Enthalpies of solution of sodium chloride and potassium sulfate in water. Thermodynamic properties of the potassium sulfate + water system

Journal of Chemical and Engineering Data

Volumn 47, Issue 1, 2002, Pages 33-46

  Archer, Donald G ^a   Kirklin, Duane R ^a  

^a NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CALORIMETRY; EQUATIONS OF STATE; FREEZING; PHASE TRANSITIONS; POTASSIUM COMPOUNDS; SODIUM CHLORIDE; SOLUTIONS; SPECIFIC HEAT; TEMPERATURE; THERMAL VARIABLES MEASUREMENT; THERMODYNAMIC PROPERTIES; WATER;

CHEMICAL POTENTIAL; FREEZING POINT; MOLALITY; POTASSIUM SULFATE;

ENTHALPY;

EID: 0036452039     PISSN: 00219568     EISSN: None     Source Type: Journal    
DOI: 10.1021/je010118a     Document Type: Article

References (91)

1. 2O-(cr), and Phase Equilibria. J. Chem. Phys. Ref. Data 1992, 21, 793-829.
2. 2O. Geochim. Cosmochim. Acta 1987, 51, 2429-2443.
3. 2O System from Zero to High Concentration at 25 ° C. Geochim Cosmochim. Acta 1980, 44, 981-997.
4. 2 Organic Substances in SI Units. J. Phys. Chem. Ref. Data 1982, 11, Suppl. 2.
5. Prosen, E. J.; Kilday, M. V. An Adiabatic Solution Calorimeter and Measurements of a Standard Reaction for Solution Calorimetry. J. Res. Natl. Bur. Stand. 1972, 77A, 179-203.
6. Archer, D. G. Enthalpy Increment Measurements from 4.5 to 318 K for Bismuth(cr). Thermodynamic Properties from 0 K to the Melting Point. J. Chem. Eng. Data 1995, 40, 1015-1024.
7. 2O System. 3. J. Chem. Eng. Data 1997, 42, 281-292.
8. 2O System. I. Thermodynamic Properties of NaCl(cr). J. Chem. Phys. Ref. Data 1992, 21, 1-21.
9. Archer D. G.; Kirklin, D. R. NIST and Standards for Calorimetry. Thermochim. Acta 2000, 347, 21-30.
10. 2O and NaCl(aq) in Cold-stable and Supercooled States. J. Phys. Chem. B 104, 8563-8584.
11. Moore, G. E.; Kelley, K. K. The Specific Heats of Anhydrous Sulfates of Iron, Magnesium, Manganese, and Potassium. J. Am. Chem. Soc. 1942, 64, 2949-2951.
12. Paukov, I. E. True Heat Capacities at Low Temperatures and Absolute Entropies and Enthalpies of Lithium and Potassium Sulphates. Russ. J. Phys. Chem. 1969, 43, 1134-1135.
13. Shomate, C. H.; Naylor, B. F. High-Temperature Heat Contents of Aluminum Oxide, Aluminum Sulfate, Potassium Sulfate, Ammonium Sulfate and Ammonium Bisulfate. J. Am. Chem. Soc. 1945, 67, 72-75.
14. Shmidt, N. E. True Heat Capacity of Sulphates of Group I Elements. Russ. J. Inorg. Chem. 1967, 12, 929-931.
15. Denielou, L.; Petitet, J.-P.; Tequi, C. Thermodynamic Study of Alkali Sulphates. Calculation of Enthalpy, Entropy and Gibbs Free Energy. Thermochim. Acta 1974, 9, 135-141.
16. Dworkin, A. S.; Bredig, M. A. Pretransition Behavior of Solid Potassium and Thallium Sulfates from Heat Content and Thermal Expansion. J. Phys. Chem. 1970, 74, 3403-3406.
17. Rubinchik, S. M.; Banashek, E. I.; Sokolov, V. A.; Fumin, A. I. Enthalpies of Alkali Metal Sulphates at High Temperatures. I. Enthalpy of Potassium Sulphate at the Melting Point. Russ. J. Phys. Chem. 1971, 45, 599-601.
18. NIST Chemistry WebBook, NIST Standard Reference Database Number 69; Mallard, W. G., Linstrom, P. J., Eds.; National Institute of Standards and Technology: Gaithersburg, MD, 20899 (http://webbook.nist.gov) 2000.
19. Chase, M. W.; Davies, J. A.; Downey, J. R.; Frurip, D. J.; McDonald, R. A.; Syverud, A. N. JANAF Thermochemical Tables. Third Edition. J. Phys. Chem. Ref. Data 1985, 14, Supplement 1.
20. 2O. J. Phys. Chem. Ref. Data 1990, V19, 1233-1274.
21. Archer, D. G., Wang, P. The Dielectric Constant of Water and Debye-Hückel Limiting Law Coefficients. J. Phys. Chem. Ref. Data 1990, 19, 371-411.
22. 2O System at 25 °C. J. Solution Chem. 1996, 25, 695-709.
23. 4 at Temperature 298.15 K. J. Chem. Thermodyn. 1996, 28, 491-496.
24. Holmes., H. F.; Mesmer, R. E. Isopiestic Studies of Aqueous Solutions at Elevated Temperature VIII. The Alkali Metal Sulfates. J. Chem. Thermodyn. 1986, 18, 263-275.
25. 2O at 25 °C. J. Appl. Chem. USSR 1979, 52, 525-530.
26. 2O. Sov. Radiochem. 1967, 9, 64-67.
27. Robinson, R. A.; Wilson, J. M; Stokes, R. H. The Activity Coefficients of Lithium Sodium Sulfate and Sodium Thiosulfate at 25 ° from Isopiestic Measurements. J. Am. Chem. Soc. 1941, 63, 1011-1013.
28. 2O Ternary System at 25° and 35 °C. Russ J. Inorg. Chem. 1973, 18, 887-888.
29. Pearce, J. N.; Eckstrom, H. C. Vapor Pressures and Partial Molal Volumes of Aqueous Solutions of the Alkali Sulfates at 25°. J. Am. Chem. Soc. 1937, 59, 2689-2691.
30. Leopold, H. G.; Johnston, J. The Vapor Pressure of the Saturated Aqueous Solutions of Certain Salts. J. Am. Chem. Soc. 1927, 49, 1974-1988.
31. Holmberg, K. E. Phase Diagrams of Some Sodium and Potassium Salts in Light and Heavy Water; Aktiebolaget Atomenegi: Stockholm, Sweden, 1968.
32. 2O. Izv. Sekt. Fiz-Khim. Anal., Inst. Obshch. Noerg. Khim., Akad. Nauk SSSR 1955, 26, 198-210.
33. Indelli, A. Cryoscopic Measurement of Aqueous Solutions of the Sulfates of Lithium, Sodium and Potassium. Ric. Sci. 1953, 23, 2258-2265.
34. Hovorka, F.; Rodebush, W. H. The Freezing Points of Very Dilute Solutions of Electrolyte. J. Am. Chem. Soc. 1925, 47, 1614-1624.
35. Hall, R. E.; Harkins, W. D. The Free Energy of Dilution and the Freezing-Point Lowering in Solutions of Some Salts of Various Types of Ionization, and of Salt Mixtures. J. Am. Chem. Soc. 1916, 38, 2658-2676.
36. Rivett, A. C. D. Neutral Salt Effect on the Freezing Points of Mixtures in Aqueous Solution. Z. Phys Chem. (Leipzig) 1912, 80, 537-563.
37. Archibald, H. E. On a Test, by the Freezing-Point Method, of the Ionization Coefficients Determined by the Conductivity Method for Solutions Containing Potassium and Sodium Sulphates. Proc. Trans. N. S. Inst. Sci. 1903, 10, 33-48.
38. Osaka, Y. On the Freezing Point of More Diluted Solutions of Mixtures. Z. Phys. Chem. 1902, 41, 560-564.
39. Jones, H. C. On the Determination of the Freezing Points of Very Dilute Salt Solutions. Z. Phys. Chem. (Leipzig) 1983, 11, 529-551.
40. Li, J.; Zhai, Z.; Zheng, Z. Enthalpies of Dilution and Relative Apparent Molar Enthalpies of the Major Aqueous Salts of Salt Lakes at 298.15 K. Wuli Huaxue Xuebao 1994, 10, 759-764.
41. 2 at 373.15, 423.65, and 472.95 K. J. Chem. Eng. Data 1983, 28, 56-59.
42. Leung, W. H.; Millero, F. J. The Enthalpy of Formation of Magnesium Sulfate Ion Pairs. J. Solution Chem. 1975, 4, 145-159.
43. 2O over a Wide Concentration Range. J. Appl. Chem. USSR 1971, 44, 179-181.
44. 4. Zh. Obshch. Khim. 1936, 6, 85.
45. 4. Z. Phys. Chem. 1931, A157, 1-31.
46. Plake, E. Heat of Dilution of Strong Electrolytes and the Association Hypothesis from Nernst. Z. Phys. Chem. 1932, A162, 257-280.
47. Mashima, M.; Usami, H.; Suzuki, S.; Takase, T. Hydration Number and Heat of Solution in Water of Tris(ethylenediamine) Complexes or Several Sulfates at Infinite Dilution. Nippon Kagaku Kaishi 1975, 6, 963-967.
48. Tsvetkov, V. G.; Rabinovich, I. B. Isotope Effects in the Heat of Dissolution of Solids. J. Phys. Chem. 1969, 43, 675-677.
49. Romanova, I. I.; Samoilov, O. Ya. Connection of Salting-out with the Short-range Hydration of Cations in Aqueous Solutions. Russ. J. Inorg. Chem. 1969, 14, 131-133.
50. Kapustinskii, A. F.; Samoilov, O. Ya. Structure of Aqueous Electrolyte Solution and Hydration of Ions. Zh. Fiz. Khim. 1952, 26, 918-927.
51. Colomina Barbera, M. Variation of the Heat of Solution of Sodium Thiosulfate Pentahydrate as a Function of Temperature. An. Fis. Quim. 1942, 38, 369-377.
52. Cohen, A.; Kooy, J. The Metastability of Elements and Bonds, Consequences of Enantiotropy and Monotropy. XII. The Heat of Solution. I. Z. Phys. Chem. 1928, 139, 273-350.
53. Saluja, P. P. S.; Lemire, R. J.; LeBlanc, J. C. High-temperature Thermodynamics of Aqueous Alkali-metal Salts. J. Chem. Thermodyn. 1992, 24, 181-203.
54. 4 at 298.15 K. Thermochim. Acta. 1988, 126, 245-253.
55. Perron, G.; Desnoyers, J. E.; Millero, F. J. Apparent Molal Volumes and Heat Capacities of Some Sulfates and Carbonates in Water at 25 °C. Can. J. Chem. 1975, 53, 1134-1138, Data from CISTI Depository of Unpublished Data.
56. Desnoyers, J. E.; de Visser, C.; Perron, G.; Picker, P. Reexamination of the Heat Capacities Obtained by Flow Microcalorimetry. Recommendation for the Use of a Chemical Standard. J. Solution. Chem. 1976, 5, 605-616.
57. Randall, M.; Rossini, F. D. Heat Capacities in Aqueous Solutions. J. Am. Chem. Soc. 1992, 51, 323-345.
58. 4 Solubilities to 100 °C. J. Res. U. S. Geol. Surv. 1978, 6, 701-705.
59. Berkeley, E. VIII. On Some Physical Constants of Saturated Solutions. Philos. Trans. R. Soc. (London) 1904, 203A, 189-215.
60. Blasdale, W. C. Equilibria in Solutions Containing Mixtures of Salts. III. The System, Water and the Chlorides and Carbonates of Sodium and Potassium at 25 ° C. IV. The System, Water and the Sulfates and Carbonates of Sodium and Potassium at 25 ° C. J. Am. Chem. Soc. 1923, 45, 2935-2946.
61. 4. III. Z. Anorg. Allg. Chem. 1929, 184, 359-368.
62. Hill, A. E.; Moskowitz, S. Ternary Systems. VIII. Potassium Carbonate, Potassium Sulfate and Water at 25 ° C. J. Am. Chem. Soc. 1929, 51, 2396-2398.
63. Malhorta, K. L.; Suri, H. D. Equilibrium in the Systems: Potassium Sulphate, Cadmium Sulphate, Water at 25 °C. J. Phys. Chem. 1930, 34, 2103-2110.
64. Starrs, B. A.; Storch, H. H. The Ternary System: Potassium Sulphate - Magnesium Sulphate - Water. J. Phys. Chem. 1930, 34, 2367-2374.
65. 4. III. Z. Anorg. Allg. Chem. 1931, 197, 113-128.
66. Schroeder, W.; Schlackman, H. On the Ternary System Cerium Sulfate - Alkali Sulfate - Water I. The Ternary System Cerium-(3) Sulfate - Potassium Sulfate - Water. Z. Anorg. Chem. 1934, 220, 369-410.
67. Akerlöf, G.; Turck, H. E. The Solubility of Some Strong, Highly Soluble Electrolytes in Methyl Alcohol and Hydrogen Peroxide-Water Mixtures at 25 °C. J. Am. Chem. Soc. 1935, 57, 1746-1750.
68. Benrath, A.; Gjedebo, F.; Schiffers, B.; Wunderlich, H. On the Solubility of Salts and Salt Mixtures in Water at Temperatures abpve 100°. Z. Anorg. Chem. 1937, 231, 285-297.
69. Calvo, C.; Simons, E. L. The Ternary Aqueous Systems of Ammonium Sulfate with Cesium, Potassium and Rubidium Sulfates. J. Am. Chem. Soc. 1952, 74, 1202-1203.
70. Ishii, T.; Fujita, S. Properties of Potassium Sulfate Aqueous Solution and Crystals. J. Chem. Eng. Data 1978, 23, 19-23.
71. Wirth, H. E. The Partial Molal Volumes of Potassium Chloride, Potassium Bromide and Potassium Sulfate in Sodium Chloride Solutions. J. Am. Chem. Soc. 1937, 59, 2549-2554.
72. Jones, G.; Colvin, J. H. The Viscosity of Electrolytes as a Function of the Concentration. VII. Silver Nitrate, Potassium Sulfate and Potassium Chromate. J. Am. Chem. Soc. 1940, 62, 338-340.
73. Kaminsky, M. Experimental Studies of the Concentration and Temperature Dependence of the Viscosity of Aqueous Solutions of Strong Electrolytes. Z. Phys. Chem. NF 1957, 12, 206-231.
74. Dunn, L. A. Apparent Molar Volumes of Electrolytes. Part 1. Some 1-1, 1-2, 2-1, 3-1 Electrolytes in Aqueous Solutions at 25 °C. Trans. Faraday Soc. 1966, 62, 2348-2354.
75. 2O Solutions from Room Temperature to 573 K. Russ. J. Inorg. Chem. 1998, 43, 268-272.
76. Ellis, A. J. Partial Molal Volumes in High-Temperature Water. Part III. Halide and Oxyanion Salts. J. Chem. Soc. A 1968, 1138-1143.
77. 4 as a Function of Temperature. J. Solution Chem. 1990, 19, 353-374.
78. 4(aq) at Temperatures from 298 K to 573 K and at Pressures up to 30 MPa. J. Chem. Eng. Data 1997, 42, 137-142.
79. Jones, G.; Ray, W. A. The Surface Tension of Electrolytes as a Function of the Concentration. I. A Differential Method for Measuring Relative Surface Tension. J. Am. Chem. Soc. 1937, 59, 187-199.
80. 2O at 25°. J. Am. Chem. Soc. 1932, 54, 2229-2243.
81. 2O System. J. Phys. Chem. Ref. Data 1999, 28, 1-17.
82. 2O. J. Solution Chem. 1975, 4, 923-947.
83. 4. Thermochim. Acta 2000, 352, 1-10.
84. Åkerlöf, G. Investigations of Sulfate Solutions. Experimental Methods and Results on Cells Without Liquid Junction. J. Am. Chem. Soc. 1926, 48, 1160-1178
85. Holmes, H. F.; Mesmer, R. E. Thermodynamics of Aqueous Solutions of the Alkali Metal Sulfates. J. Solution Chem. 1986, 15, 495-518.
86. 4. Can. J. Chem. 1978, 56, 1871-1873.
87. Pabalan, R. T., Pitzer, K. S. Apparent Molar Heat Capacity and Other Thermodynamic Properties of Aqueous KCl Solutions to High Temperatures and Pressures. J. Chem. Eng. Data 1988, 33, 354-362.
88. 2O to 300 °C. Geochim. Cosmochim. Acta 1988, 52, 2393-2404.
89. Linke, W. F.; Seidell, A. Solubilities. Inorganic and Metal-organic Compounds, 4th ed.; American Chemical Society: Washington, DC, 1965; Vol. II.
90. Goldberg, R. N. Evaluated Activity and Osmotic Coefficients for Aqueous Solutions: Thirty-Six Uni-Bivalent Electrolytes. J. Phys. Chem. Ref. Data 1981, 10, 671-764.
91. Cox, J. D.; Wagman, D. D.; Medvedev, V. A. CODATA Key Values for Thermodynamics; Hemisphere: Washington, DC, 1989.