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Carbodiimides 1 and LiA1HSeH 2 were prepared according to previously reported methods. See: for 1; Fell, J.B.; Coppola, G.M. Synth. Commun. 1995, 25, 43 and for 2; ref. 4. Biriefly, to a solution of selenium powder (0.80g, 10.0 mmol) in dry THF (100mL) was added lithium aluminium hydride (0.38 g, 10.0 mmol) at 0°C under an argon atmosphere. The mixture was stirred at 0°C for 30 min. The formed LiA1HSeH 2 is then ready for use in further reaction without concentration.
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