. Polkovnikova, Koord. Khim. 1975, 1, 1252 [Sov. J Coord. Chem. 1975, 1 (Engl. Transl.)].
52. T P. Gill, K. R. Mann, Organometallics 1982, 1, 485.
53. J. L. Schrenk, A. M. McNair, F. B. McCormick, K. R. Mann, Inorg. Chem. 1986, 25, 3501.
54. T. D. Tilley, R. H. Grubbs, J. E. Bercaw, Organometallics 1984, 3, 274.
55. M. Detzel, G. Friedrich, O. J. Scherer, G. Wolmershäuser, Angew. Chem. Int. Ed. Engl. 1995, 34, 1321.
56. F. Fabrizi de Biani, F. Laschi, P. Zanello, G. Ferguson, J. Trotter, G. M. O'Riordan, T. R. Spalding, J. Chem. Soc., Dalton Trans. 2001, 1520.
57. SMART, Bruker Molecular Analysis Research Tool, v. 5.059, Bruker AXS, Madison, Wisconsin, USA.
58. SAINTPlus Data Reduction and Correction Program, v. 6.01, Bruker AXS, Madison, Wisconsin, USA.
59. SADABS, Bruker/Siemens Area Detector Absorption Correction Program, v.2.01, Bruker AXS, Madison, Wisconsin, USA.
60. G. M. Sheldrick, SHELXTL, Structure Determination Software Suite, v. 5.10, Bruker AXS, Madison, Wisconsin, USA.