The crystal and molecular structure of one of the possible conformers of "the smallest piece of ice" - A solid-state isolation of a hydrogen bonded water hexamer trapped within channels of a crystal of a dirhodium molecule

Journal of Chemical Crystallography

Volumn 32, Issue 11, 2002, Pages 485-488

  Bernal, Ivan ^a   Bear, John L ^a  

^a University of Houston   (United States)

Author keywords

Antineoplastic; Dirhodium molecule; Hexameric cluster

Indexed keywords

RHODIUM; WATER;

ARTICLE; CHEMICAL STRUCTURE; CRYSTAL; CRYSTAL STRUCTURE; HYDROGEN BOND; MOLECULE; SOLID STATE;

EID: 0036441443     PISSN: 10741542     EISSN: None     Source Type: Journal    
DOI: 10.1023/A:1021148910894     Document Type: Article

References (15)

1. Ahsan, M.Q.; Bernal, I.; Bear, J.L. Inorg. Chem. 1986, 26, 260.
2. Hughes, R.G.; Bear, J.L.; Kimball, A.P. Proc. Amer. Assoc. Cancer Res. 1972, 13, 120; Erck, A.; Rainen, L.; Whileyman, J.; Chang, I.M.; Kimball, A.P.; Bear, J.L. Proc. Soc. Exp. Biol. Med. 1974, 145, 1278; Bear, J.L.; Gray, H.B.; Rainen, L.; Chang, I.M.; Howard, R.; Serio, G.; Kimball, A.P. Cancer Chemother Rep. 1975, 59, 611; Kitchens, J.; Bear, J.L. J. Inorg. Nuclear Chem. 1969, 31, 2415; Kitchens, J.; Bear, J.L. J. Inorg. Nuclear Chem. 1971, 33, 3479; Kitchens, J.; Bear, J.L. Thermochim. Acta, 1970, 1, 537; Kitchens, J.; Bear, J.L. J. Inorg. Nuclear Chem. 1970, 32, 49; Rainen, L.; Howard, R.A.; Kimball, A.P.; Bear, J.L. Inorg. Chem. 1975, 14, 2752; Das, K.; Bear, J.L. Inorg. Chem. 1976, 15, 2093; Das, K.; Kadish, K.M.; Bear, J.L. Inorg. Chem. 1978, 17, 930; Das, K., Simmons, E.L.; Bear, J.L. Inorg. Chem. 1977, 16, 1268; Erck, A.; Sherwood, E.; Bear, J.L.; Kimball, A.P. Cancer Res. 1976, 36, 2204.
3. Hughes, R.G.; Bear, J.L.; Kimball, A.P. Proc. Amer. Assoc. Cancer Res. 1972, 13, 120; Erck, A.; Rainen, L.; Whileyman, J.; Chang, I.M.; Kimball, A.P.; Bear, J.L. Proc. Soc. Exp. Biol. Med. 1974, 145, 1278; Bear, J.L.; Gray, H.B.; Rainen, L.; Chang, I.M.; Howard, R.; Serio, G.; Kimball, A.P. Cancer Chemother Rep. 1975, 59, 611; Kitchens, J.; Bear, J.L. J. Inorg. Nuclear Chem. 1969, 31, 2415; Kitchens, J.; Bear, J.L. J. Inorg. Nuclear Chem. 1971, 33, 3479; Kitchens, J.; Bear, J.L. Thermochim. Acta, 1970, 1, 537; Kitchens, J.; Bear, J.L. J. Inorg. Nuclear Chem. 1970, 32, 49; Rainen, L.; Howard, R.A.; Kimball, A.P.; Bear, J.L. Inorg. Chem. 1975, 14, 2752; Das, K.; Bear, J.L. Inorg. Chem. 1976, 15, 2093; Das, K.; Kadish, K.M.; Bear, J.L. Inorg. Chem. 1978, 17, 930; Das, K., Simmons, E.L.; Bear, J.L. Inorg. Chem. 1977, 16, 1268; Erck, A.; Sherwood, E.; Bear, J.L.; Kimball, A.P. Cancer Res. 1976, 36, 2204.
4. Hughes, R.G.; Bear, J.L.; Kimball, A.P. Proc. Amer. Assoc. Cancer Res. 1972, 13, 120; Erck, A.; Rainen, L.; Whileyman, J.; Chang, I.M.; Kimball, A.P.; Bear, J.L. Proc. Soc. Exp. Biol. Med. 1974, 145, 1278; Bear, J.L.; Gray, H.B.; Rainen, L.; Chang, I.M.; Howard, R.; Serio, G.; Kimball, A.P. Cancer Chemother Rep. 1975, 59, 611; Kitchens, J.; Bear, J.L. J. Inorg. Nuclear Chem. 1969, 31, 2415; Kitchens, J.; Bear, J.L. J. Inorg. Nuclear Chem. 1971, 33, 3479; Kitchens, J.; Bear, J.L. Thermochim. Acta, 1970, 1, 537; Kitchens, J.; Bear, J.L. J. Inorg. Nuclear Chem. 1970, 32, 49; Rainen, L.; Howard, R.A.; Kimball, A.P.; Bear, J.L. Inorg. Chem. 1975, 14, 2752; Das, K.; Bear, J.L. Inorg. Chem. 1976, 15, 2093; Das, K.; Kadish, K.M.; Bear, J.L. Inorg. Chem. 1978, 17, 930; Das, K., Simmons, E.L.; Bear, J.L. Inorg. Chem. 1977, 16, 1268; Erck, A.; Sherwood, E.; Bear, J.L.; Kimball, A.P. Cancer Res. 1976, 36, 2204.
5. Hughes, R.G.; Bear, J.L.; Kimball, A.P. Proc. Amer. Assoc. Cancer Res. 1972, 13, 120; Erck, A.; Rainen, L.; Whileyman, J.; Chang, I.M.; Kimball, A.P.; Bear, J.L. Proc. Soc. Exp. Biol. Med. 1974, 145, 1278; Bear, J.L.; Gray, H.B.; Rainen, L.; Chang, I.M.; Howard, R.; Serio, G.; Kimball, A.P. Cancer Chemother Rep. 1975, 59, 611; Kitchens, J.; Bear, J.L. J. Inorg. Nuclear Chem. 1969, 31, 2415; Kitchens, J.; Bear, J.L. J. Inorg. Nuclear Chem. 1971, 33, 3479; Kitchens, J.; Bear, J.L. Thermochim. Acta, 1970, 1, 537; Kitchens, J.; Bear, J.L. J. Inorg. Nuclear Chem. 1970, 32, 49; Rainen, L.; Howard, R.A.; Kimball, A.P.; Bear, J.L. Inorg. Chem. 1975, 14, 2752; Das, K.; Bear, J.L. Inorg. Chem. 1976, 15, 2093; Das, K.; Kadish, K.M.; Bear, J.L. Inorg. Chem. 1978, 17, 930; Das, K., Simmons, E.L.; Bear, J.L. Inorg. Chem. 1977, 16, 1268; Erck, A.; Sherwood, E.; Bear, J.L.; Kimball, A.P. Cancer Res. 1976, 36, 2204.
6. Hughes, R.G.; Bear, J.L.; Kimball, A.P. Proc. Amer. Assoc. Cancer Res. 1972, 13, 120; Erck, A.; Rainen, L.; Whileyman, J.; Chang, I.M.; Kimball, A.P.; Bear, J.L. Proc. Soc. Exp. Biol. Med. 1974, 145, 1278; Bear, J.L.; Gray, H.B.; Rainen, L.; Chang, I.M.; Howard, R.; Serio, G.; Kimball, A.P. Cancer Chemother Rep. 1975, 59, 611; Kitchens, J.; Bear, J.L. J. Inorg. Nuclear Chem. 1969, 31, 2415; Kitchens, J.; Bear, J.L. J. Inorg. Nuclear Chem. 1971, 33, 3479; Kitchens, J.; Bear, J.L. Thermochim. Acta, 1970, 1, 537; Kitchens, J.; Bear, J.L. J. Inorg. Nuclear Chem. 1970, 32, 49; Rainen, L.; Howard, R.A.; Kimball, A.P.; Bear, J.L. Inorg. Chem. 1975, 14, 2752; Das, K.; Bear, J.L. Inorg. Chem. 1976, 15, 2093; Das, K.; Kadish, K.M.; Bear, J.L. Inorg. Chem. 1978, 17, 930; Das, K., Simmons, E.L.; Bear, J.L. Inorg. Chem. 1977, 16, 1268; Erck, A.; Sherwood, E.; Bear, J.L.; Kimball, A.P. Cancer Res. 1976, 36, 2204.
7. Hughes, R.G.; Bear, J.L.; Kimball, A.P. Proc. Amer. Assoc. Cancer Res. 1972, 13, 120; Erck, A.; Rainen, L.; Whileyman, J.; Chang, I.M.; Kimball, A.P.; Bear, J.L. Proc. Soc. Exp. Biol. Med. 1974, 145, 1278; Bear, J.L.; Gray, H.B.; Rainen, L.; Chang, I.M.; Howard, R.; Serio, G.; Kimball, A.P. Cancer Chemother Rep. 1975, 59, 611; Kitchens, J.; Bear, J.L. J. Inorg. Nuclear Chem. 1969, 31, 2415; Kitchens, J.; Bear, J.L. J. Inorg. Nuclear Chem. 1971, 33, 3479; Kitchens, J.; Bear, J.L. Thermochim. Acta, 1970, 1, 537; Kitchens, J.; Bear, J.L. J. Inorg. Nuclear Chem. 1970, 32, 49; Rainen, L.; Howard, R.A.; Kimball, A.P.; Bear, J.L. Inorg. Chem. 1975, 14, 2752; Das, K.; Bear, J.L. Inorg. Chem. 1976, 15, 2093; Das, K.; Kadish, K.M.; Bear, J.L. Inorg. Chem. 1978, 17, 930; Das, K., Simmons, E.L.; Bear, J.L. Inorg. Chem. 1977, 16, 1268; Erck, A.; Sherwood, E.; Bear, J.L.; Kimball, A.P. Cancer Res. 1976, 36, 2204.
8. Hughes, R.G.; Bear, J.L.; Kimball, A.P. Proc. Amer. Assoc. Cancer Res. 1972, 13, 120; Erck, A.; Rainen, L.; Whileyman, J.; Chang, I.M.; Kimball, A.P.; Bear, J.L. Proc. Soc. Exp. Biol. Med. 1974, 145, 1278; Bear, J.L.; Gray, H.B.; Rainen, L.; Chang, I.M.; Howard, R.; Serio, G.; Kimball, A.P. Cancer Chemother Rep. 1975, 59, 611; Kitchens, J.; Bear, J.L. J. Inorg. Nuclear Chem. 1969, 31, 2415; Kitchens, J.; Bear, J.L. J. Inorg. Nuclear Chem. 1971, 33, 3479; Kitchens, J.; Bear, J.L. Thermochim. Acta, 1970, 1, 537; Kitchens, J.; Bear, J.L. J. Inorg. Nuclear Chem. 1970, 32, 49; Rainen, L.; Howard, R.A.; Kimball, A.P.; Bear, J.L. Inorg. Chem. 1975, 14, 2752; Das, K.; Bear, J.L. Inorg. Chem. 1976, 15, 2093; Das, K.; Kadish, K.M.; Bear, J.L. Inorg. Chem. 1978, 17, 930; Das, K., Simmons, E.L.; Bear, J.L. Inorg. Chem. 1977, 16, 1268; Erck, A.; Sherwood, E.; Bear, J.L.; Kimball, A.P. Cancer Res. 1976, 36, 2204.
9. Hughes, R.G.; Bear, J.L.; Kimball, A.P. Proc. Amer. Assoc. Cancer Res. 1972, 13, 120; Erck, A.; Rainen, L.; Whileyman, J.; Chang, I.M.; Kimball, A.P.; Bear, J.L. Proc. Soc. Exp. Biol. Med. 1974, 145, 1278; Bear, J.L.; Gray, H.B.; Rainen, L.; Chang, I.M.; Howard, R.; Serio, G.; Kimball, A.P. Cancer Chemother Rep. 1975, 59, 611; Kitchens, J.; Bear, J.L. J. Inorg. Nuclear Chem. 1969, 31, 2415; Kitchens, J.; Bear, J.L. J. Inorg. Nuclear Chem. 1971, 33, 3479; Kitchens, J.; Bear, J.L. Thermochim. Acta, 1970, 1, 537; Kitchens, J.; Bear, J.L. J. Inorg. Nuclear Chem. 1970, 32, 49; Rainen, L.; Howard, R.A.; Kimball, A.P.; Bear, J.L. Inorg. Chem. 1975, 14, 2752; Das, K.; Bear, J.L. Inorg. Chem. 1976, 15, 2093; Das, K.; Kadish, K.M.; Bear, J.L. Inorg. Chem. 1978, 17, 930; Das, K., Simmons, E.L.; Bear, J.L. Inorg. Chem. 1977, 16, 1268; Erck, A.; Sherwood, E.; Bear, J.L.; Kimball, A.P. Cancer Res. 1976, 36, 2204.
10. Hughes, R.G.; Bear, J.L.; Kimball, A.P. Proc. Amer. Assoc. Cancer Res. 1972, 13, 120; Erck, A.; Rainen, L.; Whileyman, J.; Chang, I.M.; Kimball, A.P.; Bear, J.L. Proc. Soc. Exp. Biol. Med. 1974, 145, 1278; Bear, J.L.; Gray, H.B.; Rainen, L.; Chang, I.M.; Howard, R.; Serio, G.; Kimball, A.P. Cancer Chemother Rep. 1975, 59, 611; Kitchens, J.; Bear, J.L. J. Inorg. Nuclear Chem. 1969, 31, 2415; Kitchens, J.; Bear, J.L. J. Inorg. Nuclear Chem. 1971, 33, 3479; Kitchens, J.; Bear, J.L. Thermochim. Acta, 1970, 1, 537; Kitchens, J.; Bear, J.L. J. Inorg. Nuclear Chem. 1970, 32, 49; Rainen, L.; Howard, R.A.; Kimball, A.P.; Bear, J.L. Inorg. Chem. 1975, 14, 2752; Das, K.; Bear, J.L. Inorg. Chem. 1976, 15, 2093; Das, K.; Kadish, K.M.; Bear, J.L. Inorg. Chem. 1978, 17, 930; Das, K., Simmons, E.L.; Bear, J.L. Inorg. Chem. 1977, 16, 1268; Erck, A.; Sherwood, E.; Bear, J.L.; Kimball, A.P. Cancer Res. 1976, 36, 2204.
11. Hughes, R.G.; Bear, J.L.; Kimball, A.P. Proc. Amer. Assoc. Cancer Res. 1972, 13, 120; Erck, A.; Rainen, L.; Whileyman, J.; Chang, I.M.; Kimball, A.P.; Bear, J.L. Proc. Soc. Exp. Biol. Med. 1974, 145, 1278; Bear, J.L.; Gray, H.B.; Rainen, L.; Chang, I.M.; Howard, R.; Serio, G.; Kimball, A.P. Cancer Chemother Rep. 1975, 59, 611; Kitchens, J.; Bear, J.L. J. Inorg. Nuclear Chem. 1969, 31, 2415; Kitchens, J.; Bear, J.L. J. Inorg. Nuclear Chem. 1971, 33, 3479; Kitchens, J.; Bear, J.L. Thermochim. Acta, 1970, 1, 537; Kitchens, J.; Bear, J.L. J. Inorg. Nuclear Chem. 1970, 32, 49; Rainen, L.; Howard, R.A.; Kimball, A.P.; Bear, J.L. Inorg. Chem. 1975, 14, 2752; Das, K.; Bear, J.L. Inorg. Chem. 1976, 15, 2093; Das, K.; Kadish, K.M.; Bear, J.L. Inorg. Chem. 1978, 17, 930; Das, K., Simmons, E.L.; Bear, J.L. Inorg. Chem. 1977, 16, 1268; Erck, A.; Sherwood, E.; Bear, J.L.; Kimball, A.P. Cancer Res. 1976, 36, 2204.
12. Hughes, R.G.; Bear, J.L.; Kimball, A.P. Proc. Amer. Assoc. Cancer Res. 1972, 13, 120; Erck, A.; Rainen, L.; Whileyman, J.; Chang, I.M.; Kimball, A.P.; Bear, J.L. Proc. Soc. Exp. Biol. Med. 1974, 145, 1278; Bear, J.L.; Gray, H.B.; Rainen, L.; Chang, I.M.; Howard, R.; Serio, G.; Kimball, A.P. Cancer Chemother Rep. 1975, 59, 611; Kitchens, J.; Bear, J.L. J. Inorg. Nuclear Chem. 1969, 31, 2415; Kitchens, J.; Bear, J.L. J. Inorg. Nuclear Chem. 1971, 33, 3479; Kitchens, J.; Bear, J.L. Thermochim. Acta, 1970, 1, 537; Kitchens, J.; Bear, J.L. J. Inorg. Nuclear Chem. 1970, 32, 49; Rainen, L.; Howard, R.A.; Kimball, A.P.; Bear, J.L. Inorg. Chem. 1975, 14, 2752; Das, K.; Bear, J.L. Inorg. Chem. 1976, 15, 2093; Das, K.; Kadish, K.M.; Bear, J.L. Inorg. Chem. 1978, 17, 930; Das, K., Simmons, E.L.; Bear, J.L. Inorg. Chem. 1977, 16, 1268; Erck, A.; Sherwood, E.; Bear, J.L.; Kimball, A.P. Cancer Res. 1976, 36, 2204.
13. Hughes, R.G.; Bear, J.L.; Kimball, A.P. Proc. Amer. Assoc. Cancer Res. 1972, 13, 120; Erck, A.; Rainen, L.; Whileyman, J.; Chang, I.M.; Kimball, A.P.; Bear, J.L. Proc. Soc. Exp. Biol. Med. 1974, 145, 1278; Bear, J.L.; Gray, H.B.; Rainen, L.; Chang, I.M.; Howard, R.; Serio, G.; Kimball, A.P. Cancer Chemother Rep. 1975, 59, 611; Kitchens, J.; Bear, J.L. J. Inorg. Nuclear Chem. 1969, 31, 2415; Kitchens, J.; Bear, J.L. J. Inorg. Nuclear Chem. 1971, 33, 3479; Kitchens, J.; Bear, J.L. Thermochim. Acta, 1970, 1, 537; Kitchens, J.; Bear, J.L. J. Inorg. Nuclear Chem. 1970, 32, 49; Rainen, L.; Howard, R.A.; Kimball, A.P.; Bear, J.L. Inorg. Chem. 1975, 14, 2752; Das, K.; Bear, J.L. Inorg. Chem. 1976, 15, 2093; Das, K.; Kadish, K.M.; Bear, J.L. Inorg. Chem. 1978, 17, 930; Das, K., Simmons, E.L.; Bear, J.L. Inorg. Chem. 1977, 16, 1268; Erck, A.; Sherwood, E.; Bear, J.L.; Kimball, A.P. Cancer Res. 1976, 36, 2204.
14. Chem. Eng. News 2000, 78, 50.
15. Nauta, K.; Miller, R.E. Science 2000, 287, 293.