Chemical speciation of dissolved copper in Saginaw Bay, Lake Huron, with square wave anodic stripping voltammetry

Journal of Great Lakes Research

Volumn 28, Issue 3, 2002, Pages 466-478

  Bazzi, Ali ^a   Lehman, John T ^b   Nriagu, Jerome O ^b   Hollandsworth, Donna ^a   Irish, Nicholas ^a   Nosher, Todd ^b  

^a UNIVERSITY OF MICHIGAN DEARBORN   (United States)

^b UNIVERSITY OF MICHIGAN   (United States)

Author keywords

Chemical speciation; Dissolved copper; Saginaw Bay; Square wave anodic stripping voltammetry

Indexed keywords

CHELATION; COMPLEXATION; ECOSYSTEMS; ELECTRODES; LAKES; MERCURY (METAL);

LIGANDS;

COPPER;

COPPER; ELECTRODE; SPECIATION (CHEMISTRY);

GREAT LAKES; LAKE HURON; UNITED STATES;

EID: 0036383257     PISSN: 03801330     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0380-1330(02)70598-4     Document Type: Article

References (40)

1. Achterberg, E.P., and van den Berg, C.M.G. 1994. Automated voltammetric system for shipboard determination of metal speciation in sea water. Anal. Chim. Acta 284:463-471.
2. Antelo, J.M., Arce, F., and Penedo, F.J. 1998. Effect of seasonal changes on the complexing of Cu(II) by dissolved matter in river water. Wat. Res. 32(9): 2714-2720.
3. Borman, S.A. 1982. New electroanalytical pulse techniques. Anal. Chem. 54(6):698A-705A.
4. Brand, L.E., Sunda, W.G., and Guillard, R.R.L. 1986. Reduction of marine phytoplankton reproduction rates by copper and cadmium. J. Exp. Mar. Biol. Ecol. 96:225-250.
5. Bruland, K.W., Donat, J.R., and Hutchins, D.A. 1991. Interactive influences of bioactive trace metals on biological production in oceanic waters. Limnol. Oceanogr. 36(8):1555-1577.
6. _, Rue, E.L., Donat, J.R., Skrabal, S.A., and Moffett, J.W. 2000. Intercomparison of voltammetric techniques to determine the chemical speciation of dissolved copper in a coastal seawater sample. Anal. Chim. Acta. 405:99-113.
7. Campbell, P.G.C. 1995. Interactions between trace metals and aquatic organisms: a critique of the free ion activity model. In Metal speciation and bioavailability in aquatic systems (IUPAC series on analytical and physical chemistry of environmental systems Vol. 3.), eds. A. Tessier and D.R. Turner, pp. 47-102. New York, NY: John Wiley and Sons.
8. Coale, K.H., and Flegel, A.R. 1989. Copper, zinc, cadmium and lead in surface waters of lakes Erie and Ontario. The Science of the Total Environment 87/88: 297-304.
9. Deaver, E., and Rodgers Jr., J.H. 1996. Measuring bioavailable copper using anodic stripping voltammetry. Environ. Toxicol. Chem. 15(11):1925-1930.
10. Donat, J.R., Lao, K.A., and Bruland, K.W. 1994. Speciation of dissolved copper and nickel in south San Francisco Bay: a multi-method approach. Anal. Chim. Acta 284:547-571.
11. Eriksen, R.S., Mackey, D.J., van Dam, R., and Nowak, B. 2001. Copper speciation and toxicity in Macquarie Harbor, Tasmania: an investigation using a copper ion selective electrode. Mar. Chem. 74:99-113.
12. Florence, T.M. 1986. Electrochemical approaches to trace element speciation in waters; a review. Analyst 111:489-505.
13. Hall, L.W., Jr., Anderson, R.D., Kilian, J.V., Lewis, B.L., and Treaxler, K. 1997. Acute and chronic toxicity of copper to the estuarine copepod eurytemora affinis: influence of organic complexation and speciation. Chemosphere 35(7):1567-1597.
14. Hart, B.T. 1981. Trace metal complexing capacity of natural waters: a review. Environ. Tech. Let. 2:95-110.
15. Johengen, T.H., Nalepa, T.F., Fahnenstiel, G.L., and Goudy, G. 1995. Nutrient changes in Saginaw Bay, Lake Huron, after the establishment of zebra mussel (Dreissena polymorpha). J. Great Lakes Res. 21: 449-464.
16. Kozelka, P.B., and Bruland, K.W. 1998. Chemical speciation of dissolved Cu, Zn, Cd, Pb in Narrangansett Bay, Rhode Island. Mar. Chem. 60:267-282.
17. Kramer, C.J.M. 1986. Apparent copper complexation capacity and conditional stability constants in North Atlantic waters. Mar. Chem. 18:335-349.
18. Leal, M.F.C., and van den Berg, C.M.G. 1998. Evidence for strong copper(I) complexation by organic ligands in seawater. Aquatic Geochemistry 4:49-75.
19. _, Vasconcelos, M.T.S.D., and van den Berg, C.M.G. 1999. Copper-induced release of complexing ligands similar to thiols by Emiliania huxleyi in seawater cultures. Limnol. Oceanogr. 44(7):1750-1762.
20. Lewis, B.L., Luther, G.W., III, Lane, H., and Church, T.M. 1995. Determination of metal-organic complexation in natural waters by SWASV with pseudopolarograms. Electroanalysis 7(2):166-177.
21. Mansilla-Rivera, I. 2000. Chemical speciation and bioavailability of copper in the Huron River ecosystem. Ph.D. dissertation, University of Michigan, Ann Arbor, MI.
22. Moll, R.A., Jude, D., Rossmann, R., Kantak, G.V., Barres, J., DeBoe, S., Giesy, J., and Tuchman, M.J. 1995. Movement and loadings of inorganic contaminants through the lower Saginaw River. J. Great Lakes Res. 21:17-34.
23. Mota, A.M., and Correia dos Santos, M.M. 1995. Trace metal speciation of labile chemical species in natural waters: electrochemical methods. In Metal speciation and bioavailability in aquatic systems (IUPAC series on analytical and physical chemistry of environmental systems Vol. 3.), eds. A. Tessier and D.R. Turner, pp. 223-226. New York, NY: John Wiley and Sons.
24. Nriagu, J.O., Lawson, G., Wong, H.K.T., and Azcue, J.M. 1993. A protocol for minimizing contamination in the analysis of trace metals in Great Lakes waters. J. Great Lakes Res. 19(1):175-182.
25. _, Lawson, G., Wong, H.K.T., and Cheam, V. 1996. Dissolved trace metals in Lakes Superior, Erie, and Ontario. Environ. Sci. Technol. 30:178-187.
26. Presa, M.J.R., Catoggio, J.A., Posadas, D., and Tucceri, R.I. 1998. Determination of the complexation capacity of waters. Measurements on model systems and natural waters employing copper as the titrating ion. Enviro. Tech. 19:45-54.
27. Rossmann, R., and Barres, J. 1988. Trace element concentrations in near-surface waters of the Great Lakes and methods of collection, storage, and analysis. J. Great Lakes Res. 14:188-204.
28. Rozan, T.F., and Benoit, G. 1999. Geochemical factors controlling free Cu ion concentrations in river water. Geochimica et Cosmochimica Acta 63(19/20): 3311-3319.
29. Ruzic, I. 1982. Theoretical aspects of the direct titration of natural waters and its information yield for trace metal speciation. Anal. Chim. Acta 140:99-113.
30. Scarano, G., Bramanti, E., and Zirino, A. 1992. Determination of copper complexation in sea water by a ligand competition technique with voltammetric measurement of the labile metal fraction. Anal. Chim. Acta 264:153-162.
31. Shuman, M.S., and Woodward Jr., G.P. 1973. Chemical constants of metal complexes from a complexometric titration followed with anodic stripping voltammetry. Anal. Chem. 45(12):2032-2035.
32. Skrabal, S.A., Donat, J.R., and Burdige, D.J. 2000. Pore water distributions of dissolved copper and coppercomplexing ligands in estuarine and coastal marine sediments. Geochimica et Cosmochimica Acta 64(11): 1843-1857.
33. Sunda, W.G., Tester, P.A., and Huntsman, S.A. 1987. Effects of cupric and zinc ion activities on the survival and reproduction of marine copepods. Mar. Biol. 94:203-210.
34. _, Tester, P.A., and Huntsman, S.A. 1990. Toxicity of trace metals to Acartia tonsa in the Elizabeth River and southern Chesapeake Bay. Estuarine, Coastal and Shelf Science 30:207-221.
35. van den Berg, C.M.G. 1992. Effect of the deposition potential on the voltammetric determination of complexing ligand concentrations in sea-water. Analyst 117:589-593.
36. Verweij, W., Glazewski, R., and DeHaan, H. 1992. Speciation of copper in relation to its bioavailability. Chem. Speciation Bioavailability 4(2):43-51.
37. Wu, Y. 1998. Voltammetric studies on copper, lead, and cadmium speciation in the Great Lakes, Ph.D. dissertation, University of Michigan, Ann Arbor, MI.
38. Xue, H., and Sigg, L. 1999. Comparison of the complexation of Cu and Cd by humic or fulvic acids and by ligands observed in lake waters. Aquatic Geochemistry 5:313-335.
39. 2+] measurements in lake water determined by ligand exchange and cathodic stripping voltammetry and by ion selective electrode. Environ. Sci. Technol. 31:902-1909.
40. Young, J.S., Gurtisen, J.M., Apts, C.W., and Crecelius, E.A. 1979. The relationship between the copper complexing capacity of sea water and copper toxicity in shrimp zoeae. Mar. Environ. Res. 2:265-272.