Montmorillonite K10-catalyzed aza Diels-Alder reaction of Danishefsky's diene with aldimines, generated in situ from aliphatic aldehydes and amine, in aqueous media

Synlett

Volumn , Issue 11, 2002, Pages 1898-1900

  Akiyama, Takahiko ^a   Matsuda, Keiichiro ^a   Fuchibe, Kohei ^a  

^a GAKUSHUIN UNIVERSITY   (Japan)

Author keywords

Danishefsky's dienes; Diels Alder reactions; Montmorillonite; Schiff bases; Water

Indexed keywords

ALDEHYDE DERIVATIVE; ALKADIENE; AMINE; IMINE; MONTMORILLONITE; PYRIDONE DERIVATIVE;

AQUEOUS SOLUTION; ARTICLE; CATALYSIS; CATALYST; DIELS ALDER REACTION; REACTION ANALYSIS; TEMPERATURE DEPENDENCE;

EID: 0036423241     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2002-34870     Document Type: Article

References (39)

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36. 3N) gave propyl-substituted 2,3-dihydro-4-pyridone (34.6 mg, 0.141 mmol) in 89% yield.
37. 3CN were carried out at -10°C.
38. Even when the catalyst loading was reduced to 50 mg/mmol, 10% of the standard procedure shown above, the adducts were obtained in the same yields in the three-component synthesis under the conditions A, B, and C..
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