One-pot synthesis of ω-chloroesters via the reaction of acid chlorides with tetrahydrofuran in the presence of trichloroborane

Synthetic Communications

Volumn 32, Issue 13, 2002, Pages 1997-2001

  Malladi, Rama R ^a   Kabalka, George W ^a  

^a UNIVERSITY OF TENNESSEE   (United States)

Author keywords

Boron trichloride; Chloroesters; Ester formation; Ether cleavage

Indexed keywords

BORANE DERIVATIVE; CHLORIDE; CHLORINE DERIVATIVE; OMEGA CHLOROESTER DERIVATIVE; TETRAHYDROFURAN; TRICHLOROBORANE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION KINETICS; COMPLEX FORMATION; DECOMPOSITION; PRODUCT RECOVERY; REACTION ANALYSIS; SYNTHESIS;

EID: 0036326727     PISSN: 00397911     EISSN: None     Source Type: Journal    
DOI: 10.1081/SCC-120004849     Document Type: Article

References (13)

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3. Silicon tetrachloride/sodium iodide as a convenient and highly regioselective ether cleaving reagent
4. Cleavage of ethers
5. Cobalt(II)chloride catalyzed cleavage of ethers with acyl halides: Scope and mechanism
6. Reaction of dicyclopentadienylyttrium chloride with acyl chlorides in tetrahydrofuran. Acylative cleavage of the Cp-Y π-bond and tetrahydrofuran ring
7. Cleavage of ethers and geminal diacetates using the boron triiodide-N, N-diethylaniline complex
8. An efficient cleavage of lactones with boron triiodide-N, N-diethylaniline complex
9. Boron triiodide-N-N-diethylaniline complex: A new reagent for cleaving esters
10. Preparation of ketones via the palladium-catalyzed cross-coupling of acid chlorides with trialkylboranes
11. Zinc-promoted selective cleavage of ethers in presence of acyl chloride
12. Gas-liquid chromatographic analyses. IX. Glass capillary gas chromatography of aliphatic C1-C8n-alkyl monochloro esters of acetic, chloroacetic, dichloroacetic and trichloroacetic acids
13. High pressure organic chemistry. 9. Non-catalyzed cleavage reactions with acyl halides under high pressure conditions