Measuring oxidant species in electrolyzed salt brine solutions

Journal / American Water Works Association

Volumn 94, Issue 10, 2002, Pages 111-120

  Gordon, Gilbert ^a   Bolden, Renee ^a   Emmert, Gary ^a  

^a MIAMI UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHLORINE; COMPOSITION EFFECTS; ELECTROLYSIS; OXIDATION; OZONE; POTABLE WATER; WATER ANALYSIS;

CHLORINE DIOXIDE; OXIDANT SPECIES; SALT BRINE SOLUTIONS;

BRINES;

EID: 0036806488     PISSN: 0003150X     EISSN: None     Source Type: Journal    
DOI: 10.1002/j.1551-8833.2002.tb09562.x     Document Type: Article

References (36)

1. Adam, L. & Gordon, G., 1999. Hypochlorite Ion Decomposition: Effects of Temperature, Ionic Strength, and Chloride Ion. Inorganic Chem., 38:1299.
2. Adam, L.; Fabian, I.; & Gordon, G., 1992. Hypochlorous Acid Decomposition in the pH 5 to 8 Region. Inorganic Chem., 31:3534.
3. Chiswell, B. & O'Halloran, K., 1991. Use of Lissamine Green B as a Spectrophotometric Reagent for the Determination of Low Levels of Chlorine Dioxide. Analyst, 116:657.
4. Csordas, V. et al, 2001. Kinetics and Mechanism of Catalytic Decomposition and Oxidation of Chlorine Dioxide by the Hypochlorite Ion. Inorganic Chem., 40:1833.
5. Dowd, M.T., 1994. Assessment of THM Formation With MIOX. Master's thesis, Dept. of Civil Engrg., Univ. of North Carolina, Chapel Hill.
6. Emmert, G., 1999. Chemical Aspects of Water Treatment: Part 1-Chemical Characterization of Oxidants Present in Liquors Following Electrolysis of Salt Brine. PhD Dissertation, Dept. of Chem., Miami University, Oxford, Ohio.
7. Emmert, G. et al, 2000. Studies of Selectivity in the Amaranth Method for Chlorine Dioxide. Talanta, 51:879.
8. Espenson, J., 1986. Rates of Inorganic Reactions. Investigation of Rates and Mechanisms of Reactions (vol. 6, part 1). John Wiley & Sons Inc., Hoboken, N.J.
9. Gauw, R., 1999. Reactions and Interactions of Drinking Water Treatment By-products: Characterization of the Electrochemical Formation of Inorganic By-products of the Electrolysis of Salt Brine. PhD dissertation, Dept. of Chem., Miami University, Oxford, Ohio.
10. Gord, J.; Gordon, G.; & Pacey, G., 1988. Selective Chlorine Determination by Gas Diffusion Flow Injection Analysis With Chemiluminescent Detection. Anal. Chem., 60:2.
11. Gordon, G. 1998a. Electrochemical Mixed Oxidant Treatment: Chemical Detail of Electrolyzed Salt Brine Technology. USEPA contract 68-C5-0039, Cincinnati.
12. Gordon, G. 1998b. Personal communication.
13. Gordon, G. et al, 2000a. Using Indigo Absorbance to Calculate the Indigo Sensitivity Coefficient. Jour. AWWA, 92:12:96.
14. Gordon, G.; Walters, B.; & Bubnis, B., 2000b. The Effect of Indigo Purity on Measuring the Concentration of Aqueous Ozone. Proc. IOA/PAG Conf., Orlando, Fla.
15. 3? Proc. 2000 AWWA Ann. Conf., Denver.
16. Gordon, G.; Adam, L.; & Bubnis, B., 1994. Minimizing Chlorate Ion Formation in Drinking Water When Hypochlorite Ion Is the Chlorinating Agent. AWWA Res. Fdn., Denver.
17. Gordon, G. et al, 1992 (2nd ed.). Disinfectant Residual Measurement Methods. AWWA Res. Fdn., Denver.
18. Granstrom, M. & Lee, G., 1958. Generation and Use of Chlorine Dioxide in Water Treatment. Jour. AWWA, 50:10:1453.
19. Hollowell, D. et al, 1986. Selective Chlorine Dioxide Determination Using Gas Diffusion Flow Injection Analysis With Chemiluminescent Detection. Anal. Chem., 58:1524.
20. Hollowell, D.; Pacey, G.; & Gordon, G., 1985. Selective Determination of Chlorine Dioxide Using Gas Diffusion Flow Injection Analysis. Anal. Chem., 57:2851.
21. Kalberg, B. & Pacey, G., 1989. Flow Injection Analysis, A Practical Guide. Elsevier Science Publishing Co., New York.
22. Masschelein, W., 1966. Spectrophotometric Method for Chlorine Dioxide With Acid Chrome Violet K. Anal. Chem., 38:1839.
23. Pfaff, J.; Brockhoff, C.; & O'Dell, J., 1991. Method 300.1 Revised: The Determination of Inorganic Anions in Water by Ion Chromatography. USEPA, Cincinnati.
24. Rakness, K. et al, 2001. Underestimating the Dissolved Ozone Residual Using Outdated or Impure Indigo. Proc. IOA/PAG Conf., Newport Beach, Calif.
25. Shelton, S.P. & Barton, L.L., 1992. A Review of the Effectiveness of SCOLA in the Disinfection of Water Contaminated With Microorganisms. Report for LATA Inc., Dept. of Biology, Univ. of New Mexico, Albuquerque.
26. Silverman, R. & Gordon, G., 1980. Variation of the Absorbance Spectra of Hypochlorous Acid With Perchlorate Concentration. A Hypochromic Effect. Jour. Physical Chem., 84:625.
27. Silverman, R. & Gordon, G. 1974. The Use of the Syringe as a Shrinking Bottle. Anal. Chem., 46:178.
28. Standard Methods for the Examination of Water and Wastewater, 1992 (18th ed.). APHA, AWWA, and WEF, Washington.
29. Straka, M.; Gordon, G.; & Pacey, G., 1985. Residual Aqueous Ozone Determination by Gas Diffusion Flow Injection Analysis. Anal. Chem., 57:1799.
30. Taube, H. & Dodgen, H., 1949. Applications of Radioactive Chlorine to Study the Mechanisms of Reactions Involving Changes in the Oxidation State of Chlorine. Jour. Amer. Chem. Soc., 71:3330.
31. 2 State of Chlorine Dioxide. Jour. Chem. Phys., 94:1:163.
32. Vanden Plas, B., 1997. Industrial Hygiene Survey Report for Gas Generation by MIOX Water Treatment Equipment. LATA Inc., Los Alamos, N.M.
33. US Patent, 1995. No. 5,385,711. Electrolytic Cell for Generating Sterilization Solutions Having an Increased Ozone Content (Jan.).
34. US Patent, 1994a. No. 5,308,507. Method and Apparatus for Removing Organic Contaminants (May).
35. US Patent, 1994b. No. 5,316,740. Electrolytic Cell for Generating Sterilization Solutions Having an Increased Ozone Content (May).
36. US Patent, 1988. No. 4,761,208. Electrolytic Method and Cell for Sterilizing Water (Aug.).