2-Norbornyldimethylsilyl ethers (NDMS): A new protecting group for alcohols and carboxylic acids

Synlett

Volumn , Issue 11, 2002, Pages 1919-1921

  Heldmann, Dieter K ^a   Stohrer, Jürgen ^a   Zauner, Rafael ^a  

^a WACKER CHEMIE AG   (Germany)

Author keywords

Esters; Ethers; Hydrosilylation; Protecting groups; Silicon

Indexed keywords

2 NORBORNYLDIMETHYLSILYL ETHER; ALCOHOL DERIVATIVE; CARBOXYLIC ACID DERIVATIVE; ISOPROPYLDIMETHYLSILYL ETHER; REAGENT; SILANE DERIVATIVE; TERT BUTYL DIMETHYLSILYL ETHER; TRIMETHYLSILYL DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL REACTION; HYDROLYSIS; HYDROSILYLATION; MOLECULAR STABILITY; REACTION ANALYSIS; SYNTHESIS;

EID: 0036428019     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2002-34898     Document Type: Article

References (13)

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10. (a) Eddy, V. J.; Hallgren, J. E. J. Org. Chem. 1987, 52, 1903.
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12. Depending on the catalyst batch, ratios of 93:7 up to 95:5 were obtained. Major isomer is 3a(exo) according to citation 6.
13. 3), major isomer: δ = + 17.6; minor isomer: δ = + 19.6 ppm. Analysis by GC providing the same ratio is also possible.