An alternative synthetic access to cis-4a-Methyloctahydrophenanthrene, a biomarker of Sergipe-Alagoas Basin petroleum in Brazil

Journal of the Brazilian Chemical Society

Volumn 13, Issue 5, 2002, Pages 664-668

  Rodrigues, Denise C ^a   De Meijere, Armin ^b   Marsaioli, Anita J ^a  

^a UNIVERSITY OF CAMPINAS   (Brazil)

^b UNIVERSITY OF GÖTTINGEN   (Germany)

Author keywords

Biomarker; Carmopolis petroleum; cis 4a Methyloctahydrophenanthrene; Sergipe Alagoas Basin

Indexed keywords

(2 BROMOPHENYL)ACETIC ACID; 4ALPHA METHYLOCTAHYDROPHENANTHRENE; ACETIC ACID DERIVATIVE; BIOLOGICAL MARKER; CYCLOHEXANE DERIVATIVE; DIHYDRORESORCINOL; PETROLEUM; PHENANTHRENE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; BRAZIL; GAS CHROMATOGRAPHY; HECK REACTION; STANDARD; STEREOCHEMISTRY; SYNTHESIS;

EID: 0036458877     PISSN: 01035053     EISSN: None     Source Type: Journal    
DOI: 10.1590/S0103-50532002000500020     Document Type: Article

References (20)

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20. RI exp. = Relative Retention Index calculated applying the Van den Dool and Kratz equation (van den Dool, H.; Kratz, P. D.; J. Chromatogr. 1963, 11, 463); t = traces. GC-MS-Analyses were carried out using a HP-5990/5970 system equipped with a J&W Scientific DB-5 fused silica capillary column (30 m × 0.25 mm × 0.25 mm); column temperatures were programmed from 90 to 300°C at 3.5°/min. Helium was used as carrier gas at 1 mL/min, and SIM detection mode was used.