A new binary accelerator system for filled natural rubber vulcanization

Iranian Polymer Journal (English Edition)

Volumn 11, Issue 5, 2002, Pages 311-323

  Susamma, Athikalam P ^a   Kurian, Mary ^a   Kuriakose, Arackal P ^a  

^a Department of Polymer Science and Rubber Technology   (India)

Author keywords

Amidinothiourea; Filled systems; Natural rubber; Reaction mechanism; Sulphur vulcanization

Indexed keywords

ANTIOXIDANTS; CARBON BLACK; REACTION KINETICS; SILICA; VULCANIZATION;

BINARY ACCELERATOR SYSTEMS;

RUBBER;

EID: 0036765947     PISSN: 10261265     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (22)

1. Kuriakose A.P. and Mathew G., "Anew binary accelerator system for rubber vulcanization", Ind. J. Technol. 26, 344-347 (1988).
2. Mathew G, Pillai P.V., and Kuriakose A.P., "Studies on a new binary accelerator system for the sulfur vulcanisation of styrene butadiene rubber", Rubb. Chem. Technol. 65, 277-292 (1992).
3. Mathew C., Mini V.T.E., Kuriakose A.P., and Francis D.J., "Studies on a new binary accelerator system containing TMTD and amidinothiourea in sulfur vulcanization of natural rubber", J Appl. Polym. Sci. 54, 1033-1041 (1994).
4. Mathew G., Kuriakose B., and Kuriakose A. P., "Effect of 1- substituted and 1,5- disubstituted 2,4 -dithiobiurets-N-cyclohexyl benzthiazyl sulphenamide (CBS) binary accelerator systems in the vulcanization of NR/SBR blends", Kautsch Gummi Kustst. 45, 6, 490-493 (1992).
5. Mini V.T.E., Mathew C., Kuriakose A.P., and Francis D.J., "Amidinothiourea as a secondary accelerator in a binary system for the sulphur vulcanisation of natural rubber", J. Mater. Sci. 30, 2049 -2054 (1995).
6. Willoughby B.G. and Scott K.W., "Nitrosamine formation in rubber. Influence of cure", Rubb. Chem. Technol., 71, 766-777 (1997).
7. Menta E. and Palumbo M., Expert Opinion on Therapeutic Patents., 8, 12, 1627-1672 (1998).
8. Baudy R.B., Expert Opinion on Therapeutic Patents, 8, 10, 1267-1305 (1998).
9. Blanchard A.F., The Applied Sci. of Rubber, W. J. S. Naunton, Ed., Edward Arnold, London, 414-474 (1961).
10. Alter H., "Filler particle size and mechanical properties of polymers", J. Appl. Polym. Sci, 9, 1525-1531 (1965).
11. Sato Y. and Furukawa J., "A molecular theory of filler reinforcement based on the concept of internal deformation", Rubb. Chem. Technol, 35, 857-876 (1962).
12. Guth E. "Theory of filler reinforcement", J. Appl. Phys. 16, 20-25(1945).
13. Porter M., "Structural characterization of filled vulcanisates. 1. Determination of the concentration of chemical crosslinks in natural rubber vulcanisates containing high abration furnace black", Rubb. Chem. Technol, 40, 866-882 (1967).
14. Bhowmick A.K. and S. K. De, "Kinetics of crosslinking and network changes in natural rubber vulcanisates with a dithiodimorpholine based accelerator system", Rubb. Chem. Technol, 53, 1015-1022 (1980).
15. Kraus G., Science and Technology of Rubber, Erich F. R., Ed., Academic, New York (1978).
16. Bhowmick A.K. and De S.K., "Effect of curing temperature and curing system on network structure and technical properties of polybutadiene and styrene butadiene rubber", J. Appl. Polym. Sci., 26, 529-541 (1981).
17. Bhowmick A.K. and De S.K., "Dithiodimorpholine-based accelerator system in tire teard compound for high temperature vulcaninsation", Rubb. Chem. Technol. 52, 985-995 (1979).
18. Ellis B. and Welding G.W. "Estimation from swelling of the structurel contribution of chemical reactions in the vulcanization of natural rubber", Rubb. Chem. Technol. 37, 2, 571-580 (1964).
19. Cunneen J.I. and Russel 1R.M., "Occurrence and prevention of changes in the chemical structure of natural rubber tire tread vulcanisates during service", Rubb. Chem. Technol., 43, 1215-1224 (1970).
20. Chakraborty S.K. and De S.K., "Silica and clay reinforced carboxylated nitrile rubber vulcanized by a mixed crosslinking system", Rubb. Chem. Technol., 55, 990-1003 (1982).
21. Flory P.J. and Rehner J., "Statistical mechanics of crosslinked polymer network", J. Chem. Phys. 11, 512-520 (1943).
22. Sheehan C.J. and Basio A.L., "Polymer/solvent interaction parameters", Rubb. Chem. Technol., 39, 149-192 (1966).