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Similar shapes of the Lander molecules were observed on Cu(001)
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0011251144
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note
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eV for the effective NN three-body interaction for Cu (Ref. 27).
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30
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0011221107
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note
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For the nanostructure at the step it is only the build-up of the first row (1-7) which costs energy (0.04 eV per atom mainly due to NNN changes), while the second row basically does not lead to energy changes compared to the kink-site adsorption site.
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31
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0011218014
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note
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This implies that moving kink atoms (κ) to the positions (1) and (8) requires a large formation energy of 0.28 and 0.24 eV, respectively, while the other atoms (2-7) and (9-14) encounter the same energetic situation as the equivalent atoms in the nanostructure at steps (2-7) and (9-14).
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32
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0011171331
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note
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It is also more likely to grow a nanostructure at a step, since the supply of Cu atoms is much larger than on a terrace, where only diffusing adatoms are available.
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